Skip to main content
Log in

Treatment of dairy wastewater by electrocoagulation using A-U4G (2017-Al) alloy and pure aluminum as electrode material

  • Original Paper
  • Published:
Euro-Mediterranean Journal for Environmental Integration Aims and scope Submit manuscript

Abstract

The electrocoagulation (EC) process is an efficient and low-cost system for the purification of wastewater. The aim of this work was to investigate the efficiency of two types of aluminum (Al) electrodes (Al alloy and pure Al electrodes) for the treatment of synthetic semi-skimmed milk wastewater. Turbidity, chemical oxygen demand (COD), and concentration of Al species were monitored during the experiments. The effect of various parameters, such as current density and type and nature of the electrode were examined. The results showed that Al alloy electrodes exhibited a higher efficiency than pure Al electrodes. A quasi-total reduction of turbidity and a removal of approximately 58% of the COD were achieved within 24 min at pH 7 and a current density of 14.3 mA cm−2. It was also observed that the removal performance was not affected by the state of the electrode surfaces (polished) under the same operating conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Aitbara A, Hazourli S, Boumaza S, Touahria S, Cherifi M (2013) Etude comparative d’efficacité de prétraitement des effluents d’une laiterie industrielle par coagulation-floculation et électrocoagulation en dynamique. Rev Sci Technol Synthèse 26:103–111

    Google Scholar 

  • Aitbara A, Cherifi M, Hazourli S, Leclerc J-P (2016) Continuous treatment of industrial dairy effluent by electrocoagulation using aluminum electrodes. Desalin Water Treat 57(8):3395–3404

    Google Scholar 

  • Aitbara A, Djellabi R, Eulmi A, Hazourli S (2017) Electrocoagulation and fenton hybrid processes for dairy water purification. in situ generation of H2O2. Sensor Lett 15:992–997

    Google Scholar 

  • Al-Jabari M (2017) Kinetic mass transfer adsorption model for treating dairy wastewater with stone cutting solid waste. Environ Technol Innov 7:21–29

    Google Scholar 

  • Andrade LH, Mendes FDS, Espindola JC, Amaral MCS (2014) Nanofiltration as tertiary treatment for the reuse of dairy wastewater treated by membrane bioreactor. Sep Purif Technol 126:21–29

    Google Scholar 

  • Aoudjehane M, Rezzouk M, Kellil A, Guigui C (2010) Etude comparative de l’électrocoagulation et de la coagulation floculation vis-à-vis de la modélisation d’une émulsion d’huile de coupe. Rev Des Sci 23(1):17–30

    Google Scholar 

  • Attour A, Touati M, Tlili M, Ben Amor M, Lapicque F, Leclerc J-P (2014) Influence of operating parameters on phosphate removal from water by electrocoagulation using aluminum electrodes. Sep Purif Technol 123:124–129

    Google Scholar 

  • Aydiner C, Sen U, Topcu S, Ekinci D, Altinay AD, Koseoglu-Imer DY, Keskinler B (2014) Techno-economic viability of innovative membrane systems in water and mass recovery from dairy wastewater. J Membrane Sci 458:66–75

    Google Scholar 

  • Bayar S, Yıldız YŞ, Yılmaz AE, İrdemez Ş (2011) The effect of stirring speed and current density on removal efficiency of poultry slaughterhouse wastewater by electrocoagulation method. Desalination 280(1–3):103–107

    Google Scholar 

  • Benaissa F, Kermet-Said H, Moulai-Mostefa N (2016) Optimization and kinetic modeling of electrocoagulation treatment of dairy wastewater. Desalin Water Treat 57(13):5988–5994

    Google Scholar 

  • Bennani CF, Ousji B, Ennigrou DJ (2016) Reclamation of dairy wastewater using ultrafiltration process. Desalin Water Treat 55(2):297–303

    Google Scholar 

  • Bilińskaa L, Blusa K, Gmurekb M, Ledakowicz S (2019) Coupling of electrocoagulation and ozone treatment for textile wastewater reuse. Chem Eng J 358:992–1001

    Google Scholar 

  • Bortoluzzi AC, Faitão JA, Di Luccio M, Dallago RM, Steffens J, Zabot GL, Tres MV (2017) Dairy wastewater treatment using integrated membrane systems. J Environ Chem Eng 5(5):4819–4827

    Google Scholar 

  • Can OT, Kobya M, Demirbas E, Bayramoglu M (2006) Treatment of the textile wastewater by combined electrocoagulation. Chemosphere 62(2):181–187

    Google Scholar 

  • Chakchouk I, Elloumi N, Belaid C, Mseddi S, Chaari L, Kallel M (2017) A combined electrocoagulation–electrooxidation treatment for dairy wastewater. Braz J Chem Eng 34(1):109–117

    Google Scholar 

  • Changmai M, Pasawan M, Purkait MK (2019) Treatment of oily wastewater from drilling site using electrocoagulation followed by microfiltration. Sep Purif Technol 210:463–472

    Google Scholar 

  • Chen X, Chen G, Yue PL (2002) Investigation on the electrolysis voltage of electrocoagulation. Chem Eng J 57(13):2449–2455

    Google Scholar 

  • Cook DC (2005) Spectroscopic identification of protective and non-protective corrosion coatings on steel structures in marine environments. Corrosion Sci 47(10):2550–2570

    Google Scholar 

  • Demirel B, Yenigun O, Onay TT (2005) Anaerobic treatment of dairy wastewaters: A review. Process Biochem 40(8):2583–2595

    Google Scholar 

  • Dia O, Drogui P, Buelna G, Dubé R (2018) Hybrid process, electrocoagulation-biofiltration for landfill leachate treatment. Waste Manage 75:391–399

    Google Scholar 

  • Doggaz A, Attour A, Mostefa MLP, Tlili M, Lapicque L (2018) Iron removal from waters by electrocoagulation: Investigations of the various physicochemical phenomena involved. Sep Purif Technol 203:217–225

    Google Scholar 

  • Dolati M, Aghapour AA, Khorsandi H, Karimzade S (2017) Boron removal from aqueous solutions by electrocoagulation at low concentrations. J Environ Chem Eng 5(5):5150–5156

    Google Scholar 

  • Elabbas S, Ouazzani N, Mandi L, Berrekhis F, Perdicakis M, Pontvianne S, Pons M-N, Lapicque F, Leclerc J-P (2016) Treatment of highly concentrated tannery wastewater using electrocoagulation: Influence of the quality of aluminium used for the electrode. J Hazard Mater 319:69–77

    Google Scholar 

  • Eulmi A, Hazourli S, Abrane R, Bendaia M, Aitbara A, Chérifi M, Touahria S (2019) Evaluation of electrocoagulation and activated carbon adsorption techniques used separately or coupled to treat wastewater from industrial dairy. Int J Chem Reactor Eng 17:2. https://doi.org/10.1515/ijcre-2018-0229

    Article  Google Scholar 

  • Hakizimana JN, Gourich B, Chafi M, Stiriba Y, Vial C, Drogui P, Naja J (2017) Electrocoagulation process in water treatment: a review of electrocoagulation modeling approaches. Desalination 404:1–21

    Google Scholar 

  • Hamdani A, Chennaoui M, Assobhei O, Mountadar M (2004) Caractérisation et traitement par coagulation décantation d’un effluent de laiterie. Lait 84:317–328

    Google Scholar 

  • Hashim K-S, Al Khaddar R, Jasim N, Shaw A, Phipps D, Kot P, Pedrola M-O, Alattabi A-W, Abdulredha M, Alawsh R (2019) Electrocoagulation as a green technology for phosphate removal from river water. Sep Purif Technol 210:135–144

    Google Scholar 

  • Hazourli S, Boudiba L, Fedaoui D, Ziati M (2007) Prétraitement par coagulation-floculation d’eaux résiduaires d’une laiterie industrielle. Soc Algér Chim 17(2):155–172

    Google Scholar 

  • Heaven MW, Wild K, Verheyen V, Cruickshank A, Watkins M, Nash D (2011) Seasonal and wastewater stream variation of trace organic compounds in a dairy processing plant aerobic bioreactor. Bioresour Technol 102(17):7727–7736

    Google Scholar 

  • Holt PK, Barton GW, Wark M, Mitchell CA (2002) A quantitative comparison between chemical dosing and electrocoagulation. Colloid Surface A 211(2–3):233–248

    Google Scholar 

  • Jiang J-Q, Graham N, Andre C, Kelsall GH, Brandon N (2002) Laboratory study of electrocoagulation-flotation for water treatment. Water Res 36(16):4064–4078

    Google Scholar 

  • Karadag D, Köroğlu OE, Ozkaya B, Cakmakci M (2015) A review on anaerobic biofilm reactors for the treatment of dairy industry wastewater. Process Biochem 50(2):262–271

    Google Scholar 

  • Kobya M, Demirbas E (2015) Evaluations of operating parameters on treatment of can manufacturing wastewater by electrocoagulation. J Water Process Eng 8:64–74

    Google Scholar 

  • Kobya M, Demirbas E, Can OT, Bayramoglu M (2006) Treatment of levafix orange textile dye solution by electrocoagulation. J Hazard Mater 132:183–188

    Google Scholar 

  • Liu Y, Hu X-M, Zhao Y, Wang J, Lu M-X, Peng F-H, Bao J (2018) Removal of perfluorooctanoic acid in simulated and natural waters with different electrode materials by electrocoagulation. Chemosphere 201:303–309

    Google Scholar 

  • Llanos J, Cotillas S, Cañizares P, Rodrigo MA (2014) Effect of bipolar electrode material on the reclamation of urban wastewater by an integrated electrodisinfection/electrocoagulation process. Water Res 53:329–338

    Google Scholar 

  • McBeath ST, Mohseni M, Wilkinson DP (2020) Pilot-scale iron electrocoagulation treatment for natural organic matter removal. Environ Technol 41(5):577–585

  • Mameri N, Lounici H, Belhocine D, Grib H, Piron DL, Yahiat Y (2001) Defluoridation of Sahara water by small plant electrocoagulation using bipolar aluminum electrodes. Sep Purif Technol 24(1–2):113–119

    Google Scholar 

  • Markou V, Kontogianni M-C, Frontistis Z, Tekerlekopoulou AG, KatsaounisA VD (2017) Electrochemical treatment of biologically pre-treated dairy wastewater using dimensionally stable anodes. J Environ Manage 202(1):217–224

    Google Scholar 

  • Mechelhoff M, Kelsall GH, Graham NJD (2013) Electrochemical behaviour of aluminium in electrocoagulation processes. Chem Eng Sci 95:301–312

    Google Scholar 

  • Melchiors MS, Piovesan M, Becegato VR, Becegato VA, Tambourgi EB, Paulino AT (2016) Treatment of wastewater from the dairy industry using electroflocculation and solid whey recovery. J Environ Manage 182:574–580

    Google Scholar 

  • Mouedhen G, Feki M, De PetrisWery M (2008) Behavior of aluminum electrodes in electrocoagulation process. J Hazard Mater 150(1):124–135

    Google Scholar 

  • Murugananthan M, BhaskarRaju G, Prabhakar S (2004) Separation of pollutants from tannery effluents by electro flotation. Sep Purif Technol 40(1):69–75

    Google Scholar 

  • Nagappan S, Phinney D, Heldman D (2018) Management of waste streams from dairy manufacturing operations using membrane filtration and dissolved air flotation. Applied Sci 8(12):2694

    Google Scholar 

  • Nasrullah M, Zularisam AW, Krishnan S, Sakinah M, Singh L, Fen YW (2019) High performance electrocoagulation process in treating palm oil mill effluent using high current intensity application. Chinese J Chem Eng 27(1):208–217

    Google Scholar 

  • Nawarkar CJ, Salkar VD (2019) Solar powered electrocoagulation system for municipal wastewater treatment. Fuel 237:222–226

    Google Scholar 

  • Rebhun M, Lurie M (1993) Control of organic matter by coagulation and floc separation. Water Sci Technol 27(11):1–20

    Google Scholar 

  • Rudd WJ, Scully JC (1980) The function of the repassivation process in the inhibition of pitting corrosion on aluminium. Corros Sci 20:611–631

    Google Scholar 

  • Şengil IA, Özacar M (2006) Treatment of dairy wastewaters by electrocoagulation using mild steel electrodes. J Hazard Mater 137(2):1197–1205

    Google Scholar 

  • Sher F, Malik A, Liu H (2013) Industrial polymer effluent treatment by chemical coagulation and flocculation. J Environ Chem Eng 1:684–689

    Google Scholar 

  • Sher F, Hanif K, Iqbal SZ, Imran M (2020) Implications of advanced wastewater treatment: Electrocoagulation and electroflocculation of effluent discharged from a wastewater treatment plant. J Water Process Eng 33:101101

    Google Scholar 

  • Tchamango S, Nanseu-Njiki Charles P, Ngameni E, Hadjiev D, Darchen A (2010) Treatment of dairy effluents by electrocoagulation using aluminiumelectrodes. Sci Total Environ 408:947–952

    Google Scholar 

  • Torres-Sánchez AL, López-Cervera SJ, de la Rosa C, Maldonado-Vega M, Maldonado-Santoyo M, Peralta-Hernández JM (2014) Electrocoagulation process coupled with advanced oxidation techniques to treatment of dairy industry wastewater. Int J Electrochem Sci 9(11):6103–6112

    Google Scholar 

  • Xu L, Cao G, Xu X, Liu S, Duan Z, He C, WangY HQ (2017) Simultaneous removal of cadmium, zinc and manganese using electrocoagulation: Influence of operating parameters and electrolyte nature. J Environ Manage 204(1):394–403

    Google Scholar 

  • Yahi H, Madi N, Midoune K (2014) Contribution to biological treatment of dairy effluent by sequencing batch reactor (SBR). Desalin Water Treat 52(10–12):2315–2321

    Google Scholar 

  • Yasakau K, Zheludkevich ML, Ferreira MGS (2017) Corrosion and corrosion protection of aluminum alloys.reference module in chemistry. Mol Sci Chem Eng 1:115–127

    Google Scholar 

  • Yavuz Y, Ögütveren ÜB (2018) Treatment of industrial estate wastewater by the application of electrocoagulation process using iron electrodes. J Environ Manage 207:151–158

    Google Scholar 

  • Yavuz Y, Ocal E, Koparala AS, Ogutverena UB (2011) Treatment of dairy industry wastewater by EC and EF processes using hybrid Fe–Al plate electrodes. J Chem Technol Biotechnol 86(7):964–969

    Google Scholar 

  • Yıldız YŞ, Koparal AS, Keskinler B (2008) Effect of initial pH and supporting electrolyte on the treatment of water containing high concentration of humic substances by electrocoagulation. Chem Eng J 138(1–3):63–72

    Google Scholar 

  • Ziati M, Khemmari F, Aitbara A, Hazourli S (2018) Reduction of turbidity and chromium content of tannery wastewater by electrocoagulation process. Water Environ Res 90(7):598–603

    Google Scholar 

Download references

Acknowledgments

The authors acknowledge the financial support of the Ministry of Higher Education and Scientific Research of Algeria.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Abdeltif Amrane.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Communicated by Nicolas Roche, Chief Editor.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aitbara, A., Khelalfa, A., Bendaia, M. et al. Treatment of dairy wastewater by electrocoagulation using A-U4G (2017-Al) alloy and pure aluminum as electrode material. Euro-Mediterr J Environ Integr 6, 19 (2021). https://doi.org/10.1007/s41207-020-00227-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s41207-020-00227-2

Keywords

Navigation