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Ruthenium complex immobilized on mesoporous silica as recyclable heterogeneous catalyst for visible light photocatalysis

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Abstract

Aldehyde group-functionalized [Ru(bpy)2L](PF6)2 catalyst was prepared and immobilized onto the mesoporous silica nanoparticles to act as a heterogeneous catalyst for the selective oxidation of thioanisole to methyl phenyl sulfoxide under visible light. The heterogeneous catalyst can be easily recovered by simple centrifugation without chemical treatment, exhibiting comparable catalytic efficiency with homogeneous ones and no decrease in catalytic efficiency after at least 5 cycles.

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Authors and Affiliations

  1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China

    Hongyan He, Zhigang Xie, Xiabin Jing & Yubin Huang

  2. University of Chinese Academy of Sciences, Beijing, 100049, P. R. China

    Hongyan He

  3. School of Life Sciences, Northeast Normal University, Changchun, 130024, P. R. China

    Wenliang Li

Authors
  1. Hongyan He
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  2. Wenliang Li
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  3. Zhigang Xie
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  4. Xiabin Jing
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  5. Yubin Huang
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Corresponding author

Correspondence to Yubin Huang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.51021003, 51273194, 21104075, 21174143).

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He, H., Li, W., Xie, Z. et al. Ruthenium complex immobilized on mesoporous silica as recyclable heterogeneous catalyst for visible light photocatalysis. Chem. Res. Chin. Univ. 30, 310–314 (2014). https://doi.org/10.1007/s40242-014-3367-9

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  • DOI: https://doi.org/10.1007/s40242-014-3367-9

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