Abstract
Amino acids have been categorized as green corrosion inhibitors due to their unique properties such as non-toxic and biodegradable nature. Considering its great importance in corrosion chemistry, studies were undertaken with an objective to find out the interaction behaviour of amino acids such as cysteine and alanine on corrosion inhibition of copper in 1 M sulfuric acid at varying temperatures such as 303, 308 and 313 K. Various techniques such as weight loss method, electrochemical impedance spectroscopy, potentiodynamic polarization (Tafel), basic computational calculations and adsorption studies were employed in the present investigations. Results revealed the synergic interaction of amino acids cysteine and alanine with attractive corrosion inhibition efficiency in 1 M concentration of sulfuric acid. The inhibition effect of amino acid cluster advanced with the increased concentration of the inhibitor. However, with the increase in temperature, the inhibition efficiency showed a declining trend. Such behaviour of the amino acids on copper in sulfuric acid medium may be due to surface adsorption of the inhibitor molecules on the metal which contributes to decrease in the double layer capacitance and increase in the polarization resistance.
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References
Khaled KF (2009) Experimental and atomistic simulation studies of corrosion inhibition of copper by a new benzotriazole derivative in acid medium. Electrochim Acta 54:4345–4352
Mihit M, Salghi R, El. Issami S, Bazzi L, Hammouti B, El. Ait A, Kertit S (2006) A study of tetrazoles derivatives as corrosion inhibitors of copper in nitric acid. Pigment Resin Technol 35:151–157
Dafali A, Hammouti B, Mokhlisse R, Kertit S (2003) Substituted uracils as corrosion inhibitor of copper in aerated 3% NaCl solution. Corros Sci 45:1619–1630
Kertit S, Salghi R, Bazzi L, Hammouti B, Bouchtart A (2000) Electrochemical behaviour of aluminum alloy 3003 in carbonate solution in the presence of pyrazolic compounds. Ann Chim Sci Mater 25:187–200
Li C, Li L, Wang C, Zhu Y, Zhang W (2014) Study of the protection performance of self-assembled monolayers on copper with the scanning electrochemical microscope. Corros Sci 80:511–516
Chen Z, Huang L, Zhang G, Qiu Y, Guo X (2012) Benzotriazole as a volatile corrosion inhibitor during the early stage of copper corrosion under adsorbed thin electrolyte layers. Corros Sci 65:214–222
Song P, Guo XY, Pan YC, Shen S, Sun Y, Wen Y, Yang HF (2013) Insight in cysteamine adsorption behaviours on the copper surface by electrochemistry and Raman spectroscopy. Electrochim Acta 89:503–509
Kuruvilla Mathew, John Sam, Joseph Abraham (2016) Electroanalytical studies on the interaction of l-serine-based schiff base, HHDMP, with copper in sulphuric acid. J Bio Tribo Corros 2:19–29
Kuruvilla M, John S, Joseph A (2013) Electrochemical studies on the interaction of l-cysteine with metallic copper in sulfuric acid. Res Chem Intermed 39:3531–3543
John Sam, Kuruvilla Mathew, Joseph Abraham (2013) Adsorption and inhibition effect of methyl carbamate on copper metal in 1N HNO3: an experimental and theoretical study. RSC Adv 3:8929–8938
Zhang DQ, Gao LX, Zhou GD (2005) Inhibition of copper corrosion in aerated hydrochloric acid solution by amino—acid compounds. J Appl Electrochem 35:1081–1085
Eddy NO, Awe FE, Gimba E, Ibisi NO, Ebenso EE (2011) QSAR, Experimental and computational chemistry simulation studies on the inhibition potential of some amino acids for the corrosion of mild steel in 0.1 M HCl. Int J Electrochem Sci 6:931–957
Fu JJ, Li SN, Wang Y, Liu XL, Lu LD (2011) Computational and electrochemical studies on the corrosion inhibition of mild steel by l-cysteine and its derivatives. J Mater Sci 46:3550–3559
Zhang DQ, Gao LX, Zhou GD (2003) Synergistic effect of 2-mercapto benzimidazole and KI on copper corrosion inhibition in aerated sulfuric acid solution. J Appl Electrochem 33:361–366
Bentiss F, Traisnel M, Lagrenee M (2001) Influence of 2, 5-bis(4 dimethylaminophenyl)-1, 3,4-thiadiazole on corrosion inhibition of mild steel in acidic media. J Appl Electrochem 31:41–48
Lee C, Yang W, Parr RG (1988) Development of the Colic-Salvetti correlation-energy formula into a functional of the electron density. Phys Rev B 37:789
Ignaczak JANF (1996) Gomes, interaction of halide ions with copper: the DFT approach. Chem Phys Lett 257:609–615
Lashkari M, Arshadi MR (2004) DFT studies of pyridine corrosion inhibitors in electrical double layer: solvent, substrate, and electric field effects. Chem Phys 299:131–137
Champion FA (1964) Corrosion testing procedure, 2nd edn. Chapman and Hall, London, p 32
Chetouani A, Hammouti B, Benhadda T, Daoudi M (2005) Inhibitive action of bipyrazolic type organic compounds towards corrosion of pure iron in acidic Media. Appl Surf Sci 249:375–385
El Mehdi B, Mernari B, Traisnel M, Bentiss F, Lagrenee M (2002) Synthesis and comparative study of the inhibitive effect of some new triazole derivatives towards corrosion of mild steel in hydrochloric acid solution. Mat Chem Phys 77:489–496
El Achouri M, Kertit S, Gouttaya HM, Nciri B, Bensouda Y, Perez L, Infante MR, Elkacemi K (2001) Corrosion inhibition of iron in 1 M HCl by some gemini surfactants in the series of alkanediyl—bis-(dimethyl tetradecyl ammonium bromide). Prog Org Coat 43:267–273
El Azhar M, Mernari B, Traisnel M, Bentiss F, Lagrenee M (2001) Corrosion Inhibition of mild steel by the new class of inhibitors [2,5-bis(n-pyridyl)-1,3,4-thiadiazoles] in acidic media. Corros Sci 43:2229–2238
Yurt A, Balaban A, Kandemir SU, Bereket G, Erk B (2004) Investigation on some Schiff bases as HCl corrosion inhibitors for carbon steel. Mater Chem Phys 85:420–426
Mistry Bhupendra M, Jauhari Smita (2013) Synthesis and evaluation of some quinoline Schiff bases as a corrosion inhibitor for mild steel in 1 N HCl. Res Chem Intermed 39:1049–1068
Ahamad I, Prasad R, Quraishi MA (2010) Inhibition of mild steel corrosion in acid solution by Pheniramine drug: Experimental and theoretical study. Corros Sci 52:3033–3041
Ahamad I, Prasad R, Quraishi MA (2010) Experimental and quantum chemical characterization of the adsorption of some Schiff base compounds of phthaloyl thiocarbohydrazide on the mild steel in acid solutions. Mater Chem Phys 124:1155–1165
Ferreira ES, Giancomelli C, Giacomelli FC, Spinelli A (2004) Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel. Mater Chem Phys 83:129–134
Kaan EC, Akay AA, Atakol O (2005) The corrosion inhibition of steel with Schiff base compounds in 2M HCl. Mat Chem Phys 93:325–329
Migahed A, Mohamed HM, Al-Sabagh AM (2003) Corrosion inhibition of H-11 type carbon steel in1 M Hydrochloric acid solution by N-propyl amino lauryl amide and its ethoxylated derivatives. Mat Chem Phys 80:169–175
Pearson RG (1988) Absolute electronegativity and hardness: application to inorganic chemistry. Inorg Chem 27:734–740
Pavithr MK, Venkatesh TV, Vathsal K, Nayan KO (2010) Synergistic effect of halide ions on improving corrosion inhibition behaviour of benzisothiozole-3-piperizine hydrochloride on mild steel in 0.5M H2SO4 medium. Corros Sci 52:3811–3819
Avci G (2008) Inhibitor effect of N, N-methylenediacrylamide on corrosion behavior of mild steel in 0.5 M HCl. Mater Chem Phys 112:234–238
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Financial support obtained from the University Grant Commission (UGC) for conducting the investigations is gratefully acknowledged.
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Kuruvilla, M., Prasad, A.R., John, S. et al. Enhanced Inhibition of the Corrosion of Metallic Copper Exposed in Sulphuric Acid Through the Synergistic Interaction of Cysteine and Alanine: Electrochemical and Computational Studies. J Bio Tribo Corros 3, 5 (2017). https://doi.org/10.1007/s40735-016-0064-x
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DOI: https://doi.org/10.1007/s40735-016-0064-x