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Dinuclear chelates of acyclic and cyclic tridentate Schiff bases derived from sterically hindered o-aminophenols. A new type of reactivity of tridentate ligands under electrosynthesis conditions

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Abstract

The chemical and electrochemical synthesis of cobalt(II), nickel(II), and copper(II) complexes based on sterically hindered tridentate Schiff bases obtained by the coupling of 2-amino-4,6-di-tert-butylphenol with salicylaldehyde derivatives (H2L, H2L’) was performed. The resulting dinuclear complexes were characterized by elemental analysis, IR spectroscopy, and magnetochemical measurements in the 300–2 K temperature range. The structures of the dinuclear nickel(II) and copper(II) complexes with the composition Ni2L2·2AcOH·2MeOH and Cu2L2, respectively, were established by X-ray diffraction. The copper chelates are characterized by the presence of antiferromagnetic exchange interactions. The mononuclear copper(II) complexes (DMSO)bis[2-(5,7-di-tert-butyl-4-hydroxybenzoxazol-2-yl)phenolato]copper(II) and (DMF)2bis[2-(5,7-di-tert-butyl-4-hydroxybenzoxazol-2-yl)phenolato]copper(II) were isolated upon electrochemical dissolution of copper(0) and were structurally characterized.

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Authors and Affiliations

  1. Pedagogical Institute of Southern Federal University, 35 ul. B. Sadovaya, 344010, Rostov-on-Don, Russian Federation

    T. O. Shmakova & I. E. Uflyand

  2. Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    D. A. Garnovskii, E. P. Ivakhnenko, V. V. Krasnikov, I. S. Vasil’chenko, A. I. Uraev, A. S. Burlov, E. V. Sennikova & A. D. Garnovskii

  3. Southern Scientific Center, Russian Academy of Sciences, 41 prosp. Chekhova, 344006, Rostov-on-Don, Russian Federation

    D. A. Garnovskii

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko & M. Yu. Antipin

  5. Department of Chemistry, Southern Federal University, 7 ul. Zorge, 344090, Rostov-on-Don, Russian Federation

    V. I. Simakov

  6. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

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  1. T. O. Shmakova
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  2. D. A. Garnovskii
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  3. K. A. Lyssenko
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  4. E. P. Ivakhnenko
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  5. V. V. Krasnikov
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  6. V. I. Simakov
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  7. I. S. Vasil’chenko
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  8. A. I. Uraev
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  9. A. S. Burlov
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  10. E. V. Sennikova
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  11. A. S. Bogomyakov
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  12. M. Yu. Antipin
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  13. A. D. Garnovskii
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  14. I. E. Uflyand
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Corresponding author

Correspondence to D. A. Garnovskii.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1344–1352, July, 2009.

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Shmakova, T.O., Garnovskii, D.A., Lyssenko, K.A. et al. Dinuclear chelates of acyclic and cyclic tridentate Schiff bases derived from sterically hindered o-aminophenols. A new type of reactivity of tridentate ligands under electrosynthesis conditions. Russ Chem Bull 58, 1383–1391 (2009). https://doi.org/10.1007/s11172-009-0184-2

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  • DOI: https://doi.org/10.1007/s11172-009-0184-2

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