Abstract
Fibrillated cellulose can be used as a gelation agent to thicken and improve phase stability of sodium sulfate decahydrate (SSD, Na2SO4·10H2O), a promising salt hydrate for storing thermal energy. It is expected that dissolved SSD influences the thickening action by changing the colloid interactions between the cellulose fibrils. The fibrillation degree and surface charge of the cellulose are hypothesized to control the thickening effect. Phase stability of dissolved SSD was evaluated by sedimentation. Viscoelastic behaviors were characterized to understand microstructural and thickening mechanism created by fibrillated cellulose. Effect of fibrillated cellulose on heat release of SSD was measured during phase change. Dissolved SSD reduced the electrostatic repulsion between the cellulose fibrils by compressing the electric double layer due to charge screening. This resulted in denser aggregates for the mechanically fibrillated cellulose, assisted by increased attraction force. Viscosity and storage modulus of SSD increased and stable phase was formed without sedimentation. Higher fibrillation degree of the mechanically produced cellulose eliminated phase separation due to the increased specific surface area. The phase stabilization of SSD resulted in higher and longer heat release caused by bonding between water and anhydrous sodium sulfate.
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Agoda-Tandjawa G, Durand S, Berot S, Blassel C, Gaillard C, Garnier C, Doublier J-L (2010) Rheological characterization of microfibrillated cellulose suspensions after freezing. Carbohydr Polym 80:677–686. https://doi.org/10.1016/j.carbpol.2009.11.045
Albornoz-Palma G, Betancourt F, Mendonça RT, Ching-Carrasco G, Pereira M (2020) Relationship between rheological and morphological characteristics of cellulose nanofibrils in dilute dispersions. Carbohydr Polym 230:115588. https://doi.org/10.1016/j.carbpol.2019.115588
Dimic-Misic K, Gane PAC, Paltakari J (2013) Micro and nanofibrillated cellulose as a rheology modifier additive in CMC-containing pigment-coating formulation. Ind Eng Chem Res 52:16066–16083. https://doi.org/10.1021/ie4028878
Fashandi M, Leung SN (2018) Sodium acetate trihydrate-chitin nanowhisker nanocomposites with enhanced phase change performance for thermal energy storage. Sol Energy Mater Sol Cells 178:259–265. https://doi.org/10.1016/j.solmat.2018.01.037
Feng G, Xu X, Li G, Li H, Huang K (2015) Application of Na2SO4·10H2O thermal storage in air-conditioning cooling water system. Mater Res Innov 19:S5983–S5987. https://doi.org/10.1179/1432891714Z.0000000001234
Fukuzumi H, Tanaka R, Saito T, Isogai A (2014) Dispersion stability and aggregation behavior of TEMPO-oxidized cellulose nanofibrils in water as a function of salt addition. Cellulose 21:1553–1559. https://doi.org/10.1007/s10570-014-0180-z
Garay Ramirez BML, Glorieux C, Martin Martinez ES, Flores Cuautle JJA (2014) Tuning of thermal properties of sodium acetate trihydrate by blending with polymer and silver nanoparticles. Appl Therm Eng 62:838–844. https://doi.org/10.1016/j.applthermaleng.2013.09.049
Hou P, Mao J, Chen F, Li Y, Dong X (2018) Preparation and thermal performance enhancement of low temperature eutectic composite phase change materials based on Na2SO4·10H2O. Materials 11:2230. https://doi.org/10.3390/ma11112230
Hyun K, Kim SH, Ahn KH, Lee SJ (2002) Large amplitude oscillatory shear as a way to classify the complex fluids. J Non-Newton Fluid Mech 107:51–65. https://doi.org/10.1016/S0377-0257(02)00141-6
Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3:71–85. https://doi.org/10.1039/C0NR00583E
Karimineghlani P, Emmons E, Green MJ, Shamberger P, Sukhishvili SA (2017) Temperature-responsive poly(vinyl alcohol) gel for controlling fluidity of an inorganic phase change material. J Mater Chem A Mater 5:12474–12482. https://doi.org/10.1039/C7TA02897K
Karppinen A, Saarinen T, Salmela J, Laukkanen A, Nuopponen M, Seppälä J (2012) Flocculation of microfibrillated cellulose in shear flow. Cellulose 19:1807–1819. https://doi.org/10.1007/s10570-012-9766-5
Li G, Zhang B, Li X, Zhou Y, Sun Q, Yun Q (2014) The preparation, characterization and modification of a new phase change material: CaCl2·6H2O–MgCl2·6H2O eutectic hydrate salt. Sol Energy Mater Sol Cells 126:51–55. https://doi.org/10.1016/j.solmat.2014.03.031
Li X, Zhou Y, Zian H, Zhu F, Ren X, Dong Q, Hai C, Shen Y, Zeng J (2016) Preparation and thermal energy storage studies of CH3COONa·3H2O–KCl composites salt system with enhanced phase change performance. Appl Therm Eng 102:708–715. https://doi.org/10.1016/j.applthermaleng.2016.04.029
Liu Y, Yang Y (2017) Use of nano-α-Al2O3 to improve binary eutectic hydrated salt as phase change material. Sol Energy Mater Sol Cells 160:18–25. https://doi.org/10.1016/j.solmat.2016.09.050
Liu Y, Yang Y (2018) Form-stable phase change material based on Na2CO3·10H2O-NaHPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: the influence of chemical structures of expanded graphite oxide. Renew Energy 115:734–740. https://doi.org/10.1016/j.renene.2017.08.097
Liu Y, Yang Y, Li S (2016) Graphene oxide modified hydrate salt hydrogels: form-stable phase change materials for smart thermal management. J Mater Chem A Mater 4:18134–18143. https://doi.org/10.1039/C6TA08850C
Lopez CG, Colby RH, Cabral JT (2018) Electrostatic and hydrophobic interactions in NaCMC aqueous solutions: effect of degree of substitution. Macromolecules 51:3165–3175. https://doi.org/10.1021/acs.macromol.8b00178
Lowys M-P, Desbrieres J, Rinaudo M (2001) Rheological characterization of cellulosic microfibril polymeric additives. Food Hydrocoll 15:25–32. https://doi.org/10.1016/S0268-005X(00)00046-1
Mao J, Dong X, Hou P, Lian H (2017) Preparation research of novel composite phase change materials based on sodium acetate trihydrate. Appl Therm Eng 118:817–825. https://doi.org/10.1016/j.applthermaleng.2017.02.102
Marliacy P, Solimando R, Bouroukba M, Schuffenecker L (2000) Thermodynamics of crystallization of sodium sulfate decahydrate in H2O–NaCl–Na2SO4: application to Na2SO4·10H2O-based latent heat storage materials. Thermochim Acta 344:85–94. https://doi.org/10.1016/S0040-6031(99)00331-7
Mendoza L, Batchelor W, Tabor RF, Garnier G (2018) Gelation mechanism of cellulose nanofiber gels: a colloids and interfacial perspective. J Colloid Interface Sci 509:39–46. https://doi.org/10.1016/j.jcis.2017.08.101
Oh K, Lee J-H, Im W, Rajabi Abhari A, Lee HL (2017) Role of cellulose nanofibrils in structure formation of pigment coating layers. Ind Eng Chem Res 56:9569–9577. https://doi.org/10.1021/acs.iecr.7b02750
Raghavan SR, Khan SA (1997) Shear-thickening response of fumed silica suspensions under steady and oscillatory shear. J Colloid Interface Sci 185:57–67. https://doi.org/10.1006/jcis.1996.4581
Saarikoski E, Saarinen T, Salmela J, Seppala J (2012) Flocculated flow of microfibrillated cellulose water suspension: imaging approach for characterization of rheological behavior. Cellulose 19:647–659. https://doi.org/10.1007/s10570-012-9661-0
Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromolecules 8:2485–2491. https://doi.org/10.1021/bm0703970
Schenker M, Schoelkopf J, Gane P, Mangin P (2018) Influence of shear rheometer measurement systems on the rheological properties of microfibrillated cellulose (MFC) suspensions. Cellulose 25:961–976. https://doi.org/10.1007/s10570-017-1642-x
Schenker M, Schoelkopf J, Gane P, Mangin P (2019) Rheology of microfibrillated cellulose (MFC) suspensions: influence of the degree of fibrillated and residual fibre content on flow and viscoelastic properties. Cellulose 26:845–860. https://doi.org/10.1007/s10570-018-2117-4
Shin S, Park S, Park M, Jeong E, Na K, Youn HJ, Hyun J (2017) Cellulose nanofibers for the enhancement of printability of low viscosity gelatin derivatives. BioResources 12:2941–2954. https://doi.org/10.15376/biores.12.2.2941-2954
Taheri H, Samyn P (2016) Effect of homogenization (microfluidization) process parameters in mechanical production of micro- and nanofibrillated cellulose on its rheological and morphological properties. Cellulose 23:1221–1238. https://doi.org/10.1007/s10570-016-0866-5
Wang Y, Yu K, Peng H, Ling X (2019) Preparation and thermal properties of sodium acetate trihydrate as a novel phase change material for energy storage. Energy 167:269–274. https://doi.org/10.1016/j.energy.2018.10.164
Xu W, Molino BZ, Cheng F, Molino PJ, Yue Z, Su D, Wang X, Willfor S, Xu C, Wallace GG (2019a) On low-concentration inks formulated by nanocellulose assisted with gelatin methacrylate (GelMA) for 3D printing toward wound healing application. ACS Appl Mater Interfaces 11:8838–8848. https://doi.org/10.1021/acsami.8b21268
Xu W, Zhang X, Yang P, Långvik O, Wang X, Zhang Y, Cheng F, Österberg M, Willför S, Xu C (2019b) Surface engineered biomimetic inks based on UV cross-linkable wood biopolymers for 3D printing. ACS Appl Mater Interfaces 11:12389–12400. https://doi.org/10.1021/acsami.9b03442
Yziquel F, Carreau PJ, Moan M, Tanguy PA (1999) Rheological modeling of concentrated colloidal suspensions. J Non-Newton Fluid Mech 86:133–155. https://doi.org/10.1016/S0377-0257(98)00206-7
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This research was supported by a National Research Foundation of Korea (NRF) Grant funded by the Korean government (NRF-2019R1C1C1003126).
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Oh, K., Kwon, S., Xu, W. et al. Effect of micro- and nanofibrillated cellulose on the phase stability of sodium sulfate decahydrate based phase change material. Cellulose 27, 5003–5016 (2020). https://doi.org/10.1007/s10570-020-03121-w
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DOI: https://doi.org/10.1007/s10570-020-03121-w