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Unusual crystal and molecular structure of palladium iminoquinonoid complex Pd2Cl2(PPh3)2L (L = N,N′-di(4-methyl-4-trichloromethylcyclohexa-2,5-dien-1-ylidene)hydrazine)

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Abstract

The structure of the first iminoquinonoid complex Pd2Cl2(PPh3)2L·0.4(Me2CO), where L = N,N′-di(4-methyl-4-trichloromethylcyclohexa-2,5-dien-1-ylidene)hydrazine, was established by X-ray crystallography. The centrosymmetric and non-centrosymmetric molecules of meso-form (RS) and the molecule of optically active (SS) threo-form were found to be simultaneously present (cocrystallize) in the crystal. The molecule in the crystal has a general formula [Pd(meso-L)]2[Pd(threo-L)].

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References

  1. T. M. Zapol’skikh, T. V. Artyomova, S. B. Khrebtova, P. V. Petrovskii, Z. A. Starikova, V. A. Nikanorov, in Third Youth School-Conference on Organic Synthesis (June 24–27, 2002, Saint-Petersburg, Russia): Organic Synthesis in the New Century (YSCOS-3), Saint-Petersburg, 2002, 294.

    Google Scholar 

  2. Programs APEX II, Version 2.0-1; SAINT, Version 7.23A; SADABS, Version 2004/1; XPREP, Version 2005/2.

  3. G. M. Sheldrick, Acta Crystallogr., Sect. A, 2008, 64, 112.

    Article  CAS  Google Scholar 

  4. Structure Correlation, Eds H.-B. Burge, J. D. Dunits, VCH, Weinheim-New York, 1994, 2, 767.

    Google Scholar 

  5. R. Bosque, C. Lopez, J. Sales, X. Solans, J. Silver, J. Chem. Soc., Dalton Trans., 1996, 3195.

    Google Scholar 

  6. K. Molcanov, M. Curic, D. Babic, B. Kojic-Prodic, J. Organomet. Chem., 2007, 692, 3874.

    Article  CAS  Google Scholar 

  7. D. Babic, M. Curic, K. Molcanov, G. Ilc, J. Plavec, Inorg. Chem., 2008, 47, 10446.

    Article  CAS  Google Scholar 

  8. M. Curic, D. Babic, A. Visnjevac, K. Molcanov, Inorg. Chem., 2005, 44, 5975.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Z. A. Starikova

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  1. Z. A. Starikova
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Correspondence to Z. A. Starikova.

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Dedicated to the memory of the Corresponding Member of the Russian Academy of Sciences Mikhail Yuvenal’evich Antipin (1951–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1866–1870, August, 2013.

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Starikova, Z.A. Unusual crystal and molecular structure of palladium iminoquinonoid complex Pd2Cl2(PPh3)2L (L = N,N′-di(4-methyl-4-trichloromethylcyclohexa-2,5-dien-1-ylidene)hydrazine). Russ Chem Bull 62, 1866–1870 (2013). https://doi.org/10.1007/s11172-013-0268-x

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  • DOI: https://doi.org/10.1007/s11172-013-0268-x

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