Abstract
Zinc and its alloy coatings have been used extensively for the cathodic protection of steel. Zinc coating corrodes in preference to the steel substrate due to its negative corrosion potential. Numerous studies have been conducted on the corrosion behavior of zinc and its alloy coatings deposited using several techniques viz., hot dip galvanizing, electrodeposition, metalizing or thermal spray etc. Cold spray is an emerging low temperature variant of thermal spray family which enables deposition of thick, dense, and pure coatings at a rapid rate with an added advantage of on-site coating of steel structures. In the present study, the corrosion characteristics of cold sprayed zinc coatings have been investigated for the first time. In addition, the influence of heat treatment of zinc coating at a temperature of 150 °C on its corrosion behavior has also been addressed.
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References
A.R. Marder, The Metallurgy of Zinc coated Steel, Prog. Mater. Sci., 2000, 45, p 191
F.M. Androsch, K. Kösters, and K.H. Stellnberger, Accelerated Corrosion Tests for Corrosion Protection Systems on Steel Sheet for the Automotive Industry, Stahl Eisen, 2000, 121, p 37
S.R. Lampman, T.B. Zorc, Ed., Properties and Selection of Non-Ferrous Alloys and Special Materials, 10th ed., ASM Handbook, Vol 2, 1998, p 1618
American Welding Society, “Corrosion Tests of Flame Sprayed Coated Steel 19 Year Report”, C2 14-79, 1974
S. Kuroda, J. Kawakita, and M. Takemoto, An 18-Year Exposure Test of Thermal-Sprayed Zn, Al, and Zn-Al Coatings in Marine Environment, Corrosion, 2006, 62(7), p 635
M. Mounga, P. Bercot, and J.Y. Rauch, Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions. Part I: Corrosion Layer Characterization, Corros. Sci., 2010, 52, p 3984
M. Mouanga and P. Bercot, Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions; Part II: Electrochemical Analyses, Corros. Sci., 2010, 52, p 3993
A.K. Neufeld, I.S. Cole, A.M. Bond, and S.A. Furman, The Initiation Mechanism of Corrosion of Zinc by Sodium Chloride Particle Deposition, Corros. Sci., 2002, 44, p 555
S. Bonk, M. Wicinski, A.W. Hassel, and M. Stratmann, Electrochemical Characterizations of Precipitates Formed on Zinc in Alkaline Sulphate Solution with Increasing pH Values, Electrochem. Commun., 2004, 6, p 800
G.A. El-Mahdy, A. Nishikata, and T. Tsuru, Electrochemical Corrosion Monitoring of Galvanized Steel Under Cyclic Wet-Dry Conditions, Corros. Sci., 2000, 42, p 183
Wiki Factbox, The Vital Statistics of Zinc, London CRU Group, Retrieved 3 March 2010
V. Barranco, S. Feliu, Jr., and S. Feliu, EIS Study of the Corrosion Behaviour of Zinc-Based Coatings on Steel in Quiescent 3% NaCl Solution. Part 1: Directly Exposed Coatings, Corros. Sci., 2004, 46, p 2203
F.M. Queiroz and I. Costa, Electrochemical, Chemical and Morphological Characterization of Galvannealed Steel Coating, Surf. Coat. Technol., 2007, 201, p 7024
R. Ramanauskas, P. Quintana, L. Maldonado, R. Pomés, and M.A. Pech-Canul, Corrosion Resistance and Microstructure of Electrodeposited Zn and Zn Alloy Coatings, Surf. Coat. Technol., 1997, 92, p 16
A.P. Yadav, A. Nishikata, and T. Tsuru, Degradation Mechanism of Galvanized Steel in Wet-Dry Cyclic Environment Containing Chloride Ions, Corros. Sci., 2004, 46, p 361
V. de Freitas Cunha Lins, G.F. de Andrade Reis, C.R. de Araujo, and T. Matencio, Electrochemical Impedance Spectroscopy and Linear Polarization Applied to Evaluation of Porosity of Phosphate Conversion Coatings on Electrogalvanized Steels, Appl. Surf. Sci., 2006, 253, p 2875
M. Hosseini, H. Ashassi-Sorkhabi, and H.A.Y. Ghiasvand, Corrosion Protection of Electro-Galvanized Steel by Green Conversion Coatings, J. Rare Earths, 2007, 25, p 537
D. Chaliampalias, G. Vourlias, N. Pistofidis, G. Stergioudis, and E.K. Polychroniadis, A Morphological and Microstructural Study of Flame-Sprayed Zinc Coatings on Low-Alloyed Steels as a Contribution to Explaining Their Corrosion Resistance, Phys. Status Solidi. (a), 2008, 205, p 1566
T. Kobayashi, T. Maruyama, and M. Kano, Characterization of Pure Aluminum and Zinc Sprayed Coatings produced by Flame Spraying, Mater. Trans., 2003, 44, p 2711
W. Zhao, Y. Wang, C. Liu, L. Dong, H. Yu, and H. Ai, Erosion-Corrosion of Thermally Sprayed Coatings in Simulated Splash Zone, Surf. Coat. Technol., 2010, 205, p 2267
E. Almeida, D. Pereira, and O. Figueiredo, The Degradation of Zinc Coatings in Salty Atmospheres, Prog. Org. Coat., 1989, 17, p 175
C.J. Li, W.-Y. Li, and H. Fukanuma, Impact Fusion Phenomenon During Cold Spraying of Zinc, Proceedings of the International Thermal Spray Conference, 2004, p 335
W.-Y. Li, C.-J. Li, and G.-J. Yang, Effect of Impact-Induced Melting on Interface Microstructure and Bonding of Cold-Sprayed Zinc Coating, Appl. Surf. Sci., 2010, 257, p 1516
A. Wank, B. Wielage, H. Podlesak, and T. Grund, High-Resolution Microstructural Investigations of Interfaces Between Light Metal Alloy Substrates and Cold Gas-Sprayed Coatings, J. Therm. Spray Technol., 2006, 15, p 280
B. Wielage, T. Grund, S. Ahrens, A. Wank, and F. Trommer, Cold Gas Sprayed Filler Coatings for Brazing of Light Alloys, Surf. Eng., 2006, 22, p 98
J.G. Legoux, E. Irissou, and C. Moreau, Effect of Substrate Temperature on the Formation Mechanism of Cold-Sprayed Aluminum, Zinc and Tin Coatings, J. Therm. Spray Technol., 2007, 16, p 619
H. Koivuluoto, J. Lagerbom, M. Kylmalahti, and P. Vuoristo, Microstructure and Mechanical Properties of Low-Pressure Cold-Sprayed (LPCS) Coatings, J. Therm. Spray Technol., 2008, 17, p 721
P. Sudharshan Phani, D. Srinivasa Rao, S.V. Joshi, and G. Sundararajan, Effect of Process Parameters and Heat Treatments on Properties of Cold Sprayed Copper Coatings, J. Therm. Spray Technol., 2007, 16, p 425
P. Sudharshan Phani, V. Vishnukanthan, and G. Sundararajan, Effect of Heat Treatment on Properties of Cold Sprayed Nanocrystalline Copper Alumina Coatings, Acta Mater., 2007, 55, p 4741-4751
H.-R. Wang, B.-R. Hou, J. Wang, Q. Wang, and W.-Y. Li, Effect of Process Conditions on Microstructure and Corrosion Resistance of Cold-Sprayed Ti Coatings, J. Therm. Spray Technol., 2008, 17, p 736
L. Ajdelsztajn, B. Jodoin, and J.M. Schoenung, Synthesis and Mechanical Properties of Nanocrystalline Ni Coatings Produced by Cold Gas Dynamic Spraying, Surf. Coat. Technol., 2006, 201, p 1166
R.S. Lima, J. Karthikeyan, C.M. Kay, J. Lindemann, and C.C. Berndt, Microstructural Characteristics of Cold-Sprayed Nanostructured WC-Co Coatings, Thin Solid Films, 2002, 416, p 129
L. Ajdelsztajn, B. Jodoin, G.E. Kim, and J.M. Schoenung, Cold Spray Deposition of Nanocrystalline Aluminum Alloys, Metall. Mater. Trans. A, 2005, 36, p 657
H.Y. Lee, Y.H. Yu, Y.C. Lee, Y.P. Hong, and K.H. Ko, Cold Spray of SiC and Al2O3 with Soft Metal Incorporation: A Technical Contribution, J. Therm. Spray Technol., 2004, 13, p 184
H. Koivuluoto, J. Nakki, and P. Vuoristo, Corrosion Properties of Cold-Sprayed Tantalum Coatings, J. Therm. Spray Technol., 2009, 18, p 75
K. Balani, T. Laha, A. Agarwal, J. Karthikeyan, and N. Munroe, Effect of Carrier Gases on Microstructural and Electrochemical Behavior of Cold-Sprayed 1100 Aluminum Coatings, Surf. Coat. Technol., 2005, 195, p 272
N. Bala, H. Singh, and S. Prakash, Accelerated Hot Corrosion Studies of Cold Spray Ni-50Cr Coating on Boiler Steels, Mater. Des., 2010, 31, p 244
H.-R. Wang, W.-Y. Li, L. Ma, J. Wang, and Q. Wang, Corrosion Behavior of Cold Sprayed Titanium Protective Coating on 1Cr13 Substrate in Seawater, Surf. Coat. Technol., 2007, 201, p 5203
G. Sundararajan, P. Sudharshan Phani, A. Jyothirmayi, and R.C. Gundakaram, The Influence of Heat Treatment on the Microstructural, Mechanical and Corrosion Behaviour of Cold Sprayed SS 316L Coatings, J. Mater. Sci., 2009, 44, p 2320
G. Sundararajan, N.M. Chavan, G. Sivakumar, and P. Sudharshan Phani, Evaluation of Parameters for Assessment of Inter-Splat Bond Strength in Cold Sprayed Coatings, J. Therm. Spray Technol., 2010, 19, p 1255
N.M. Chavan, M. Ramakrishna, P. Sudharshan Phani, D. Srinivasa Rao, and G. Sundararajan, The Influence of Process Parameters and Heat Treatment on the Properties of Cold Sprayed Silver Coatings, Surf. Coat. Technol., 2011, 205, p 4798
W.Y. Li, C.-J. Li, and H. Liao, Effect of Annealing Treatment on the Microstructure and Properties of Cold-Sprayed Cu Coating, J. Therm. Spray Technol., 2006, 15, p 206
A. Jyothirmayi, “Corrosion Behaviour of Zinc Coatings”, Unpublished work, ARCI, Hyderabad, India, 2011
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One of the authors would like to thank Mr. Nitin P. Wasekar for helpful discussions, Mr. G.V. Reddy and Mr. K. Ramesh Reddy for X-ray diffraction and SEM analyses.
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Chavan, N.M., Kiran, B., Jyothirmayi, A. et al. The Corrosion Behavior of Cold Sprayed Zinc Coatings on Mild Steel Substrate. J Therm Spray Tech 22, 463–470 (2013). https://doi.org/10.1007/s11666-013-9893-z
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DOI: https://doi.org/10.1007/s11666-013-9893-z