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Potential Application of Macrocyclic Compounds for Selective Recovery of Rare Earth Scandium Elements from Aqueous Media

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Abstract

Recently, efforts have been made to develop the extraction, recovery, and analysis of rare earth elements, especially the scandium Sc (III). This study describes the use of 15-crown-5, 12-crown-4, cryptand 2.2.2, and DC18-crown-6 as novel extractants using molecular recognition technology to effectively and selectively separate and recover Sc from aqueous media. The results show that 15-crown-5, 12-crown-4, and cryptand 2.2.2 have exhibited high selectivity for Sc, which could be of potential value in the separation and purification of Sc rare earth elements processing industry. Typically, 15-crown-5, 12-crown-4, and cryptand 2.2.2 ligands have achieved the maximum extraction efficiency > 99%, depending on the pH value of the aqueous solution. On the other hand, DC18-crown-6 only reaches 25.81%. Notably, the complex metal ions can be efficiently recovered/stripped out from the complex by HCl and HNO3. The results of the multielement extraction experiments by cryptand 2.2.2 indicate that the pH of the aqueous solution significantly impacts extraction efficiency and selectivity. Where, at pH 2 the extraction efficiency of Sc ~ 97% compared with Y ~ 18.23%, La ~ 10.21% and Ce ~ 9.2%. Moreover, the complexed Sc ions can be efficiently recovered from complexes using a precise concentration of oxalic acid, with a recovery rate of 100% at 0.1 mol/L oxalic acids, compared to 30.7% for Y, 20.3% for La, and 21.12% for Ce.

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References

  1. Haxel G (2002) Rare earth elements: critical resources for high technology, vol 87. vol 2. US Department of the Interior, US Geological Survey

  2. Tyler G (2004) Rare earth elements in soil and plant systems-a review. Plant soil 267(1–2):191–206

    Article  CAS  Google Scholar 

  3. Banihashemi SR, Taheri B, Razavian SM, Soltani F (2019) Selective nitric acid leaching of rare-earth elements from calcium and phosphate in fluorapatite concentrate. JOM 71(12):4578–4587. https://doi.org/10.1007/s11837-019-03605-6

    Article  CAS  Google Scholar 

  4. Vaughan J, Tungpalan K, Parbhakar-Fox A, Fu W, Gagen EJ, Nkrumah PN, Southam G, van der Ent A, Erskine PD, Gow P, Valenta R (2021) Toward closing a loophole: recovering rare earth elements from uranium metallurgical process tailings. JOM 73(1):39–53. https://doi.org/10.1007/s11837-020-04451-7

    Article  CAS  Google Scholar 

  5. Deng B, Li G, Luo J, Ye Q, Liu M, Rao M, Peng Z, Jiang T (2018) Selective extraction of rare earth elements over TiO2 from bauxite residues after removal of their Fe-, Si-, and Al-bearing constituents. JOM 70(12):2869–2876. https://doi.org/10.1007/s11837-018-3130-7

    Article  CAS  Google Scholar 

  6. Zhang G, Yan P, Yang Y, McLean A (2020) Recovery of scandium from reservoir silt by electrical separation. JOM 72(7):2741–2747. https://doi.org/10.1007/s11837-020-04076-w

    Article  CAS  Google Scholar 

  7. Avdibegovic D, Binnemans K (2020) Separation of scandium from hydrochloric acid-ethanol leachate of bauxite residue by a supported ionic liquid phase. Ind Eng Chem Res. https://doi.org/10.1021/acs.iecr.0c02943

    Article  Google Scholar 

  8. Meng F, Li X, Wang P, Yang F, Liang D, Gao F, He C, Wei Y (2020) Recovery of scandium from bauxite residue by selective sulfation roasting with concentrated sulfuric acid and leaching. JOM 72(2):816–822. https://doi.org/10.1007/s11837-019-03931-9

    Article  CAS  Google Scholar 

  9. Yan P, Zhang G, Yang Y, McLean A (2019) Characterization and pre-concentration of scandium in low-grade magnetite ore. JOM 71(12):4666–4673. https://doi.org/10.1007/s11837-019-03541-5

    Article  CAS  Google Scholar 

  10. Xiao J, Zou K, Chen T, Peng Y, Ding W, Chen J, Deng B, Li H, Wang Z (2021) Extraction of Sc from Sc-bearing V-Ti magnetite tailings. JOM 73(6):1836–1844. https://doi.org/10.1007/s11837-021-04665-3

    Article  CAS  Google Scholar 

  11. Ramasamy DL, Puhakka V, Repo E, Ben Hammouda S, Sillanpää M (2018) Two-stage selective recovery process of scandium from the group of rare earth elements in aqueous systems using activated carbon and silica composites: dual applications by tailoring the ligand grafting approach. Chem Eng J 341:351–360. https://doi.org/10.1016/j.cej.2018.02.024

    Article  CAS  Google Scholar 

  12. Ambaye TG, Vaccari M, Castro FD, Prasad S, Rtimi S (2020) Emerging technologies for the recovery of rare earth elements (REEs) from the end-of-life electronic wastes: a review on progress, challenges, and perspectives. Environ Sci Pollut Res 27(29):36052–36074. https://doi.org/10.1007/s11356-020-09630-2

    Article  CAS  Google Scholar 

  13. Wang W, Pranolo Y, Cheng CY (2011) Metallurgical processes for scandium recovery from various resources: a review. Hydrometallurgy 108(1):100–108. https://doi.org/10.1016/j.hydromet.2011.03.001

    Article  CAS  Google Scholar 

  14. Zhang N, Li H-X, Liu X-M (2016) Recovery of scandium from bauxite residue—red mud: a review. Rare Met 35(12):887–900

    Article  CAS  Google Scholar 

  15. Wang W, Cheng CY (2011) Separation and purification of scandium by solvent extraction and related technologies: a review. J Chem Technol Biotechnol 86(10):1237–1246

    Article  CAS  Google Scholar 

  16. Liu Z, Li H (2015) Metallurgical process for valuable elements recovery from red mud—a review. Hydrometallurgy 155:29–43

    Article  CAS  Google Scholar 

  17. Shyam Sunder GS, Adhikari S, Rohanifar A, Poudel A, Kirchhoff JR (2020) Evolution of environmentally friendly strategies for metal extraction. Separations 7(1):4

    Article  Google Scholar 

  18. Salman AD, Juzsakova T, Ákos R, Ibrahim RI, Al-Mayyahi MA, Mohsen S, Abdullah TA, Domokos E (2021) Synthesis and surface modification of magnetic Fe3O4@SiO2 core-shell nanoparticles and its application in uptake of scandium (III) ions from aqueous media. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-020-12170-4

    Article  Google Scholar 

  19. Ashour RM, El-sayed R, Abdel-Magied AF, Abdel-khalek AA, Ali MM, Forsberg K, Uheida A, Muhammed M, Dutta J (2017) Selective separation of rare earth ions from aqueous solution using functionalized magnetite nanoparticles: kinetic and thermodynamic studies. Chem Eng J 327:286–296. https://doi.org/10.1016/j.cej.2017.06.101

    Article  CAS  Google Scholar 

  20. Mohammedi H, Miloudi H, Boos A, Bertagnolli C (2020) Lanthanide recovery by silica-Cyanex 272 material immobilized in alginate matrix. Environ Sci Pollut Res 27(21):26943–26953. https://doi.org/10.1007/s11356-020-08484-y

    Article  CAS  Google Scholar 

  21. Bradshaw J, Izatt R, Savage P, Bruening R, Krakowiak K (2000) The design of ion selective macrocycles and the solid-phase extraction of ions using molecular recognition technology: a synopsis. Supramol Chem 12:23–26. https://doi.org/10.1080/10610270008029802

    Article  CAS  Google Scholar 

  22. Makanyire T, Sanchez-Segado S, Jha A (2016) Separation and recovery of critical metal ions using ionic liquids. Adv Manuf 4(1):33–46. https://doi.org/10.1007/s40436-015-0132-3

    Article  CAS  Google Scholar 

  23. Liu Y, Gao Y, Wei Z, Zhou Y, Zhang M, Hou H, Tian G, He H (2018) Extraction behavior and third phase formation of neodymium(III) from nitric acid medium in N,N′-dimethyl-N,N′-dioctyl-3-oxadiglcolamide. J Radioanal Nucl Chem 318(3):2087–2096. https://doi.org/10.1007/s10967-018-6261-y

    Article  CAS  Google Scholar 

  24. Ruepert A, Keizer K, Steg L, Maricchiolo F, Carrus G, Dumitru A, García Mira R, Stancu A, Moza D (2016) Environmental considerations in the organizational context: a pathway to pro-environmental behaviour at work. Energy Res Soc Sci 17:59–70. https://doi.org/10.1016/j.erss.2016.04.004

    Article  Google Scholar 

  25. Hu J, Zou D, Chen J, Li D (2020) A novel synergistic extraction system for the recovery of scandium (III) by Cyanex272 and Cyanex923 in sulfuric acid medium. Sep Purif Technol 233:115977. https://doi.org/10.1016/j.seppur.2019.115977

    Article  CAS  Google Scholar 

  26. Yang Y, Arora G, Fernandez FA, Crawford JD, Surowiec K, Lee EK, Bartsch RA (2011) Lower-rim versus upper-rim functionalization in di-ionizable calix[4]arene-crown-5 isomers. Synthesis and divalent metal ion extraction. Tetrahedron 67(7):1389–1397. https://doi.org/10.1016/j.tet.2010.12.006

    Article  CAS  Google Scholar 

  27. Lakshmanan V, Vijayan S (2018) A review on application of crown ethers in separation of rare earths and precious metals: proceedings of the first global conference on extractive metallurgy, pp 1913–1930. https://doi.org/10.1007/978-3-319-95022-8_159

  28. Rounaghi GH, Mohajeri M, Doaei M, Ghaemi A (2010) Solvent influence upon complex formation between benzo-15-crown-5 and Mg2+, Ca2+ and Sr2+ cations in some pure and binary mixed solvents using conductometric method. J Incl Phenom Macrocycl Chem 67(3):443–450. https://doi.org/10.1007/s10847-009-9727-2

    Article  CAS  Google Scholar 

  29. Abdurrahmanoglu S, Gündüz C, Çakır Ü, Çiçek B, Bulut M (2005) The synthesis and complexation study of some coumestan and coumestan analog derivatives of crown ethers using conductometry. Dyes Pigm 65(3):197–204. https://doi.org/10.1016/j.dyepig.2004.07.011

    Article  CAS  Google Scholar 

  30. Kimura K, Shono T (1992) Chapter 4 - applications of crown compounds to analytical and separation chemistry: ion sensor and liquid chromatography. In: Hiraoka M (ed) Studies in organic chemistry, vol 45. Elsevier, Amsterdam, pp 198–264

    Google Scholar 

  31. Rounaghi GH, Mohajeri M, Tarahomi S, Rahmanian R (2011) Study of complex formation of dibenzo-18-crown-6 with Ce3+, Y3+, $\mathrm{UO}_{2}^{2 +}$ and Sr2+ cations in acetonitrile–dioxane binary solvent mixtures. J Solution Chem 40(3):377–389. https://doi.org/10.1007/s10953-011-9651-0

    Article  CAS  Google Scholar 

  32. Khayatian G, Salehi F (2006) Conductance and thermodynamic study of the complexation of ammonium ion with different crown ethers in binary nonaqueous solvents. J Chin Chem Soc. https://doi.org/10.1002/jccs.200800055

    Article  Google Scholar 

  33. Alivertis D, Paraskevopoulos G, Theodorou V, Skobridis K (2009) Dendritic effects of crown ether-functionalized dendrimers on the solvent extraction of metal ions. Tetrahedron Lett 50(44):6019–6021. https://doi.org/10.1016/j.tetlet.2009.08.053

    Article  CAS  Google Scholar 

  34. Pozzi G, Quici S, Fish RH (2008) Perfluorocarbon soluble crown ethers as phase transfer catalysts. Adv Synth Catal 350:2425–2436. https://doi.org/10.1002/adsc.200800393

    Article  CAS  Google Scholar 

  35. Rounaghi GH, Tarahomi S, Mohajeri M (2009) A conductometric study of complexation reaction between dibenzo-24-crown-8 with yttrium cation in some binary mixed non-aqueous solvents. J Incl Phenom Macrocycl Chem 63:319–325. https://doi.org/10.1007/s10847-008-9525-2

    Article  CAS  Google Scholar 

  36. Çiçek B, Yıldız A (2011) Synthesis, metal ion complexation and computational studies of thio oxocrown ethers. Molecules. https://doi.org/10.3390/molecules16108670

    Article  Google Scholar 

  37. Yongzhu J, Hirose K, Nakamura T, Nishioka R, Ueshige T, Tobe Y (2006) Preparation and evaluation of a chiral stationary phase covalently bound with a chiral pseudo-18-crown-6 ether having a phenolic hydroxy group for enantiomer separation of amino compounds. J Chromatogr A 1129(2):201–207. https://doi.org/10.1016/j.chroma.2006.07.003

    Article  CAS  Google Scholar 

  38. Salman AD, Juzsakova T, Jalhoom MG, Le Phuoc C, Mohsen S, Adnan Abdullah T, Zsirka B, Cretescu I, Domokos E, Stan CD (2020) Novel hybrid nanoparticles: synthesis, functionalization, characterization, and their application in the uptake of scandium (III) ions from aqueous media. Materials. https://doi.org/10.3390/ma13245727

    Article  Google Scholar 

  39. Shirikova A, Pasechnik L, Yatsenko S (2014) Prospects of application of microencapsulated extractants for extraction of scandium and rare-earth elements. Non-Ferrous Metals 1:41–44

    Google Scholar 

  40. Kostikova GV, Krasnova OG, Tsivadze AY, Zhilov VI (2018) Scandium extraction with benzo-15-crown-5 from neutral nitrate–trichloroacetate solutions. Russ J Inorg Chem 63(4):555–560. https://doi.org/10.1134/S0036023618040125

    Article  CAS  Google Scholar 

  41. Pyrzyńska K, Kilian K, Pęgier M (2019) Separation and purification of scandium: from industry to medicine. Sep Purif Rev 48(1):65–77. https://doi.org/10.1080/15422119.2018.1430589

    Article  CAS  Google Scholar 

  42. Marczenko Z, Balcerzak M (2000) Chapter 39 - rare-earth elements. In: Marczenko Z, Balcerzak M (eds) Analytical spectroscopy library, vol 10. Elsevier, Amsterdam, pp 341–349

    Google Scholar 

  43. Su J, Burnette R (2008) First principles investigation of noncovalent complexation: a [2.2.2]-cryptand ion-binding selectivity study. ChemPhysChem 9:1989–1996. https://doi.org/10.1002/cphc.200800376

    Article  CAS  Google Scholar 

  44. Hancock R (1986) Macrocycles and their selectivity for metal ions on the basis of size. Pure Appl Chem 58:1445–1452. https://doi.org/10.1351/pac198658111445

    Article  CAS  Google Scholar 

  45. Chekhlov AN (2003) Crystal structure of (2.2.2-cryptand)lithium perchlorate. Russ J Coord Chem 29(12):828–832. https://doi.org/10.1023/B:RUCO.0000008393.57920.7d

    Article  CAS  Google Scholar 

  46. Moeller T, Martin DF, Thompson LC, Ferrús R, Feistel GR, Randall WJ (1965) The coordination chemistry of yttrium and the rare earth metal ions. Chem Rev 65(1):1–50. https://doi.org/10.1021/cr60233a001

    Article  CAS  Google Scholar 

  47. Henderson P (2013) Rare earth element geochemistry. Elsevier, Amsterdam

    Google Scholar 

  48. Gongyi G, Yuli C, Yu L (1988) Solvent extraction off scandium from wolframite residue. JOM 40(7):28–31. https://doi.org/10.1007/BF03258146

    Article  Google Scholar 

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Acknowledgements

The authors would like to thank the Hungarian GINOP-2.2.1-15-2017-00106 project: “Complex utilization of red mud and recovery of rare earth metals from red mud” and project of The University of Danang B2019-DN03-40 for the generous support of the research.

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Authors and Affiliations

  1. Sustainability Solutions Research Lab, University of Pannonia, Veszprém, Hungary

    Ali Dawood Salman, Tatjána Juzsakova, Thamer Adnan Abdullah & Endre Domokos

  2. Department of Chemical and Petroleum Refining Engineering, College of Oil and Gas Engineering, Basra University, Basra, Iraq

    Ali Dawood Salman

  3. Department of Production Engineering and Minerals, University of Technology, Baghdad, Iraq

    Moayyed G. Jalhoom

  4. The University of Danang, University of Science and Technology, Danang, 550000, Vietnam

    Phuoc-Cuong Le

  5. Gheorghe Asachi Technical University of Iasi, Iasi, Romania

    Igor Cretescu

  6. Faculty of Biotechnology, Binh Duong University, Thu Dau Mot, Vietnam

    Van-Huy Nguyen

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  1. Ali Dawood Salman
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Salman, A.D., Juzsakova, T., Jalhoom, M.G. et al. Potential Application of Macrocyclic Compounds for Selective Recovery of Rare Earth Scandium Elements from Aqueous Media. J. Sustain. Metall. 8, 135–147 (2022). https://doi.org/10.1007/s40831-021-00484-7

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