Abstract
We report the single-step synthesis of novel tin-based core–carbosilazane shell nano-composites using laser pyrolysis technique. Controlled NH3 flows were used to entrain the vapors of volatile precursors: Sn(CH3)4 (TMT) and Fe(CO)5 injected through center for the core and [Si(CH3)3]2NH (HMDS) through the annular nozzle for the shell. Both NH3 and HMDS plays also the role of absorbers of the IR laser radiation. The obtained nanoparticles shown polydispersity with sizes from 5 up to around 120 nm, having spheroidal crystalline core—disordered shell morphology as confirmed by transmission electron microscopy images, where also short amorphous nanofibers were observed. The dominant crystalline phase β-Sn (having mean crystallite size between 22 and 29 nm) and minor tin-iron intermetallic and nitride phases were identified by X-ray diffraction. Infrared spectra show the presence of Si–N and Si–C bonds, pointing to a carbosilazane composition of the shells, accompanied by Si–O bonds due to partial oxidation after air exposure. Three different samples were obtained by keeping constant the Sn and Fe precursors flows and diminishing the HDMS flow, together with the corresponding NH3 flows. Preliminary tests of these materials as anodes for Li-ion battery showed an initial discharge capacity near 800 mAg/h which decreased to 300 mAh/g after 20 cycles for the sample having the highest Sn content.
Similar content being viewed by others
References
N. Nitta, F. Wu, J.T. Lee, G. Yushin, Mater. Today 18, 252 (2015)
P. Roy, S.K. Srivastava, J. Mater. Chem. A 3, 2454 (2015)
V.A. Agubra, L. Zuniga, D. Flores, J. VIllareal, M. Alcoutlabi, Electrochim. Acta 19, 529 (2016)
M.M. Thackeray, C. Wolverton, E.D. Isaacs, Energy Environ. Sci. 5, 7854 (2012)
N. Nitta, G. Yushin, Part. Part. Synth. Charact. 317, 331 (2014)
B.W.R. Chowdari, Bulk- and nanomaterials for Li ion batteries. https://www.iitk.ac.in/reach/2007/NUS/NUS_01_BVRChowdari.ppt.pdf. Accessed 10 June 2017
N. Oehl, G. Schmuelling, M. Knipper, R. Kloepsch, T. Placke, J. Kolny-Olesiak, T. Plaggenborg, M. Winter, J. Parisi, CrystEngComm 17, 8500 (2015)
G.R. Goward, N.J. Taylor, D.C.S. Souza, L.F. Nazar, J. Alloys Cpds. 329, 82 (2001)
C. Lupu, J.-G. Mao, J.W. Rabalais, A.M. Guloy, J.W. Richardson Jr., Inorg. Chem. 42, 3765 (2003)
M. Zhang, T. Wang, G. Gao, Int. Mater. Rev. 60, 330 (2015)
H. Tian, F. Xin, X. Wang, W. He, W. Han, J. Materiomics 1, 153 (2015)
J. Li, Z. Du, R.E. Ruther, S.J. An, L.A. David, K. Hays, M. Wood, N.D. Phillip, Y. Sheng, C. Mao, S. Kalnaus, C. Daniel, D.L. Wood, III, JOM (2017) doi:10.1007/s11837-017-2404-9
C.-M. Park, KJ.-H. Kim, H. Kim, H.-J. Sohn, Chem. Soc. Rev. 39, 3115 (2010)
A.S. Arico, P. Bruce, B. Scrosati, J.-M. Tarascon, V. Van Schalkwijk, Nat. Mater. 4, 366 (2005)
J. Chen, Materials 6, 156 (2013)
P. Bruce, B. Scrosati, J.-M. Tarascon, Angew. Chem. Int. Ed. 47, 2930 (2008)
A. Patil, V. Patil, D.W. Shin, J.-W. Choi, D.-S. Paik, S.-J. Yon, Mater. Res. Bull. 43, 1913 (2008)
L. Su, Z. Zhou, M. Ren, Chem. Commun. 46, 2590 (2010)
M. Mouyane, L. Aldon, M. Womes, B. Ducourant, J.-C. Jumas, J. Olivier-Fourcade, J. Power Sources 189, 818 (2009)
J.-M. Lee, H. Jung, Y. Hwa, H. Kim, D. Im, S.-G. Doo, H.-J. Sohn, J. Power Sources 195, 5044 (2010)
S.L. Weeks, N. Leick, S. Agarwal, Plasma Process. Polym. 13, 116 (2016)
G. Conubeer, M. Green, E.-C. Cho, D. König, Y.-H. Cho, T. Fangsuwannarak, G. Scandera, E. Pink, Y. Huang, T. Puzzer, S. Huuang, D. Song, C. Flynn, S. Park, X. Hao, D. Mansfield, Thin Solid Films 516, 6748 (2008)
S. Huang, Y.H. So, G. Coinbeer, M.A. Green, J. Appl. Phys. 105, 124303 (2009)
C.-S. Yang, Q. Liu, S.M. Kauzlarich, Chem. Mater. 12, 983 (2000)
W. Kafrouni, V. Rouessac, A. Julbe, J. Durand, J. Membr. Sci. 329, 130 (2009)
W. Kafrouni, V. Rouessac, A. Julbe, J. Durand, Appl. Surf. Sci. 257, 1196 (2010)
E. Ferreira, P. Fortunato, A.S. Vilarinho, A.R. Viana, E. Ramos, R. Alves, Martins, J. Non Cryst. Solids 235, 1361 (2006)
G.W. Rice, R.L. Woodin, J. Mater. Res. 4, 1538 (1989)
N. Herlin, O. Croix, M. Cauchetier, M. Luce, E. Musset, J. Phys. IV, 314981 (1993)
M. Cauchetier, O. Croix, N. Herlin, M. Luce, J. Am. Ceram. Soc. 77, 993 (1994)
M. Cauchetier, O. Croix, M. Luce, M.I. Barton, T. Merle, P. Quintard, J. Eur. Ceram. Soc. 8, 215 (1990)
R. Alexandrescu, I. Morjan, E. Borsella, S. Botti, R. Fantoni, A.T. Dikonimos-Makris, R. Giorgi, S. Erzo, J. Mater. Res. 6, 2442 (1991)
E. Dutu, F. Dumitrache, C.T. Fleaca, I. Morjan, L. Gavrila-Florescu, I.P. Morjan, I. Sandu, M. Scarisoreanu, C. Luculescu, A.-M. Niculescu, E. Vasile, Appl. Surf. Sci. 336, 290 (2015)
R. Alexandrescu, I. Morjan, F. Dumitrache, R. Birjega, C. Fleaca, I.P. Morjan, M. Scarisoreanu, C. Luculescu, E. Dutu, V. Kuncser, G. Filoti, E. Vasile, V. Ciupina, Appl. Surf. Sci. 3258, 9421 (2012)
C.T. Fleaca, I. Morjan, R. Alexandrescu, F. Dumitrache, I. Soare, L. Gavrila-Florescu, F. Le Normand, A. Derory, Appl. Surf. Sci. 255, 5386 (2009)
C. Fleaca, F. Dumitrache, E. Dutu, C. Luculescu, A.-M. Niculescu, A. Ilie, E. Vasile, U.P.B. Sci. Bull. B 78, 43 (2016)
C.E. Housecroft, K. Wade, B.C. Smith, J. Organomet. Chem. 179, C1 (1979)
R.P. Johnson, J.W. Price, Can. J. Chem. 50, 50 (1972)
J. Pola, M. Marysko, V. Vorlicek, Z. Bastl, A. Galokova, K. Vacek, R. Alexandrescu, F. Dumitrache, I. Morjan, L. Albu, G. Prodan, Appl. Organomet. Chem. 19, 1015 (2005)
N. Inagaki, Y. Hashimoto, Polym. Bull. 12, 437 (1984)
X. Zhang, Y. Rao, J. Guo, G. Qin, Carbon 96, 972 (2016)
Y. El Mendili, J.-F. Bardeau, N. Randrianantoandro, A. Gourbil, J.-M. Greneche, A.-M. Mercier, F. Grasset, J. Raman Spectrosc. 42, 239 (2011)
Z. Dohicevic-Mitrovic, Z.V. Popovic, Solid State Phenom. 6162, 258 (1998)
C. Serenaud, A. Gheorghiu, G. de la Rocque, N. Dufour, Herlin, J. Appl. Phys. 84, 4945 (1998)
K.C.H. Kumar, P. Wollants, L. Delaey, Calphad 20, 139 (1996)
Y. Suda, K. Maruyama, T. Iida, H. Takikawa, H. Ue, K. Shimizu, Y. Umeda, Crystals 5, 47 (2015)
A.B. Kuriganova, C.A. Vlaic, S. Ivanov, D.V. Leontyeva, A. Bund, N.V. Smirnova, J. Appl. Electochem. 46, 527 (2016)
Y. Guo, X. Zeng, Y. Zhang, Z. Dai, H. Fan, Y. Huang, W. Zhang, H. Zhang, J. Lu, F. Huo, Q. Yan, Sn nanoparticles encapsulated in 3D nanoporous carbon derived from a metal–organic framework for anode material in lithium-ion batteries. ACS Appl. Mater. Interfaces 9, 17172–17177 (2017)
X. Chang, T. Wang, Z. Liu, X. Zheng, J. Zheng, X. Li, Ultrafine Sn nanocrystals in a hierarchically porous N-doped carbon for lithium ion batteries. Nano Res. 10, 1950–1958 (2017)
Y. Xu, Q. Liu, Y. Zhu, Y. Liu, A. Langrock, M.R. Zachariah, C. Wang, Uniform nano-Sn/C composite anodes for lithium ion batteries. Nano Lett. 13, 470–474 (2013)
Y. Ye, P. Wu, X. Zhang, T. Zhou, Y. Tang, Y. Zhou, T. Lu, Facile synthesis of graphene supported FeSn2 nanocrystals with enhanced Li-storage capability. RSC Adv. 4, 17401 (2014)
Acknowledgements
The financial support from Human Resources Program—Young Researcher Teams Subprogram PN-II-RU-TE-2014-4-2834 of the Romanian Ministry of Education and Research and from Romanian National Authority for Research and Innovation Nucleu Program 4N/2016 is greatly acknowledged. In addition, the authors are grateful to the following collaborators for their help: Dr. Cristian Mihailescu (XPS analysis), Dr. Marius Dumitru (EDS elemental evaluation) and Dr. Oana Marinica (magnetic measurements).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Fleaca, C.T., Dumitrache, F., Sandu, I. et al. Laser pyrolysis synthesis of Sn–Fe–N@polycarbosilazane nanocomposites, characterization and evaluation as energy storage materials. Appl. Phys. A 123, 695 (2017). https://doi.org/10.1007/s00339-017-1300-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-017-1300-z