Abstract
We report on a simple technique for the production of mechanically durable water-repellent layer on viscose fibers via spray-coating of a lanolin-silicon rubber solution in petroleum ether. Depending on the silicon rubber solution concentration, it was achievable to gain surfaces with hierarchical morphology. Extracted lanolin was admixed with a mixture of a room temperature vulcanizing silicon rubber and petroleum ether to afford the silicon rubber-lanolin formulation, which was applied successfully onto viscose fabrics employing spray-coat procedure. The surface characteristics of the spray-coated viscose fibers were studied by scanning electron microscope, energy dispersive X-ray analysis, and static water contact and sliding angle measurements. The alteration in the chemical composition of viscose-treated fabric was studied using Fourier-transform infrared spectroscopy. The wetting behavior was found to be a function of silicon rubber concentration in ether solution affording coatings with high static water contact angle and low sliding angle values. The treated viscose fabric exhibited excellent ultraviolet protection and enhanced hydrophobicity without adverse effect on its inherent physico-mechanical properties. The comfort characteristics of spray-coated viscose fibers were also evaluated by studying their air-permeability and stiffness. The results displayed durable water-repellent properties of the treated viscose, introducing a good opportunity for a large-scale manufacture of water-repellent textiles for a diversity of industrial purposes.
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References
Abbas R, Khereby M, Sadik W, El Demerdash A (2015) Fabrication of durable and cost effective superhydrophobic cotton textiles via simple one step process. Cellulose 22:887–896
Abdelmoez S, Abd El Azeem R, Nada A, Khattab A (2016) Electrospun PDA-CA nanofibers toward hydrophobic coatings. Zeitschrift für Anorganische und Allgemeine Chemie 642:219–221
Abdelrahman MS, Khattab TA (2019) Development of one-step water-repellent and flame-retardant finishes for cotton. ChemistrySelect 4(13):3811–3816
Aboutalebi S, Jalili R, Esrafilzadeh D, Salari M, Gholamvand Z, Yamini S, Konstantinov K et al (2014) High-performance multifunctional graphene yarns: toward wearable all-carbon energy storage textiles. ACS Nano 8:2456–2466
Aziz F, Ismail A (2015) Spray coating methods for polymer solar cells fabrication: a review. Mater Sci Semicond Process 39:416–425
Bian P, Dai Y, Qian X, Chen W, Yu H, Li J, Shen J (2014) A process of converting cellulosic fibers to a superhydrophobic fiber product by internal and surface applications of calcium carbonate in combination with bio-wax post-treatment. RSC Adv 4:52680–52685
Cao G, Zhang W, Jia Z, Liu F, Yang H, Yu Q, Wang Y, Di X, Wang C, Ho S (2017) Dually prewetted underwater superoleophobic and under oil superhydrophobic fabric for successive separation of light oil/water/heavy oil three-phase mixtures. ACS Appl Mater Interfaces 9:36368–36376
Chauhan P, Kumar A, Bhushan B (2019) Self-cleaning, stain-resistant and anti-bacterial superhydrophobic cotton fabric prepared by simple immersion technique. J Colloid Interface Sci 535:66–74
Chen X, Guan Y, Wang L, Sanbhal N, Zhao F, Zou Q, Zhang Q (2016) Antimicrobial textiles for sutures, implants, and scaffolds. In: Sun G (ed) Antimicrobial textiles. Woodhead Publishing, Sawston, pp 263–285
Cheng Q, Liu M, Li Y, Zhu J, Du A, Zeng B (2018) Biobased super-hydrophobic coating on cotton fabric fabricated by spray-coating for efficient oil/water separation. Polym Test 66:41–47
Edman B, Möller H (1989) Testing a purified lanolin preparation by a randomized procedure. Contact Dermat 20:287–290
Flockhart I, Steel I, Kitchen G (1998) Nanoemulsions derived from lanolin show promising drug delivery properties. J Pharm Pharmacol 50:141-141
Girotto C, Rand B, Genoe J, Heremans P (2009) Exploring spray coating as a deposition technique for the fabrication of solution-processed solar cells. Sol Energy Mater Sol Cells 93:454–458
Heredia-Guerrero A, Ceseracciu L, Guzman-Puyol S, Paul Uttam, Alfaro-Pulido A, Grande Chiara, Vezzulli L et al (2018) Antimicrobial, antioxidant, and waterproof RTV silicone-ethyl cellulose composites containing clove essential oil. Carbohyd Polym 192:150–158
Hoefnagels H, Wu D, With G, Ming W (2007) Biomimetic superhydrophobic and highly oleophobic cotton textiles. Langmuir 23:13158–13163
Huang K, Yeh J, Shun T, Chen S (2004) Multi-principal-element alloys with improved oxidation and wear resistance for thermal spray coating. Adv Eng Mater 6:74–78
Holme I (2007) Innovative technologies for high performance textiles. Color Technol 123:59–73
Khalil-Abad M, Yazdanshenas M (2010) Superhydrophobic antibacterial cotton textiles. J Colloid Interface Sci 351:293–298
Khattab TA, Helmy H (2019) Industrial and filtration textiles. In: Paul R (ed) High performance technical textiles. Wiley, Hoboken, pp 215–237
Khattab T, Elnagdi M, Haggag K, Abdelrahman A, Abdelmoez S (2017) Green synthesis, printing performance, and antibacterial activity of disperse dyes incorporating arylazopyrazolopyrimidines. AATCC J Res 4:1–8
Khattab T, Abou-Yousef H, Kamel S (2018a) Photoluminescent spray-coated paper sheet: write-in-the-dark. Carbohyd Polym 200:154–161
Khattab T, Rehan M, Hamouda T (2018b) Smart textile framework: photochromic and fluorescent cellulosic fabric printed by strontium aluminate pigment. Carbohyd Polym 195:143–152
Khattab T, Rehan M, Hamdy Y, Shaheen T (2018c) Facile development of photoluminescent textile fabric via spray coating of Eu(II)-doped strontium aluminate. Ind Eng Chem Res 57:11483–11492
Khattab TA, Fouda MM, Abdelrahman MS, Othman SI, Bin-Jumah M, Alqaraawi MA, Al Fassam H, Allam AA (2019) Development of illuminant glow-in-the-dark cotton fabric coated by luminescent composite with antimicrobial activity and ultraviolet protection. J Fluoresc 29(3):703–710
Kumar V, Lee D, Lee J (2016) Studies of RTV silicone rubber nanocomposites based on graphitic nanofillers. Polym Testing 56:369–378
Labouriau A, Cady C, Gill J, Taylor D, Zocco A, Stull J, Henderson K, Wrobleski D (2015a) The effects of gamma irradiation on RTV polysiloxane foams. Polym Degrad Stab 117:75–83
Labouriau A, Robison T, Meincke L, Wrobleski D, Taylor D, Gill J (2015b) Aging mechanisms in RTV polysiloxane foams. Polym Degrad Stab 121:60–68
Liu K-F, Li P-P, Zhang Y-P, Liu P-F, Cui C-X, Wang J-C, Li X-J, Qu L-B (2019) Laboratory filter paper from superhydrophobic to quasi-superamphiphobicity: facile fabrication, simplified patterning and smart application. Cellulose 26(6):3859–3872
Ma Y, Cao C, Hou C (2018) Preparation of super-hydrophobic cotton fabric with crosslinkable fluoropolymer. In: Zhao P, Ouyang Y, Xu M, Yang L, Ren Y (eds) Applied sciences in graphic communication and packaging. Springer, Singapore, pp 955–962
Madara D, Namango S (2014) Wool grease recovery from scouring effluent at textile mill. J Agric Pure Appl Sci Technol 10:1–9
Moridi A, Gangaraj S, Guagliano M, Dao M (2014) Cold spray coating: review of material systems and future perspectives. Surf Eng 30:369–395
Nouri NM, Saadat-Bakhsh M (2017) Fabrication method of large-scale and mechanically durable superhydrophobic silicon rubber/aerogel coating on fibrous substrates. J Coat Technol Res 14(2):477–488
Ogihara H, Okagaki J, Saji T (2011) Facile fabrication of colored superhydrophobic coatings by spraying a pigment nanoparticle suspension. Langmuir 27:9069–9072
Ogihara H, Xie J, Okagaki J, Saji T (2012) Simple method for preparing superhydrophobic paper: spray-deposited hydrophobic silica nanoparticle coatings exhibit high water-repellency and transparency. Langmuir 28:4605–4608
Ogihara H, Xie J, Saji T (2013) Factors determining wettability of superhydrophobic paper prepared by spraying nanoparticle suspensions. Colloids Surf A 434:35–41
Oulton P (1995) Fire-retardant textiles. Chemistry of the textiles industry. In: Carr CM (ed) Blackie academic and professional, chapter 3. Springer, Singapore, pp 102–124
Pan G, Xiao X, Yu N, Ye Z (2018) Fabrication of superhydrophobic coatings on cotton fabric using ultrasound-assisted in situ growth method. Prog Org Coat 125:463–471
Qiang S, Chen K, Yin Y, Wang C (2017) Robust UV-cured superhydrophobic cotton fabric surfaces with self-healing ability. Mater Des 116:395–402
Rehan M, Khattab T, Barohum A, Gätjen L, Wilken R (2018) Development of Ag/AgX (X = Cl, I) nanoparticles toward antimicrobial, UV-protected and self-cleanable viscose fibers. Carbohyd Polym 197:227–236
Sabri F, King D, Lokesh A, Hatch C, Duran R (2015) Thermal, optical, and electrical characterization of thin film coated RTV 655 bilayer system. J Appl Polym Sci 132:41396–41407
Seyedmehdi SA, Zhang H, Zhu J (2012) Superhydrophobic RTV silicone rubber insulator coatings. Appl Surf Sci 258(7):2972–2976
Si Y, Guo Z (2016) Eco-friendly functionalized superhydrophobic recycled paper with enhanced flame-retardancy. J Colloid Interface Sci 477:74–82
Wang L, Zhang X, Li B, Sun P, Yang J, Xu H, Liu Y (2011) Superhydrophobic and ultraviolet-blocking cotton textiles. ACS Appl Mater Interfaces 3:1277–1281
Xu F, Liu Y, Lin F, Mondal B, Lyons A (2013) Superhydrophobic TiO2–polymer nanocomposite surface with UV-induced reversible wettability and self-cleaning properties. ACS Appl Mater Interfaces 5:8915–8924
Xue C, Jia S, Zhang J, Tian L, Chen H, Wang M (2008) Preparation of superhydrophobic surfaces on cotton textiles. Sci Technol Adv Mater 9:035008
Xue C, Ji P, Zhang P, Li Y, Jia S (2013) Fabrication of superhydrophobic and superoleophilic textiles for oil–water separation. Appl Surf Sci 284:464–471
Xue C, Li M, Guo X, Li X, An Q, Jia S (2017) Fabrication of superhydrophobic textiles with high water pressure resistance. Surf Coat Technol 310:134–142
Xue C, Fan Q, Guo X, An Q, Jia S (2019) Fabrication of superhydrophobic cotton fabrics by grafting of POSS-based polymers on fibers. Appl Surf Sci 465:241–248
Yao L, Hammond G (2006) Isolation and melting properties of branched-chain esters from lanolin. J Am Oil Chem Soc 83:547–552
Zhang M, Wang C, Wang S, Li J (2013) Fabrication of superhydrophobic cotton textiles for water–oil separation based on drop-coating route. Carbohyd Polym 97:59–64
Zhang Y-P, Yang J-H, Li L-L, Cui C-X, Li Y, Liu S-Q, Zhou X-M, Qu L-B (2019a) Facile fabrication of superhydrophobic copper-foam and electrospinning polystyrene fiber for combinational oil-water separation. Polymers 11(1):97
Zhang Y-P, Li P-P, Liu P-F, Zhang W-Q, Wang J-C, Cui C-X, Li X-J, Qu L-B (2019b) Fast and simple fabrication of superhydrophobic coating by polymer induced phase separation. Nanomaterials 9(3):411
Zhu J (2018) A novel fabrication of superhydrophobic surfaces on aluminum substrate. Appl Surf Sci 447:363–367
Zimmermann J, Reifler F, Fortunato A, Gerhardt L, Seeger S (2008) A simple, one-step approach to durable and robust superhydrophobic textiles. Adv Func Mater 18:3662–3669
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The authors are indebted to the National Research Centre of Egypt for the financial support through Project Number 11070204.
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Khattab, T.A., Mowafi, S. & El-Sayed, H. Development of mechanically durable hydrophobic lanolin/silicone rubber coating on viscose fibers. Cellulose 26, 9361–9371 (2019). https://doi.org/10.1007/s10570-019-02721-5
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DOI: https://doi.org/10.1007/s10570-019-02721-5