Atomic Symbol: V
Atomic Number: 23
Atomic Weight: 50.9415 g/mol
Isotopes and Abundances: 50V 0.25 %, 51V 99.75 %
1 Atm Melting Point: 1910 °C
1 Atm Boiling Point: 3407 °C
Common Valences: 5+, 4+, 3+, 2+
Ionic Radii: 64 pm (in 3+, 6-fold coordination)
Pauling Electronegativity: 1.63
First Ionization Energy: 6.74 eV
Chondritic (CI) Abundance: 54.6 ppma
Silicate Earth Abundance: 86 ppma
Crustal Abundance: 138 ppmb
Seawater Abundance: ~30–37 nmol/kgc
Core Abundance: ~150 ppmd
aPalme et al. (2014)
bRudnick and Gao (2014)
cBruland et al. (2014)
dMcDonough (2014)
Properties
Vanadium (chemical symbol, V) is a d-block transition metal, silver in color, appearing in the first long period of the periodic table between titanium and chromium. Vanadium has two stable isotopes: 50V and 51V, with atomic abundance of 0.25 % and 99.75 %, respectively. Vanadium has several oxidation forms (between 2+ and 5+). In the lithosphere, V occurs as reducing V(III) form, whereas in...
References
Bruland, K. W., Middag, R., and Lohan, M. C., 2014. 8.2 – controls of trace metals in seawater. In Holland, H. D., and Turekian, K. K. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 19–51.
Chatterjee, M., 2009. Vanadium. In Schwab, M. (ed.), Encyclopedia of Cancer. Berlin/Heidelberg: Springer, pp. 3140–3142.
Gaillardet, J., Viers, J., and Dupré, B., 2014. 7.7 – trace elements in river waters. In Holland, H. D., and Turekian, K. K. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 195–235.
Haynes, W. M., 2015. CRC Handbook of Chemistry and Physics, 96th edn. Boca Raton: CRC Press.
Hope, B. K., 2008. A dynamic model for the global cycling of anthropogenic vanadium. Global Biogeochemical Cycles, 22, GB4021.
Huang, J.-H., Huang, F., Evans, L., and Glasauer, S., 2015. Vanadium: global (bio)geochemistry. Chemical Geology, 417, 68–89.
Imtiaz, M., Rizwan, M. S., Xiong, S., Li, H., Ashraf, M., Shahzad, S. M., Shahzad, M., Rizwan, M., and Tu, S., 2015. Vanadium, recent advancements and research prospects: a review. Environmental International, 80, 79–88.
Mallmann, G., and O’Neill, H. S. C., 2009. The crystal/melt partitioning of V during mantle melting as a function of oxygen fugacity compared with some other elements (Al, P, Ca, Sc, Ti, Cr, Fe, Ga, Y, Zr and Nb). Journal of Petrology, 50, 1765–1794.
McDonough, W. F., 2014. 3.16 – compositional model for the Earth’s core. In Holland, H. D., and Turekian, K. K. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 559–577.
Moskalyk, R. R., and Alfantazi, A. M., 2003. Processing of vanadium: a review. Minerals Engineering, 16, 793–805.
Mukherjee, B., Patra, B., Mahapatra, S., Banerjee, P., Tiwari, A., and Chatterjee, M., 2004. Vanadium – an element of atypical biological significance. Toxicology Letters, 150, 135–143.
Palme, H., Lodders, K., and Jones, A., 2014. 2.2 – solar system abundances of the elements. In Holland, H. D., and Turekian, K. K. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 15–36.
Pourret, O., Dia, A., Gruau, G., Davranche, M., and Bouhnik-Le, C. M., 2012. Assessment of vanadium distribution in shallow groundwaters. Chemical Geology, 294, 89–102.
Rehder, D., 2008. Bioinorganic Vanadium Chemistry. Chichester: Wiley, 213 pp.
Richards, R. L., 2006. Vanadium: inorganic & coordination chemistry. In Encyclopedia of Inorganic Chemistry. Chichester: Wiley.
Rudnick, R. L., and Gao, S., 2014. 4.1 – composition of the continental crust. In Turekian, H. D., and Holland, K. K. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 1–51.
Wood, B. J., Walter, M. J., and Wade, J., 2006. Accretion of the Earth and segregation of its core. Nature, 441, 825–833.
Wu, F., Qin, T., Li, X., Liu, Y., Huang, J.-H., Wu, Z., and Huang, F., 2015. First-principles investigation of vanadium isotope fractionation in solution and during adsorption. Earth and Planetary Science Letters, 426, 216–224.
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Pourret, O., Dia, A. (2016). Vanadium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_272-1
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DOI: https://doi.org/10.1007/978-3-319-39193-9_272-1
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