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Synthesis and properties of phenylenebis-1H-tetrazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Heterocyclization of m- and p-phenylenediamines with orthoformic ester and sodium azide has given phenylenebis-1H-tetrazoles. Under these conditions, o-phenylenediamine gives benzimidazole. o-, m-, and p-Phenylenebis-1H-tetrazoles were also obtained from the nitroanilines via the intermediate nitro- and aminophenyltetrazoles. The reactions of the bistetrazoles examined were basic hydrolysis, aminomethylation, and complex formation with copper salts.

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Authors and Affiliations

  1. Research Institute for Physicochemical Problems, V. I. Lenin Belorussian State University, 220080, Minsk

    P. N. Gaponik, V. P. Karavai, I. E. Davshko, M. M. Degtyarik & A. N. Bogatikov

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  1. P. N. Gaponik
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  2. V. P. Karavai
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  3. I. E. Davshko
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  4. M. M. Degtyarik
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  5. A. N. Bogatikov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1528–1532, November, 1990.

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Gaponik, P.N., Karavai, V.P., Davshko, I.E. et al. Synthesis and properties of phenylenebis-1H-tetrazoles. Chem Heterocycl Compd 26, 1274–1278 (1990). https://doi.org/10.1007/BF00476984

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  • DOI: https://doi.org/10.1007/BF00476984

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