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Nanobiochar-Based Formulations for Sustained Release of Agrochemicals in Precision Agriculture Practices

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Handbook of Green and Sustainable Nanotechnology

Abstract

The modern agricultural practices intensively use agrochemicals to increase crop yield resulting into hike in cost of farming. Fertilizers are one of the major agrochemicals used to boost crop yield. However, a significant amount of applied chemical fertilizers in the fields is lost due to various abiotic and biotic factors including photolysis, volatilization, leaching, hydrolysis and microbial immobilization. These factors reduce the nutrient use efficiency (NUE) and increase the frequency of fertilizer application. Current agricultural practices are ineffective at concurrently boosting nutrient use efficiency and agriculture productivity. The losses of fertilizers at ground level may be minimized by controlling the nutrient release kinetics through anchoring the nutrient with an appropriate porous carrier material.

Slow-release fertilizers (SRFs) smartly deliver nutrients to the plants at a relatively slow rate for better synchronization of nutrient requirements during plant growth with minimal harm to the environment. Nanobiochar (N-BC)-based slow-release fertilizer is an effective, economic, robust, and environment friendly approach to improve nutrient use efficiency (NUE) of plant. Neat N-BC has also been used as a carrier for targeted delivery of agrochemicals in a few studies; the same opens a research opportunity to be taken up in the offing. Hence, N-BC can play a vital role in sustainable agriculture practices. This chapter gives an overview of synthesis, characteristics and characterization of biochar-based nanoformulation for agricultural applications including sustained release of agrochemicals. Aspects such as the effect of biochar-based nanoformulation on soil health (heavy metal and agrochemicals immobilization), plant growth and yield improvement have been included in the discussion.

Future studies may focus on the development of novel, efficient, economical, robust, viable, and eco-friendly smart N-BC based fertilizers.

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References

  • Cao L, Iris K, Cho D-W, Wang D, Tsang DC, Zhang S, Ding S, Wang L, Ok YS (2019) Microwave-assisted low-temperature hydrothermal treatment of red seaweed (Gracilaria lemaneiformis) for production of levulinic acid and algae hydrochar. Bioresour Technol 273:251–258

    Article  CAS  Google Scholar 

  • Chausali N, Saxena J, Prasad R (2021) Nanobiochar and biochar based nanocomposites: advances and applications. J Agri Food Res 5:100191

    CAS  Google Scholar 

  • Chen M, Alim N, Zhang Y, Xu N, Cao X (2018) Contrasting effects of biochar nanoparticles on the retention and transport of phosphorus in acidic and alkaline soils. Environ Pollut 239:562–570

    Article  CAS  Google Scholar 

  • Chen X, Zhou B, Wang Q, Tao W, Lin H (2020) Nano-biochar reduced soil erosion and nitrate loss in sloping fields on the Loess Plateau of China. Catena 187:104346

    Article  CAS  Google Scholar 

  • Chen X, Duan M, Zhou B, Cui L (2022) Effects of biochar nanoparticles as a soil amendment on the structure and hydraulic characteristics of a sandy loam soil. Soil Use Manag 38:836–849

    Article  Google Scholar 

  • Costa MM, Cabral-Albuquerque EC, Alves TL, Pinto JC, Fialho RL (2013) Use of polyhydroxybutyrate and ethyl cellulose for coating of urea granules. J Agric Food Chem 61:9984–9991

    Article  CAS  Google Scholar 

  • Das SK, Ghosh GK (2021) Development and evaluation of biochar-based secondary and micronutrient enriched slow release nano-fertilizer for reduced nutrient losses. Biomass Conv Bioref:1–12. https://doi.org/10.1007/s13399-021-01880-5

  • Dong X, He L, Liu Y, Piao Y (2018) Preparation of highly conductive biochar nanoparticles for rapid and sensitive detection of 17β-estradiol in water. Electrochim Acta 292:55–62

    Article  CAS  Google Scholar 

  • Evy Alice Abigail M (2019) Biochar-based nanocarriers: fabrication, characterization, and application as 2, 4-dichlorophenoxyacetic acid nanoformulation for sustained release. 3 Biotech 9:1–9

    Article  Google Scholar 

  • Feng Y, Lu H, Liu Y, Xue L, Dionysiou DD, Yang L, Xing B (2017) Nano-cerium oxide functionalized biochar for phosphate retention: preparation, optimization and rice paddy application. Chemosphere 185:816–825

    Article  CAS  Google Scholar 

  • Ghassemi-Golezani K, Farhangi-Abriz S (2021) Biochar-based metal oxide nanocomposites of magnesium and manganese improved root development and productivity of safflower (Carthamus tinctorius L.) under salt stress. Rhizosphere 19:100416

    Article  Google Scholar 

  • Green JM, Beestman GB (2007) Recently patented and commercialized formulation and adjuvant technology. Crop Prot 26:320–327

    Article  CAS  Google Scholar 

  • Guo F, Bao L, Wang H, Larson SL, Ballard JH, Knotek-Smith HM, Zhang Q, Su Y, Wang X, Han F (2020) A simple method for the synthesis of biochar nanodots using hydrothermal reactor. MethodsX 7:101022

    Article  CAS  Google Scholar 

  • Hamadeen HM, Elkhatib EA (2022) Nanostructured modified biochar for effective elimination of chlorpyrifos from wastewater: enhancement, mechanisms and performance. J Water Proc Eng 47:102703

    Article  Google Scholar 

  • Hernandez-Soriano MC, Kerré B, Kopittke PM, Horemans B, Smolders E (2016) Biochar affects carbon composition and stability in soil: a combined spectroscopy-microscopy study. Sci Rep 6:1–13

    Article  Google Scholar 

  • Hiloidhari M, Das D, Baruah D (2014) Bioenergy potential from crop residue biomass in India. Renew Sust Energ Rev 32:504–512

    Article  Google Scholar 

  • Huang X, Zhu S, Zhang H, Huang Y, Wang X, Wang Y, Chen D (2021) Biochar nanoparticles induced distinct biological effects on freshwater algae via oxidative stress, membrane damage, and nutrient depletion. ACS Sustain Chem Eng 9:10761–10770

    Article  CAS  Google Scholar 

  • Igalavithana AD, Mandal S, Niazi NK, Vithanage M, Parikh SJ, Mukome FN, Rizwan M, Oleszczuk P, Al-Wabel M, Bolan N (2017) Advances and future directions of biochar characterization methods and applications. Crit Rev Environ Sci Technol 47:2275–2330

    Article  CAS  Google Scholar 

  • Jampilek J, Kos J, Kralova K (2019) Potential of nanomaterial applications in dietary supplements and foods for special medical purposes. Nanomaterials 9:296

    Article  CAS  Google Scholar 

  • Jenie SA, Kristiani A, Kustomo Simanungkalit S, Mansur D (2017) Preparation of nanobiochar as magnetic solid acid catalyst by pyrolysis-carbonization from oil palm empty fruit bunches. AIP conference proceedings, AIP Publishing LLC, 020018

    Google Scholar 

  • Jia D, Liu M, Xia J, Li C (2020) Effective removal of aqueous glyphosate using CuFe2O4@ biochar derived from phragmites. J Chem Technol Biotechnol 95:196–204

    Article  CAS  Google Scholar 

  • Jiang C, Bo J, Xiao X, Zhang S, Wang Z, Yan G, Wu Y, Wong C, He H (2020) Converting waste lignin into nano-biochar as a renewable substitute of carbon black for reinforcing styrene-butadiene rubber. Waste Manag 102:732–742

    Article  CAS  Google Scholar 

  • Joseph S, Anawar HM, Storer P, Blackwell P, Chee CHIA, Yun LIN, … Solaiman ZM (2015) Effects of enriched biochars containing magnetic iron nanoparticles on mycorrhizal colonisation, plant growth, nutrient uptake and soil quality improvement. Pedosphere 25(5):749–760

    Google Scholar 

  • Kah M, Kookana RS, Gogos A, Bucheli TD (2018) A critical evaluation of nanopesticides and nanofertilizers against their conventional analogues. Nat Nanotechnol 13:677–684

    Article  CAS  Google Scholar 

  • Kalia A, Sharma SP, Kaur H, Kaur H (2020) Novel nanocomposite-based controlled-release fertilizer and pesticide formulations: prospects and challenges. In: Multi hybrid nanomaterials for sustainable agri-food and ecosystems. pp 99–134, Editor: Kamel A. Abd-Elsalam, Publisher: Elsevier, Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands

    Google Scholar 

  • Khan HA, Naqvi SR, Mehran MT, Khoja AH, Niazi MBK, Juchelková D, Atabani A (2021) A performance evaluation study of nano-biochar as a potential slow-release nano-fertilizer from wheat straw residue for sustainable agriculture. Chemosphere 285:131382

    Article  CAS  Google Scholar 

  • Khare P (2021) A comprehensive evaluation of inherent properties and applications of nano-biochar prepared from different methods and feedstocks. J Clean Prod 320:128759

    Article  Google Scholar 

  • Kumar M, Xiong X, Wan Z, Sun Y, Tsang DC, Gupta J, Gao B, Cao X, Tang J, Ok YS (2020) Ball milling as a mechanochemical technology for fabrication of novel biochar nanomaterials. Bioresour Technol 312:123613

    Article  CAS  Google Scholar 

  • Lateef A, Nazir R, Jamil N, Alam S, Shah R, Khan MN, Saleem M (2016) Synthesis and characterization of zeolite based nano–composite: an environment friendly slow release fertilizer. Microporous Mesoporous Mater 232:174–183

    Article  CAS  Google Scholar 

  • Lateef A, Nazir R, Jamil N, Alam S, Shah R, Khan MN, Saleem M (2019) Synthesis and characterization of environmental friendly corncob biochar based nano-composite–a potential slow release nano-fertilizer for sustainable agriculture. Environ Nanotechnol Monit Manag 11:100212

    Google Scholar 

  • Lehmann J, Joseph S (2015) Biochar for environmental management: an introduction. In: Biochar for environmental management. Routledge

    Google Scholar 

  • Li S, Chen G (2020) Agricultural waste-derived superabsorbent hydrogels: preparation, performance, and socioeconomic impacts. J Clean Prod 251:119669

    Article  CAS  Google Scholar 

  • Li J, Yao J, Li Y, Shao Y (2012) Controlled release and retarded leaching of pesticides by encapsulating in carboxymethyl chitosan/bentonite composite gel. J Environ Sci Health B 47:795–803

    Article  Google Scholar 

  • Li L, Zhang K, Chen L, Huang Z, Liu G, Li M, Wen Y (2017) Mass preparation of micro/nano-powders of biochar with water-dispersibility and their potential application. New J Chem 41:9649–9657

    Article  CAS  Google Scholar 

  • Liu G, Zheng H, Jiang Z, Zhao J, Wang Z, Pan B, Xing B (2018) Formation and physicochemical characteristics of nano biochar: insight into chemical and colloidal stability. Environ Sci Technol 52:10369–10379

    Article  CAS  Google Scholar 

  • Liu W, Li Y, Feng Y, Qiao J, Zhao H, Xie J, Fang Y, Shen S, Liang S (2020) The effectiveness of nanobiochar for reducing phytotoxicity and improving soil remediation in cadmium-contaminated soil. Sci Rep 10:1–10

    Google Scholar 

  • Luo W, Qian L, Liu W, Zhang X, Wang Q, Jiang H, Cheng B, Ma H, Wu Z (2021) A potential Mg-enriched biochar fertilizer: excellent slow-release performance and release mechanism of nutrients. Sci Total Environ 768:144454

    Article  CAS  Google Scholar 

  • Mahmoud E, El Baroudy A, Ali N, Sleem M (2020) Spectroscopic studies on the phosphorus adsorption in salt-affected soils with or without nano-biochar additions. Environ Res 184:109277

    Article  CAS  Google Scholar 

  • Makshut NA, Ngaini Z, Wahi R, Hussain H, Mahmut NI, Bahrin NQ (2020) Nano-sized adsorbent from pyrolysed sago activated sludge for removal of Pb (II) from aqueous solution. Pertanika J Sci Technol 28:893–916

    Google Scholar 

  • Moradi N, Moezzi A, Khajavi-Shojaei S, Khaji P (2022) Cadmium immobilization in contaminated soil by nano-biochar and Fe-modified nano-biochar. Iran J Soil Water Res 53:795–808

    Google Scholar 

  • Naghdi M, Taheran M, Brar SK, Kermanshahi-Pour A, Verma M, Surampalli RY (2017a) Immobilized laccase on oxygen functionalized nanobiochars through mineral acids treatment for removal of carbamazepine. Sci Total Environ 584:393–401

    Article  Google Scholar 

  • Naghdi M, Taheran M, Brar SK, Rouissi T, Verma M, Surampalli RY, Valero JR (2017b) A green method for production of nanobiochar by ball milling-optimization and characterization. J Clean Prod 164:1394–1405

    Article  CAS  Google Scholar 

  • Oleszczuk P, Ćwikła-Bundyra W, Bogusz A, Skwarek E, Ok YS (2016) Characterization of nanoparticles of biochars from different biomass. J Anal Appl Pyrolysis 121:165–172

    Article  CAS  Google Scholar 

  • Pariyar P, Kumari K, Jain MK, Jadhao PS (2020) Evaluation of change in biochar properties derived from different feedstock and pyrolysis temperature for environmental and agricultural application. Sci Total Environ 713:136433

    Article  CAS  Google Scholar 

  • Pereira AE, Grillo R, Mello NF, Rosa AH, Fraceto LF (2014) Application of poly (epsilon-caprolactone) nanoparticles containing atrazine herbicide as an alternative technique to control weeds and reduce damage to the environment. J Hazard Mater 268:207–215

    Article  CAS  Google Scholar 

  • Purbalisa W, Zulaehah I, Paputri D (2021) Application of remediation treatment to reduce lead in the soil of shallot cropping. IOP Conference Series: Earth and Environmental Science. IOP Publishing, 012063

    Google Scholar 

  • Qiao D, Liu H, Yu L, Bao X, Simon GP, Petinakis E, Chen L (2016) Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer. Carbohydr Polym 147:146–154

    Article  CAS  Google Scholar 

  • Rajput VD, Minkina T, Ahmed B, Singh VK, Mandzhieva S, Sushkova S, Bauer T, Verma KK, Shan S, Van Hullebusch ED (2022) Nano-biochar: a novel solution for sustainable agriculture and environmental remediation. Environ Res 210:112891

    Article  CAS  Google Scholar 

  • Ramanayaka S, Tsang DC, Hou D, Ok YS, Vithanage M (2020a) Green synthesis of graphitic nanobiochar for the removal of emerging contaminants in aqueous media. Sci Total Environ 706:135725

    Article  CAS  Google Scholar 

  • Ramanayaka S, Vithanage M, Alessi DS, Liu W-J, Jayasundera AC, Ok YS (2020b) Nanobiochar: production, properties, and multifunctional applications. Environ Sci Nano 7:3279–3302

    Article  CAS  Google Scholar 

  • Ramezanzadeh H, Reyhanitabar A, Oustan S, Mohammadi M, Van der Zee S (2021) Enhanced sorption of cadmium by using biochar nanoparticles from ball milling in a sandy soil. Eurasian Soil Sci 54:201–211

    Article  CAS  Google Scholar 

  • Ritchie H (2017) How many people does synthetic fertilizer feed? Our World in Data

    Google Scholar 

  • Salama DM, Abd el Aziz ME, El-Naggar ME, Shaaban EA, Abd El-Wahed MS (2021) Synthesis of an eco-friendly nanocomposite fertilizer for common bean based on carbon nanoparticles from agricultural waste biochar. Pedosphere 31:923–933

    Article  CAS  Google Scholar 

  • Seleiman MF, Almutairi KF, Alotaibi M, Shami A, Alhammad BA, BATTAGLIA, M. L. (2020) Nano-fertilization as an emerging fertilization technique: why can modern agriculture benefit from its use? Plan Theory 10:2

    Google Scholar 

  • Shaheen SM, Niazi NK, Hassan NE, Bibi I, Wang H, Tsang DC, Ok YS, Bolan N, Rinklebe J (2019) Wood-based biochar for the removal of potentially toxic elements in water and wastewater: a critical review. Int Mater Rev 64:216–247

    Article  CAS  Google Scholar 

  • Shen Z, Hou D, Jin F, Shi J, Fan X, Tsang DC, Alessi DS (2019) Effect of production temperature on lead removal mechanisms by rice straw biochars. Sci Total Environ 655:751–758

    Article  CAS  Google Scholar 

  • Song B, Chen M, Zhao L, Qiu H, Cao X (2019) Physicochemical property and colloidal stability of micron-and nano-particle biochar derived from a variety of feedstock sources. Sci Total Environ 661:685–695

    Article  CAS  Google Scholar 

  • Ullah M, Ali M, Abd Hamid SB (2014) Surfactant-assisted ball milling: a novel route to novel materials with controlled nanostructure-a review. Rev Adv Mater Sci 37:1–14

    Google Scholar 

  • Ullmann C, Babick F, Koeber R, Stintz M (2017) Performance of analytical centrifugation for the particle size analysis of real-world materials. Powder Technol 319:261–270

    Article  CAS  Google Scholar 

  • Wallace CA, Afzal MT, Saha GC (2019) Effect of feedstock and microwave pyrolysis temperature on physio-chemical and nano-scale mechanical properties of biochar. Bioresour Bioprocess 6:1–11

    Article  Google Scholar 

  • Wang Y, Wei Y, Sun J (2016) Biochar application promotes growth parameters of soybean and reduces the growth difference. Communications in Soil Science and Plant Analysis 47(12):1493–1502

    Google Scholar 

  • Xu X, Cölfen H (2021) Ultracentrifugation techniques for the ordering of nanoparticles. Nanomaterials 11:333

    Article  Google Scholar 

  • Yang F, Sun L, Xie W, Jiang Q, Gao Y, Zhang W, Zhang Y (2017) Nitrogen-functionalization biochars derived from wheat straws via molten salt synthesis: An efficient adsorbent for atrazine removal. Science of the Total Environment 607:1391–1399

    Google Scholar 

  • Yang Y, Zhou B, Hu Z, Lin H (2020) The effects of nano-biochar on maize growth in northern Shaanxi Province on the Loess Plateau. Appl Ecol Environ Res 18:2863–2877

    Article  Google Scholar 

  • Yao Y, Gao B, Chen J, Yang L (2013) Engineered biochar reclaiming phosphate from aqueous solutions: mechanisms and potential application as a slow-release fertilizer. Environ Sci Technol 47:8700–8708

    Article  CAS  Google Scholar 

  • Yuan Y, Zhang N, Hu X (2020) Effects of wet and dry ball milling on the physicochemical properties of sawdust derived-biochar. Instrum Sci Technol 48:287–300

    Article  CAS  Google Scholar 

  • Yue L, Lian F, Han Y, Bao Q, Wang Z, Xing B (2019) The effect of biochar nanoparticles on rice plant growth and the uptake of heavy metals: implications for agronomic benefits and potential risk. Sci Total Environ 656:9–18

    Article  CAS  Google Scholar 

  • Zhang M, Gao B, Yao Y, Xue Y, Inyang M (2012) Synthesis of porous MgO-biochar nanocomposites for removal of phosphate and nitrate from aqueous solutions. Chem Eng J 210:26–32

    Article  CAS  Google Scholar 

  • Zhang Q, Wang J, Lyu H, Zhao Q, Jiang L, Liu L (2019) Ball-milled biochar for galaxolide removal: sorption performance and governing mechanisms. Sci Total Environ 659:1537–1545

    Article  CAS  Google Scholar 

  • Zhang X, Wells M, Niazi N, Bolan N, Shaheeng S, Hou D, Gao B, Wang H, Rinklebe J, Wang Z (2022) Nanobiochar-rhizosphere interactions: implications for the remediation of heavy-metal contaminated soils. Environ Pollut 299, 118810

    Google Scholar 

  • Zhou B, Chen X, Wang Q, Wei W, Zhang T (2018) Effects of nano carbon on soil erosion and nutrient loss in a semi-arid loess region of northwestern China. Int J Agric Biol Eng 11:138–145

    Google Scholar 

  • Zhou S, Ni X, Zhou H, Meng X, Sun H, Wang J, Yin X (2021) Effect of nZVI/biochar nanocomposites on Cd transport in clay mineral-coated quartz sand: facilitation and rerelease. Ecotoxicol Environ Saf 228:112971

    Article  CAS  Google Scholar 

  • Zhu D, Pan J, Lu L, Holmes RJ (2015) Iron ore pelletization. Iron ore. Elsevier

    Google Scholar 

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Sheokand, M. et al. (2023). Nanobiochar-Based Formulations for Sustained Release of Agrochemicals in Precision Agriculture Practices. In: Shanker, U., Hussain, C.M., Rani, M. (eds) Handbook of Green and Sustainable Nanotechnology. Springer, Cham. https://doi.org/10.1007/978-3-030-69023-6_109-1

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