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Palladium Complexes [Ph3PCH2CN]2[PdBr4], [Ph4P]2[PdBr4], [Ph3PC5H9-cyclo][PdBr3(Et2SO)], and [Ph4P]2[Pd2Br6]. Synthesis and Structure

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Abstract

Palladium phosphonium complexes with mononuclear anions [Ph3PCH2CN][PdBr4], [Ph4P][PdBr4], and [Ph3PC5H9-cyclo][PdBr3(Et2SO)] were synthesized by the reaction of organyltriphenylphosphonium bromides with palladium(II) bromide in the presence of hydrobromic acid followed by recrystallization from acetonitrile, dimethyl sulfoxide, or diethyl sulfoxide. Holding the [Ph4P][PdBr4] complex in acetonitrile with the addition of diamyl sulfoxide led to the formation of the [Ph4P]2[Pd2Br6] complex. According to single crystal X-ray diffraction analysis, mononuclear [PdBr4]2–, [PdBr3(Et2SO)]– and binuclear [Pd2Br6]2– anions in the complexes have a planar structure.

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

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  1. V. V. Sharutin
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Sharutin, V.V., Sharutina, O.K. & Senchurin, V.S. Palladium Complexes [Ph3PCH2CN]2[PdBr4], [Ph4P]2[PdBr4], [Ph3PC5H9-cyclo][PdBr3(Et2SO)], and [Ph4P]2[Pd2Br6]. Synthesis and Structure. Russ J Gen Chem 92, 1309–1316 (2022). https://doi.org/10.1134/S1070363222070209

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