Abstract
Manufacturing industries synthesize new chemical products every day, which eventually find their way into domestic and industrial wastewaters. As a result, wastewater is becoming increasingly more complex in nature. The emerging pollutants escape the treatment systems and appear in the receiving water bodies. Wastewater treatment plants in India still report effluent parameters in terms of biological oxygen demand (BOD) and chemical oxygen demand (COD) at the ppm level, whereas these emerging pollutants, many of whom are non-biodegradable, can be toxic and carcinogenic at the ppb level. Therefore, it is imperative to look for alternatives or upgrade the existing systems which safely remove these harmful compounds from wastewater. In this research, efficiency of electrocoagulation process was assessed in a laboratory-scale setup in removing recalcitrant carbon from a real wastewater. The wastewater was collected from an effluent treatment plant that receives domestic wastewater and industrial effluents from chemical, bulk drugs and allied industries, for treatment. In this study, the wastewater sample was analyzed for total dissolved solids (TDS) and total organic carbon (TOC), and then treated biologically in a respirometer using aerobic microorganisms. After the oxygen uptake curve plateaued, indicating a cessation of biological process, the sample was analyzed for TDS and TOC and put in a lab-scale electrocoagulation setup. Iron and Aluminium electrodes were used in the study and efficiency of the system in removing the recalcitrant/residual carbon and TDS was studied with respect to the reaction time. The results showed that electrocoagulation can be a potential post-biological treatment system for removal of recalcitrant carbon from wastewaters.
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Ilhan F, Kurt U, Apaydin O, Gonullu MT (2008) Treatment of leachate by electrocoagulation using aluminum and iron electrodes. J Hazard Mat 154(1–3):381–389
Asadollahfardi G, Rezaee M, Tavakoli G (2016) Simulation of unenhanced electrokinetic process for lead removal from Kaolinite clay. Int J Civil Eng 14:263–270. doi:10.1007/s40999-016-0049-7
Battula SK, Cheukuri J, Raman NVVSS, Bhagawan D (2014) Effective removal of fluoride from ground water using electro- coagulation. Int J Eng Res Appl 4(2):439–445
Wang CT, Chou WL, Kuo YM (2009) Removal of COD from laundry wastewater by electrocoagulation/electro flotation. J Hazard Mat 164(1):81–86
Drogui P, Asselin M, Brar SK, Benmoussa H, Blais JF (2008) Electrochemical removal of pollutants from agro-industry wastewaters. Sep Purif Technol 61(3):301–310
Faraji A, Asadollafardi G, Shevidi A (2013) A pilot study for the application of one- and two-stage tube settlers as a secondary clarifier for wastewater treatment. Int J Civil Eng 11(4):272–280
Bazrafshan E, Moein H, Mostafapour FK, Nakhaie S (2013) Application of electrocoagulation process for dairy wastewater treatment. J Chem 2013:1155–1163
Sengil AI, Ozacar M (2006) Treatment of dairy wastewaters by electrocoagulation using mild steel electrodes. J Hazard Mater 137(2):1197–1205
Tchamango S, Nanseu-njiki CP, Ngameni E, Hadjiev D, Darchen A (2010) Treatment of dairy effluents by electrocoagulation using aluminium electrodes. Sci Total Environ 408(4):947–952
Khandegar V, Saroha AK (2012) Electrochemical treatment of distillery spent wash using aluminum and iron electrodes. Chin J Chem Eng 20(3):439–443
Kumar M, Ponselvan FIA, Malviya JR, Srivastava VC, Mall ID (2009) Treatment of bio-digester effluent by electrocoagulation using iron electrodes. J Hazard Mat 165:345–352
Sridhar R, Sivakumar V, Immanuel VP, Maran JP (2011) Treatment of pulp and paper industry bleaching effluent by electrocoagulant process. J Hazard Mat 186:1495–1502
Zaied M, Bellakhal N (2009) Electrocoagulation treatment of black liquor from paper industry. J Hazard Mat 163:995–1000
Nasution A, Ng BL, Ali E, Yaakob Z, Kamarudin SK (2014) Electrocoagulation of palm oil mill effluent for treatment and hydrogen production using response surface methodology. Pol J Environ Stud 23(5):1669–1677
Zaroual Z, Azzi M, Saib N, Chainet E (2006) Contribution to the study of electrocoagulation mechanism in basic textile effluent. J Hazard Mat 131:73–78
Drouiche N, Ghaffour N, Lounici H, Mameri N (2008) Electrochemical treatment of chemical mechanical polishing wastewater: removal of fluoride—sludge characteristics—operating cost. Desalination 223:134–142
Koparal AS, Ogutveren UB (2002) Removal of nitrate from water by electroreduction and electrocoagulation. J Hazard Mat 89:83–94
Vasudevan S, Lakshmi J, Jayaraj J, Sozhan G (2009) Remediation of phosphate-contaminated water by electrocoagulation with aluminium, aluminium alloy and mild steel anodes. J Hazard Mat 164:1480–1486
Gao P, Chen X, Shen F, Chen G (2005) Removal of chromium (VI) from wastewater by combined electrocoagulation–electroflotation without a filter. Sep Purif Technol 43:117–123
Vasudevan S, Lakshmi J (2011) Effects of alternating and direct current in electrocoagulation process on the removal of cadmium from water—a novel approach. Sep Purif Technol 80(3):643–651
Hasnain M, Henry E, Ahmed Z (2014) Boron removal by electrocoagulation and recovery. Water Res 51:113–123
Kabdasli I, Arslan T, Hansi TO, Arslan-alaton I, Tünay O (2009) Complexing agent and heavy metal removals from metal plating effluent by electrocoagulation with stainless steel electrodes. J Hazard Mat 165:838–845
Melnik ES. Alternative design for electrocoagulation treatment of cromium containing electroplating wastewater. J Water Chem Technol 38 (1): 45–50. doi:10.3103/S1063455X16010082
Moreno-casillas HA, Cocke DL, Gomes JAG, Morkovsky P, Parga JR, Peterson E (2007) Electrocoagulation mechanism for COD removal. Sep Purif Technol 56:204–211
Marsili-Libelli S, Tabani F (2002) Accuracy analysis of a respirometer for activated sludge dynamic modelling. Water Res 36(5):1181–1192
Jing-wei Feng, Ya-bing Sun, Zheng Zheng, Ji-biao Zhang, Shu Li, Yuan-chun Tian (2007) Treatment of tannery wastewater by electrocoagulation. J Environ Sci 19(12):1409–1415
Kobya M, Can OT, Bayramoglu M (2003) Treatment of textile wastewaters by electrocoagulation using iron and aluminum electrodes. J Hazard Mat 100(1–3):163–178
Mollah MYA, Morkovsky P, Gomes JAG, Kesmez M, Parga J, Cocke DL (2004) Fundamentals, present and future perspectives of electrocoagulation. J Hazard Mat 114(1–3):199–210
Varank G, Erkan H, Yazycy S, Demir A, Engin G (2014) Electrocoagulation of tannery wastewater using monopolar electrodes: process optimization by response surface methodology. Int J Environ Res 8(1):165–180
Standards for Emission or Discharge of Environmental Pollutants from various industries. http://www.cpcb.nic.in/Industry-Specific-Standards/Effluent/446-1.pdf.
Acknowledgements
We express our sincere gratitude to the Department of Civil Engineering at IIT Hyderabad for providing the necessary infrastructure for undertaking this research. We also thank wholeheartedly Rahyals Envergy India Pvt Ltd for providing necessary funds for the project.
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Damaraju, M., Bhattacharyya, D. & Kurilla, K.K. Removal of Recalcitrant Carbon from an Industrial Wastewater Using Electrocoagulation. Int J Civ Eng 15, 697–703 (2017). https://doi.org/10.1007/s40999-017-0187-6
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DOI: https://doi.org/10.1007/s40999-017-0187-6