Abstract
3D printing has attracted increasing attention as it exhibits excellent potential in the fabrication of 3D complex structures, which are very difficult to make using conventional techniques, with low cost, less energy, and material consumption. Thermosets are integral to today’s aerospace, automotive, marine, and energy industries and will be vital to the next generation of lightweight, energy-efficient structures, owing to their excellent specific strength, thermal stability, and chemical resistance. Manufacturing with thermosets using innovative 3D printing techniques has the potential to revolutionize composite manufacturing. However, thermosets are highly crosslinked and irreversibly cured, and it is challenging to integrate the printing process with curing process at high rate and high quality. This review will address current effort and future direction in 3D printing of thermosets.
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Shi Q et al (2017) Recyclable 3D printing of vitrimer epoxy. Mater Horiz 4(4):598–607. https://doi.org/10.1039/C7MH00043J
Robertson ID et al (2018) Rapid energy-efficient manufacturing of polymers and composites via frontal polymerization. Nature 557(7704):223–227. https://doi.org/10.1038/s41586-018-0054-x
Rodriguez JN, Zhu C, Duoss EB, Wilson TS, Spadaccini CM, Lewicki JP (2016) Shape-morphing composites with designed micro-architectures. Sci Rep 6(1). https://doi.org/10.1038/srep27933
Baekeland LH (1909) The synthesis, constitution, and uses of bakelite. J Ind Eng Chem 1(3):149–161. https://doi.org/10.1021/ie50003a004
Bryce DM (1996) Plastic injection molding: manufacturing process fundamentals. Society of Manufacturing Engineers, Dearborn
Agarwal BD, Broutman LJ, Chandrashekhara K (2006) Analysis and performance of fiber composites, 3rd edn. Wiley, Hoboken
Rouison D, Sain M, Couturier M (2004) Resin transfer molding of natural fiber reinforced composites: cure simulation. Compos Sci Technol 64(5):629–644. https://doi.org/10.1016/j.compscitech.2003.06.001
Advani SG, Hsiao K-T (eds) (2012) Manufacturing techniques for polymer matrix composites (PMCs). Woodhead Publishing, Cambridge
Kuang X, Zhao Z, Chen K, Fang D, Kang G, Qi HJ (2018) High-speed 3D printing of high-performance thermosetting polymers via two-stage curing. Macromol Rapid Commun 39(7):1700809. https://doi.org/10.1002/marc.201700809
Fette M, Sander P, Wulfsberg J, Zierk H, Herrmann A, Stoess N (2015) Optimized and cost-efficient compression molds manufactured by selective laser melting for the production of thermoset fiber reinforced plastic aircraft components. Procedia CIRP 35:25–30. https://doi.org/10.1016/j.procir.2015.08.082
Chandrasekaran S, Duoss EB, Worsley MA, Lewicki JP (2018) 3D printing of high performance cyanate ester thermoset polymers. J Mater Chem A 6(3):853–858. https://doi.org/10.1039/C7TA09466C
Taormina G, Sciancalepore C, Bondioli F, Messori M (2018) Special resins for stereolithography: in situ generation of silver nanoparticles. Polymers 10(2):212. https://doi.org/10.3390/polym10020212
Lewicki JP et al (2017) 3D-printing of meso-structurally ordered carbon fiber/polymer composites with unprecedented orthotropic physical properties. Sci Rep 7:43401. https://doi.org/10.1038/srep43401
Chiappone A et al (2017) Study of graphene oxide-based 3D printable composites: effect of the in situ reduction. Compos Part B Eng 124:9–15. https://doi.org/10.1016/j.compositesb.2017.05.049
Szebenyi G, Czigany T, Magyar B, Karger-Kocsis J (2017) 3D printing-assisted interphase engineering of polymer composites: concept and feasibility. Express Polym Lett 11(7):525–530. https://doi.org/10.3144/expresspolymlett.2017.50
Hao W, Liu Y, Zhou H, Chen H, Fang D (2018) Preparation and characterization of 3D printed continuous carbon fiber reinforced thermosetting composites. Polym Test 65:29–34. https://doi.org/10.1016/j.polymertesting.2017.11.004
Yang K et al (2017) Diels-Alder reversible thermoset 3D Printing: isotropic thermoset polymers via fused filament fabrication. Adv Funct Mater 27(24):1700318. https://doi.org/10.1002/adfm.201700318
Compton BG et al (2018) Direct-write 3D printing of NdFeB bonded magnets. Mater Manuf Process 33(1):109–113. https://doi.org/10.1080/10426914.2016.1221097
Chen K, Kuang X, Li V, Kang G, Qi HJ (2018) Fabrication of tough epoxy with shape memory effects by UV-assisted direct-ink write printing. Soft Matter 14(10):1879–1886. https://doi.org/10.1039/C7SM02362F
Ligon-Auer SC, Schwentenwein M, Gorsche C, Stampfl J, Liska R (2016) Toughening of photo-curable polymer networks: a review. Polym Chem 7(2):257–286. https://doi.org/10.1039/C5PY01631B
Osswald TA, Puentes J, Kattinger J (2018) Fused filament fabrication melting model. Addit Manuf 22:51–59. https://doi.org/10.1016/j.addma.2018.04.030
Ambrosi A, Pumera M (2016) 3D-printing technologies for electrochemical applications. Chem Soc Rev 45(10):2740–2755. https://doi.org/10.1039/C5CS00714C
Compton BG, Lewis JA (2014) 3D-printing of lightweight cellular composites. Adv Mater 26(34):5930–5935. https://doi.org/10.1002/adma.201401804
Wang X, Jiang M, Zhou Z, Gou J, Hui D (2017) 3D printing of polymer matrix composites: a review and prospective. Compos Part B Eng 110:442–458. https://doi.org/10.1016/j.compositesb.2016.11.034
Rimdusit S, Lohwerathama M, Hemvichian K, Kasemsiri P, Dueramae I (2013) Shape memory polymers from benzoxazine-modified epoxy. Smart Mater Struct 22(7):075033. https://doi.org/10.1088/0964-1726/22/7/075033
Licari JJ, Swanson DW (2011) Chemistry, formulation, and properties of adhesives. In: Adhesives technology for electronic applications. Elsevier, pp 75–141
Wang R-M, Zheng S-R, Zheng Y-P (2011) Matrix materials. In: Polymer matrix composites and technology. Elsevier, pp 101–548
Zhu W et al (2016) A novel method based on selective laser sintering for preparing high-performance carbon fibres/polyamide12/epoxy ternary composites. Sci Rep 6(1). https://doi.org/10.1038/srep33780
Robertson ID, Dean LM, Rudebusch GE, Sottos NR, White SR, Moore JS (2017) Alkyl phosphite inhibitors for frontal ring-opening metathesis polymerization greatly increase pot life. ACS Macro Lett. 6(6):609–612. https://doi.org/10.1021/acsmacrolett.7b00270
Vallons KAM, Drozdzak R, Charret M, Lomov SV, Verpoest I (2015) Assessment of the mechanical behaviour of glass fibre composites with a tough polydicyclopentadiene (PDCPD) matrix. Compos Part Appl Sci Manuf 78:191–200. https://doi.org/10.1016/j.compositesa.2015.08.016
Wang B et al (2019) 3D printing of in-situ curing thermally insulated thermosets. Manuf Lett 21:1–6. https://doi.org/10.1016/j.mfglet.2019.06.001
Garcia JM et al (2014) Recyclable, strong thermosets and organogels via paraformaldehyde condensation with diamines. Science 344(6185):732–735. https://doi.org/10.1126/science.1251484
Montarnal D, Capelot M, Tournilhac F, Leibler L (2011) Silica-like malleable materials from permanent organic networks. Science 334(6058):965–968. https://doi.org/10.1126/science.1212648
Capelot M, Montarnal D, Tournilhac F, Leibler L (2012) Metal-catalyzed transesterification for healing and assembling of thermosets. J Am Chem Soc 134(18):7664–7667. https://doi.org/10.1021/ja302894k
Chen X (2002) A thermally re-mendable cross-linked polymeric material. Science 295(5560):1698–1702. https://doi.org/10.1126/science.1065879
Sun H-B, Matsuo S, Misawa H (1999) Three-dimensional photonic crystal structures achieved with two-photon-absorption photopolymerization of resin. Appl Phys Lett 74(6):786–788. https://doi.org/10.1063/1.123367
Zhang B, Kowsari K, Serjouei A, Dunn ML, Ge Q (2018) Reprocessable thermosets for sustainable three-dimensional printing. Nat Commun 9(1). https://doi.org/10.1038/s41467-018-04292-8
Miao S et al (2017) 4D printing of polymeric materials for tissue and organ regeneration. Mater Today 20(10):577–591. https://doi.org/10.1016/j.mattod.2017.06.005
Choong YYC, Maleksaeedi S, Eng H, Wei J, Su P-C (2017) 4D printing of high performance shape memory polymer using stereolithography. Mater Des 126:219–225. https://doi.org/10.1016/j.matdes.2017.04.049
Zarek M, Layani M, Cooperstein I, Sachyani E, Cohn D, Magdassi S (2016) 3D printing of shape memory polymers for flexible electronic devices. Adv Mater 28(22):4449–4454. https://doi.org/10.1002/adma.201503132
Ligon SC, Liska R, Stampfl J, Gurr M, Mülhaupt R (2017) Polymers for 3D printing and customized additive manufacturing. Chem Rev 117(15):10212–10290. https://doi.org/10.1021/acs.chemrev.7b00074
Kelbassa I, Wohlers T, Caffrey T (2012) Quo vadis , laser additive manufacturing? J Laser Appl 24(5):050101. https://doi.org/10.2351/1.4745081
Tumbleston JR et al (2015) Continuous liquid interface production of 3D objects. Science 347(6228):1349–1352. https://doi.org/10.1126/science.aaa2397
Walker DA, Hedrick JL, Mirkin CA (2019) Rapid, large-volume, thermally controlled 3D printing using a mobile liquid interface. Science 366(6463):360–364. https://doi.org/10.1126/science.aax1562
Kelly BE, Bhattacharya I, Heidari H, Shusteff M, Spadaccini CM, Taylor HK (2019) Volumetric additive manufacturing via tomographic reconstruction. Science 363(6431):1075–1079. https://doi.org/10.1126/science.aau7114
Hamerton I, Mooring L (2012) The use of thermosets in aerospace applications. In: Thermosets. Elsevier, pp 189–227
Jimenez M, Duquesne S, Bourbigot S (2006) Characterization of the performance of an intumescent fire protective coating. Surf Coat Technol 201(3–4):979–987. https://doi.org/10.1016/j.surfcoat.2006.01.026
Song D, Gupta RK (2012) The use of thermosets in the building and construction industry. In: Thermosets. Elsevier, pp 165–188
A. K. H.P.S. et al (2017) Nanofibrillated cellulose reinforcement in thermoset polymer composites. In: Cellulose-Reinforced Nanofibre Composites. Elsevier, pp 1–24
Martone A, Formicola C, Giordano M, Zarrelli M (2010) Reinforcement efficiency of multi-walled carbon nanotube/epoxy nano composites. Compos Sci Technol 70(7):1154–1160. https://doi.org/10.1016/j.compscitech.2010.03.001
Kliem M, Høgsberg J, Wang Q, Dannemann M (2017) Characterization of clay-modified thermoset polymers under various environmental conditions for the use in high-voltage power pylons. Adv Mech Eng 9(5):168781401769889. https://doi.org/10.1177/1687814017698890
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The authors received funding support from Texas A&M Engineering Experiment Station (TEES), National Science Foundation and State of Texas.
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Wang, B., Zhang, Z., Pei, Z. et al. Current progress on the 3D printing of thermosets. Adv Compos Hybrid Mater 3, 462–472 (2020). https://doi.org/10.1007/s42114-020-00183-z
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DOI: https://doi.org/10.1007/s42114-020-00183-z