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Molecular structure of [CpRu(PPh3)2(C6H11SH)]BF4·CH2Cl2

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Abstract

The structure of the [CpRu(PPh3)2(C6H11SH)]BF4·CH2Cl2 complex was determined by X-ray diffraction techniques; triclinic space group\(P\bar 1\),a=12.567(1),b=13.409(1),c=14.733(1) Å, α=95.380(7), β=111.041(7), γ=96.454(8)°,V=2278.5(4) Å3,Z=2,R=0.056,R w=0.088. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the S atom of the cyclohexylthiol. The Ru−S distance is 2.389(2) Å and the S−H distance is 1.23 Å.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Arkansas State University, State University, 72467, Arkansas

    Yanjing Jiang & M. Draganjac

  2. Department of Chemistry and Biochemistry, University of Arkansas, 72701, Fayetteville, Arkansas

    A. W. Cordes

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  1. Yanjing Jiang
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  2. M. Draganjac
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  3. A. W. Cordes
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Jiang, Y., Draganjac, M. & Cordes, A.W. Molecular structure of [CpRu(PPh3)2(C6H11SH)]BF4·CH2Cl2 . J Chem Crystallogr 25, 653–656 (1995). https://doi.org/10.1007/BF01665971

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