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Whiteness process of tile ceramics: using a synthetic flow as a modifier agent of color firing

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Abstract

Synthetic flow is proposed as a modifier agent of color firing in tile ceramic mass during the sinterization process, turning the red color firing into whiteness. Therefore, the 57Fe Mössbauer spectroscopy was used to understand how the interaction of the iron element in the mechanism of color firing mass occurs in this system. The results suggest that the change of color firing can be alternatively due to two main factors: (i) diluting the hematite content in the sample because of the use of synthetic flow and (ii) part of the hematite is converted in other uncolored crystal structures, which makes the final color firing lighter.

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References

  1. Anfacer.: Setor.www.anfacer.org.br (2012). Acessed 31 Oct 2012

  2. Junior, M.C., et al.: Panorama e Perspectivas da Indústria de Revestimentos Cerâmicos no Brasil. Ceram. Ind. 15(3), 7–18 (2010)

    Google Scholar 

  3. Motta, J.F.M., Zanardo, A., Junior, M.C.: As Matérias-Primas Cerâmicas. Parte I: O Perfil das Principais Indústrias Cerâmicas e Seus Produtos. Ceram. Ind. 6(2), 28–39 (2001)

    Google Scholar 

  4. Yatsenko, N., et al.: Regularities of tinting ceramics based on low-melting clays. Glass Ceram. 63(7), 265–266 (2006)

    Article  Google Scholar 

  5. Santos, G.R., Salvetti, A.R., Morelli, M.R.: Estudo de um aditivo descolorante de massas para revestimentos cerâmicos. Anais 54° Congresso Brasileiro de Cerâmica: Foz do Iguaçu—PR (2010)

  6. Santos, G.R., et al.: Composições de vidro soda-cal com massas cerâmicas vermelhas, processo de obtenção de artefatos cerâmicos, artefatos cerâmicos assim obtidos e uso dos mesmos. INPI. PI1102416-0 (2011)

  7. Zanotto, E.D.: Crystallization of liquids and glasses. Braz. J. Phys. 22(2), 77–84 (1992)

    Google Scholar 

  8. Barbieri, L., et al.: Crystallization of (Na2O–MgO)–CaO–Al2O3–SiO2 glassy systems formulated from waste products. J. Am. Ceram. Soc. 83(10), 2515–2520 (2000)

    Article  Google Scholar 

  9. Saiello, S., et al.: Crystallization of glasses in the 2 Na2O.CaO.3SiO2 -Na2O.2CaO.3SiO2 Composition Range. Thermochim. Acta 52(1–3), 263–269 (1982)

    Article  Google Scholar 

  10. Poirier, T., et al.: Formation of crystalline phases in (SiO2-CaO-Fe2O3)-TiO2 based glasses. Mater. Lett. 59(2–3), 308–312 (2005)

    Article  Google Scholar 

  11. Navarro, J.M.F.: El vidro. CSIC, España (2003)

  12. Matteucci, F., Dondi, M., Guarini, G.: Effect of soda-lime glass on sintering and technological properties of porcelain stoneware tiles. Ceram. Int.28(8), 873–880 (2002)

    Article  Google Scholar 

  13. Martín-Márquez, J., Rincón, J.M., Romero, M.: Effect of microstructure on mechanical properties of porcelain stoneware. J. Eur. Ceram. Soc. 30(15), 3063–3069 (2010)

    Article  Google Scholar 

  14. Suvaci, E., Tamsu, N.: The role of viscosity on microstructure development and stain resistance in porcelain stoneware tiles. J. Eur. Ceram. Soc. 30(15), 3071–3077 (2010)

    Article  Google Scholar 

  15. Martín-Márquez, J., Rincón, J.M., Romero, M.: Effect of firing temperature on sintering of porcelain stoneware tiles. Ceram. Int. 34(8), 1867–1873 (2008)

    Article  Google Scholar 

  16. Rambaldi, E., et al.: Using waste glass as a partial flux substitution and pyroplastic deformation of a porcelain stoneware tile body. Ceram. Int. 33(5), 727–733 (2007)

    Article  Google Scholar 

  17. Zanelli, C., et al.: Glass-ceramic frits for porcelain stoneware bodies: effects on sintering, phase composition and technological properties. Ceram. Int. 34(3), 455–465 (2008)

    Article  Google Scholar 

  18. Luz, A.P., Ribeiro, S.: Use of glass waste as a raw material in porcelain stoneware tile mixtures. Ceram. Int. 33(5), 761–765 (2007)

    Article  Google Scholar 

  19. Tucci, A., et al.: Use of soda-lime scrap-glass as a fluxing agent in a porcelain stoneware tile mix. J. Eur. Ceram. Soc. 24(1), 83–92 (2004)

    Article  MathSciNet  Google Scholar 

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Correspondence to G. R. dos Santos.

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Proceedings of the Thirteenth Latin American Conference on the Applications of the Mössbauer Effect, (LACAME 2012), Medellín, Columbia, 11–16 Novermber 2012.

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dos Santos, G.R., Pereira, M.C., Olzon-Dionysio, M. et al. Whiteness process of tile ceramics: using a synthetic flow as a modifier agent of color firing. Hyperfine Interact 224, 137–142 (2014). https://doi.org/10.1007/s10751-013-0859-9

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  • DOI: https://doi.org/10.1007/s10751-013-0859-9

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