Skip to main content
Log in

Identification of nerve agents and their homologues and dialkyl methylphosphonates by gas chromatography/fourier transform infrared spectrometry (GC-FTIR)

Part I: Spectral interpretation

  • Original Papers
  • Organic Analysis
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

GC-Direct deposition-FTIR spectra of 55 nerve agent homologues and dialkyl methylphosphonates were analysed. Spectral features of these compounds are discussed. A method is proposed for identification of the alkyl and alkoxy groups of compounds belonging to sarin, tabun or dialkyl methylphosphonates families.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Report of the Ad Hoc Committee on Chemical Weapons CD/1170, 26 August 1992

  2. Recommended Operating Procedures for Sampling and Analysis in the Verification of Chemical Disarmament (1993) Ministry for Foreign Affairs of Finland, Helsinki

  3. Franke S (1977) Lehrbuch der Militärchemie, Bd 1. Militärverlag der Deutschen Demokratischen Republik, Berlin

    Google Scholar 

  4. Haefner AM, Norton KL, Griffiths PR, Bourne S, Curbelo R (1988) Anal Chem 60:2441–2444

    Google Scholar 

  5. Bourne S, Haefner AM, Norton KL, Griffiths PR (1990) Anal Chem 62:2448–2452

    Google Scholar 

  6. Jackson P, Dent G, Carter D, Schofield DJ, Chalmers JM, Visser T, Vredenbregt M (1993) J High Res Chromatogr 16:515–521

    Google Scholar 

  7. Thomas LC, Chittenden RA (1964) Spectrochim Acta 20:467–487

    Google Scholar 

  8. Thomas LC, Chittenden RA (1964) Spectrochim Acta 20:489–502

    Google Scholar 

  9. Chittenden RA, Thomas LC (1964) Spectrochim Acta 20:1679–1696

    Google Scholar 

  10. Chittenden RA, Thomas LC (1965) Spectrochim Acta 21:861–876

    Google Scholar 

  11. Thomas LC, Chittenden RA (1965) Spectrochim Acta 21:1905–1914

    Google Scholar 

  12. Chittenden RA, Thomas LC (1966) Spectrochim Acta 22:1449–1463

    Google Scholar 

  13. Thomas LC, Chittenden RA (1970) Spectrochim Acta 26A:781–800

    Google Scholar 

  14. Bellamy LJ (1975) The infrared spectra of complex molecules, vol 1, 3rd edn. Chapman and Hall, London New York

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Söderström, M.T., Ketola, R.A. Identification of nerve agents and their homologues and dialkyl methylphosphonates by gas chromatography/fourier transform infrared spectrometry (GC-FTIR). Fresenius J Anal Chem 350, 162–167 (1994). https://doi.org/10.1007/BF00323181

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00323181

Keywords

Navigation