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Waugh-Type NiMo Heteropolycompounds as More Effective Precursors of Hydrodesulfurization Catalyst

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Abstract

NiMo catalysts were prepared using Waugh-type NiMo heteropolycompounds as active phase precursors and evaluated in hydrodesulfurization (HDS) of dibenzothiophene (DBT). These catalysts were compared with corresponding reference catalysts prepared from the conventional precursors (ammonium heptamolybdate and nickel nitrate). Prepared catalysts were characterized by N2 physisorption, XRD, FT-IR, H2-TPR, DRIFT of CO adsorption and HRTEM techniques. It was found that NiMo catalysts prepared from Waugh-type NiMo HPCs showed higher performance in HDS of DBT than their counterparts. Possible reasons of this result were discussed.

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Acknowledgments

This work was supported by the National Basic Research Program of China (2010CB226905), the Natural Science Foundation of China (21176258, U1162203, 21301190), Specialized Research Fund for the Doctoral Program of Higher Education of China (20110133110002), and the Fundamental Research Funds for the Central Universities (13CX06039A, 13CX02007A, 13CX05020A).

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Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum (East China), Qingdao, 266555, People’s Republic of China

    Jilei Liang, Yunqi Liu, Jinchong Zhao, Xuehui Li, Yukun Lu, Mengmeng Wu & Chenguang Liu

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  1. Jilei Liang
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  2. Yunqi Liu
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  3. Jinchong Zhao
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  4. Xuehui Li
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  5. Yukun Lu
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Correspondence to Yunqi Liu or Yukun Lu.

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Liang, J., Liu, Y., Zhao, J. et al. Waugh-Type NiMo Heteropolycompounds as More Effective Precursors of Hydrodesulfurization Catalyst. Catal Lett 144, 1735–1744 (2014). https://doi.org/10.1007/s10562-014-1326-1

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  • DOI: https://doi.org/10.1007/s10562-014-1326-1

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