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Structural characterization and luminescence properties of two 4d-4f Ln-Ag coordination compounds based on dinuclear lanthanide clusters

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Abstract

Two new compounds, [ErAg(INA)2(C2O4)]·2H2O(1)(HINA=nicotinic acid) and [Tb0.8Y0.2Ag2(IN)4·(H2O)5]·NO3·2H2O(2)(HIN=isonicotinic acid), based on the {2} building units, have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermal analysis and powder X-ray diffraction(PXRD). Single-crystal X-ray diffraction data reveal that both compounds crystallized in the low-symmetry triclinic space group P \(\mathop {\rm{1}}\limits^{\rm{ - }} \). Compound 1 is a 3D heterometallic coordination framework based on {Er2} clusters, oxalate ligands and bridging [Ag(INA)] linkers, while compound 2 consists of 0D [Tb0.8·Y0.2Ag2(IN)4(H2O)5]2 subunits that give a 3D supramolecular structure through hydrogen bond interaction. The photoluminescent properties of both compounds(1 and 2) were studied.

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Authors and Affiliations

  1. State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China

    Yu Zhang, Lei Chen, Weiwei Ju & Yan Xu

Authors
  1. Yu Zhang
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  2. Lei Chen
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  3. Weiwei Ju
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  4. Yan Xu
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Corresponding author

Correspondence to Yan Xu.

Additional information

Supported by the Natural Science Foundation of Jiangsu Province, China(No.BK2012823) and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Zhang, Y., Chen, L., Ju, W. et al. Structural characterization and luminescence properties of two 4d-4f Ln-Ag coordination compounds based on dinuclear lanthanide clusters. Chem. Res. Chin. Univ. 30, 194–199 (2014). https://doi.org/10.1007/s40242-014-3368-8

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  • DOI: https://doi.org/10.1007/s40242-014-3368-8

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