Abstract
Three-dimensional (3D) microstructures with micron scale are fabricated in photoresist using two-photon direct laser writing with an infrared femtosecond laser at 800 nm. The positive photoresist of Novolak/diazonaphthoquinone (DNQ) is used for the fabrication of line structures and 3D microstructures. Linewidths of line structures are fabricated with laser power ranging from 1 to 15 mW and scanning speeds ranging from 5 to 50 μm s−1. The obtained linewidth is analyzed using an exposure kinetics model of DNQ for two-photon absorption. Both 3D inversed woodpile structures and helical structures are fabricated.
Graphical abstract
Two-photon direct laser writing is used to fabricate microstructures in positive photoresist. Microstructures with helical and inversed woodpile shapes were fabricated with positive photoresist Novolak/DNQ using two-photon direct laser writing.
Similar content being viewed by others
References
S. Maruo, O. Nakamura, S. Kawata, Three-dimensional microfabrication with two-photon-absorbed photopolymerization. Opt. Lett. 22, 132–134 (1997)
M. Malinauskas, A. Žukauskas, S. Hasegawa, Y. Hayasaki, V. Mizeikis, R. Buividas, S. Juodkazis, Ultrafast laser processing of materials: from science to industry. Light Sci. Appl. 5, e16133 (2016)
T. Bückmann, M. Thiel, M. Kadic, R. Schittny, M. Wegener, An elasto-mechanical unfeelability cloak made of pentamode metamaterials. Nat. Commun. 5, 4130 (2014)
E. Yablonovitch, Inhibited spontaneous emission in solid-state physics and electronics. Phys. Rev. Lett. 58, 2059–2062 (1987)
E. Yablonovitch, K.M. Leung, Hope for photonic bandgap. Nature 351, 278 (1991)
H.-B. Sun, S. Matsuo, H. Misawa, Three-dimensional photonic crystal structures achieved with two-photon-absorption photopolymerization of resin. Appl. Phys. Lett. 74, 786–788 (1999)
K. Kaneko, H.B. Sun, X.M. Duan, S. Kawata, Submicron diamond-lattice photonic crystals produced by two-photon laser nanofabrication. Appl. Phys. Lett. 83, 2091–2093 (2003)
K.K. Seet, V. Mizeikis, S. Matsuo, S. Juodkazis, H. Misawa, Three-dimensional spiral-architecture photonic crystals obtained by direct laser writing. Adv. Mater. 17, 541–545 (2005)
M. Thiel, M. Decker, M. Deubel, M. Wegener, S. Linden, G. von Freymann, Polarization stop bands in chiral polymeric three-dimensional photonic crystals. Adv. Mater. 19, 207–210 (2007)
M. Thiel, M.S. Rill, G. von Freymann, M. Wegener, Three-dimensional bi-chiral photonic crystals. Adv. Mater. 21, 4680–4682 (2009)
M.S. Rill, C. Plet, M. Thiel, I. Staude, G. von Freymann, S. Linden, M. Wegener, Photonic metamaterials by direct laser writing and silver chemical vapour deposition. Nat. Mater. 7, 543–546 (2008)
J.K. Gansel, M. Thiel, M.S. Rill, M. Decker, K. Bade, V. Saile, G. von Freymann, S. Linden, M. Wegener, Gold helix photonic metamaterial as broadband circular polarizer. Science 325, 1513–1515 (2009)
Y. Yan, M.I. Rashad, E.J. Teo, H. Tanoto, J. Teng, A.A. Bettiol, Selective electroless silver plating of three dimensional SU-8 microstructures on silicon for metamaterials applications. Opt. Mater. Express 1, 1548–1554 (2011)
J. Moughames, S. Jradi, T.M. Chan, S. Akil, Y. Battie, A.E. Naciri, Z. Herro, S. Guenneau, S. Enoch, L. Joly, J. Cousin, A. Bruyant, Wavelength-scale light concentrator made by direct 3D laser writing of polymer metamaterials. Sci. Rep. 6, 33627 (2016)
G. Kenanakis, A. Xomalis, A. Selimis, M. Vamvakaki, M. Farsari, M. Kafesaki, C.M. Soukoulis, E.N. Economou, Three-dimensional infrared metamaterial with asymmetric transmission. ACS Photonics 2, 287–294 (2015)
S. Bagheri, K. Weber, T. Gissibl, T. Weiss, F. Neubrech, H. Giessen, Fabrication of square-centimeter plasmonic nanoantenna arrays by femtosecond direct laser writing lithography: effects of collective excitations on SEIRA enhancement. ACS Photonics 2, 779–786 (2015)
J. Kaschke, M. Wegener, Gold triple-helix mid-infrared metamaterial by STED-inspired laser lithography. Opt. Lett. 40(17), 3986–3989 (2015)
J. Kaschke, L. Blume, L. Wu, M. Thiel, K. Bade, Z. Yang, M. Wegener, A helical metamaterial for broadband circular polarization conversion. Adv. Opt. Mater. 3(10), 1411–1417 (2015)
P. Tayalia, C.R. Mendonca, T. Baldacchini, D.J. Mooney, E. Mazur, 3D cell-migration studies using two-photon engineered polymer scaffolds. Adv. Mater. 20, 4494–4498 (2008)
M. Röhrig, M. Thiel, M. Worgull, H. Hölscher, 3D direct laser writing of nano- and microstructured hierarchical gecko-mimicking surfaces. Small 8, 3009–3015 (2012)
J. Mačiulaitis, M. Deveikytė, S. Rekštytė, M. Bratchikov, A. Darinskas, A. Šimbelytė, G. Daunoras, A. Laurinavičienė, A. Laurinavičius, R. Gudas, Preclinical study of SZ2080 material 3D microstructured scaffolds for cartilage tissue engineering made by femtosecond direct laser writing lithography. Biofabrication 7, 015015 (2015)
A.M. Greiner, B. Richter, M. Bastmeyer, Micro-engineered 3D scaffolds for cell culture studies. Macromol. Biosci. 12, 1301–1314 (2012)
K.C. Hribar, K. Meggs, J. Liu, W. Zhu, X. Qu, S. Chen, Three-dimensional direct cell patterning in collagen hydrogels with near-infrared femtosecond laser. Sci. Rep. 5, 17203 (2015)
M. Mihailescu, I.A. Paun, M. Zamfirescu, C.R. Luculescu, A.M. Acasandrei, M. Dinescu, Laser-assisted fabrication and non-invasive imaging of 3D cell-seeding constructs for bone tissue engineering. J. Mater. Sci. 51, 4262–4273 (2016)
A. Marino, J. Barsotti, G. de Vito, C. Filippeschi, B. Mazzolai, V. Piazza, M. Labardi, V. Mattoli, G. Ciofani, Two-photon lithography of 3D nanocomposite piezoelectric scaffolds for cell stimulation. ACS Appl. Mater. Interfaces. 7(46), 25574–25579 (2015)
I.A. Paun, M. Zamfirescu, C.R. Luculescu, A.M. Acasandrei, C.C. Mustaciosu, M. Mihailescu, M. Dinescu, Electrically responsive microreservoires for controllable delivery of dexamethasone in bone tissue engineering. Appl. Surf. Sci. 392, 321–331 (2017)
S. Tottori, L. Zhang, F. Qiu, K.K. Krzysztof, A. Franco-Obregón, B.J. Nelson, Magnetic helical micromachines: fabrication, controlled swimming, and cargo transport. Adv. Mater. 24, 811–816 (2012)
S. Kim, F. Qiu, S. Kim, A. Ghanbari, C. Moon, L. Zhang, B.J. Nelson, H. Choi, Fabrication and characterization of magnetic microrobots for three-dimensional cell culture and targeted transportation. Adv. Mater. 25, 5863–5868 (2013)
R. Nakamura, K. Kinashi, W. Sakai, N. Tsutsumi, Fabrication of gold microstructures using negative photoresists doped with gold ions through two-photon excitation. Phys. Chem. Chem. Phys. 18, 17024–17028 (2016)
S. Rekštytė, T. Jonavičius, D. Gailevičius, M. Malinauskas, V. Mizeikis, E.G. Gamaly, S. Juodkazis, Nanoscale precision of 3D polymerization via polarization control. Adv. Opt. Mater. 4(8), 1209–1214 (2016)
H.-Z. Cao, M.-L. Zheng, X.-Z. Dong, F. Jin, Z.-S. Zhao, X.-M. Duan, Two-photon nanolithography of positive photoresist thin film with ultrafast laser direct writing. Appl. Phys. Lett. 102, 201108 (2013)
N.K. Urdabayev, V.V. Popik, Wolff rearrangement of 2-diazo-1(2H)-naphthalenone induced by nonresonant two-photon absorption of NIR radiation. J. Am. Chem. Soc. 126, 4058–4059 (2004)
A. Žukauskas, M. Malinauskas, G. Seniutinas, S. Juodkazis, Rapid laser optical printing in 3D at a nanoscale, in Multiphoton lithography: Techniques, Materials and Applications, ed. by J. Stampfl, R. Liska, A. Ovsianikov eds, (Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2016), Chap. 1
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tsutsumi, N., Fukuda, A., Nakamura, R. et al. Fabrication of three-dimensional microstructures in positive photoresist through two-photon direct laser writing. Appl. Phys. A 123, 553 (2017). https://doi.org/10.1007/s00339-017-1170-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-017-1170-4