Encyclopedia of Astrobiology

Living Edition
| Editors: Muriel Gargaud, William M. Irvine, Ricardo Amils, Henderson James Cleaves, Daniele Pinti, José Cernicharo Quintanilla, Michel Viso

Formaldehyde

  • Henderson James (Jim) CleavesIIEmail author
Living reference work entry
DOI: https://doi.org/10.1007/978-3-642-27833-4_585-3

Synonyms

Definition

Formaldehyde (methanal, HCHO), the simplest aldehyde, is a one carbon molecule intermediary along the redox continuum between CO2 and CH4, at the same oxidation state (0) as graphite. Formaldehyde was first reported by the Russian chemist Butlerow in 1860 and was conclusively identified by von Hofmann. It exists transiently but prominently in the abiological carbon cycle (Cleaves 2008). It is an abundant interstellar molecule and is a constituent of cometary ices (Biver et al. 2002). It is readily produced in prebiotic simulation experiments from a variety of gas mixtures and energy sources.

HCHO may have played an important role in the synthesis of organic molecules relevant to the origin of life. HCHO is likely a significant precursor for the prebiotic synthesis of glycine and other amino acids (Miller 1957). HCHO can react to form sugars under basic conditions (Butlerow 1861) via the so-called formose...

Keywords

Formose Prebiotic chemistry Strecker synthesis 
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References and Further Reading

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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  1. 1.Geophysical LaboratoryCarnegie Institution of WashingtonWashingtonUSA