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Co3O4 polyhedrons with enhanced electric conductivity as efficient water oxidation electrocatalysts in alkaline medium

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Abstract

It is a great challenge to develop Co3O4-based electrocatalysts of excellent performance for oxygen evolution reaction, because of its poor electrical conductivity. In this paper, we have prepared pristine Co3O4 (P-Co3O4) and Co3O4-C polyhedrons via two different calcination strategies. Then we have also displayed a simple and green reduction method to synthesize reduced Co3O4 (R-Co3O4) polyhedron with abundant surface oxygen vacancies. Oxygen vacancies and the doping of carbon species can enhance conductivity of electrocatalysts, thus, improving their electrocatalytic activities obviously. R-Co3O4 and Co3O4-C polyhedrons show lower overpotentials of 380 and 420 mV, respectively, compared to P-Co3O4 polyhedron (520 mV) at the current density of 10 mA cm−2 in 1 M KOH solution (pH 13.7). And they also have smaller Tafel slopes of 86 and 78 mV dec−1 than that of P-Co3O4 polyhedron (93 mV dec−1), respectively. The integrated strategy reported here provides the way to design high-performance electrocatalysts for water oxidation.

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Acknowledgements

This work was financially supported by Natural Science Foundation of Ningbo (Grant No. 2016A610069), National Natural Science Foundation of China (Grant No. 21603110) and K. C. Wong Magna Fund.

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  1. Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, 818 Fenghua Road, Ningbo, 315211, Zhejiang Province, People’s Republic of China

    Shi-Yuan Zhang, Ting-Ting Li, Hong-Lin Zhu & Yue-Qing Zheng

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  1. Shi-Yuan Zhang
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Zhang, SY., Li, TT., Zhu, HL. et al. Co3O4 polyhedrons with enhanced electric conductivity as efficient water oxidation electrocatalysts in alkaline medium. J Mater Sci 53, 4323–4333 (2018). https://doi.org/10.1007/s10853-017-1855-2

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