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Electrophilic heterocyclization of unsaturated amino compounds in the synthesis of nitrogen-containing heterocycles (review)

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The literature data on the electrophilic heterocyclization reactions of unsaturated amines, enamines, amidines, amides, and urethanes are correlated. The factors that affect the reactivities of unsaturated amino compounds in electrophilic intramolecular-cyclization reactions are discussed. The problems involved in the regioselectivity of the addition of electrophiles and the stereochemistry of the resulting products are examined, and kinetic data are presented.

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  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660, Kiev

    Yu. I. Gevaza & V. I. Staninets

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  1. Yu. I. Gevaza
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 435–449, April, 1985.

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Gevaza, Y.I., Staninets, V.I. Electrophilic heterocyclization of unsaturated amino compounds in the synthesis of nitrogen-containing heterocycles (review). Chem Heterocycl Compd 21, 359–371 (1985). https://doi.org/10.1007/BF00504390

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  • DOI: https://doi.org/10.1007/BF00504390

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