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Conversion of biological substrates to fuel components in the presence of industrial catalysts

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Abstract

Conditions were found under which the industrial aluminum-platinum catalyst AP-64 and the pilot zeolite system Pd-Zn/Al2O3/MFI (MFI is a high-silica ZSM-5 type zeolite) catalyze single-stage highly selective conversion of rapeseed oil and ethanol to either alkane or alkanearomatic fraction of hydrocarbons suitable as engine fuel components. The hydrocarbon chain grows with participation of ethylene, which is formed in the argon medium directly from the ethanol molecule. Under these conditions, hydrogenation of this alkene on intermetallic clusters arising during the long-term reductive preactivation is suppressed. The alcohol supplies not only ethylene but also hydrogen. In the presence of Pd-Zn/Al2O3/MFI, ethanol is converted to alkanes and aromatic hydrocarbons according to independent pathways. Joint processing of alcohols and rapeseed oil in the presence of the Pd-Zn/Al2O3/MFI catalyst system is an efficient and promising route to C3-C11 hydrocarbons in the absence of an external source of hydrogen.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    M. V. Tsodikov, A. V. Chistyakov, M. A. Gubanov & S. N. Khadzhiev

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. E. Gekhman & I. I. Moiseev

Authors
  1. M. V. Tsodikov
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  2. A. V. Chistyakov
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  3. M. A. Gubanov
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  4. S. N. Khadzhiev
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  5. A. E. Gekhman
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  6. I. I. Moiseev
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Corresponding author

Correspondence to A. V. Chistyakov.

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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0819–0828, March, 2013.

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Tsodikov, M.V., Chistyakov, A.V., Gubanov, M.A. et al. Conversion of biological substrates to fuel components in the presence of industrial catalysts. Russ Chem Bull 62, 820–829 (2013). https://doi.org/10.1007/s11172-013-0111-4

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  • DOI: https://doi.org/10.1007/s11172-013-0111-4

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