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Photochemistry and Photophysics of Coordination Compounds: Ruthenium

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Photochemistry and Photophysics of Coordination Compounds I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 280))

Abstract

Ruthenium compounds, particularly Ru(II) polypyridine complexes, are the class of transition metal complexes which has been most deeply investigated from a photochemical viewpoint. The reason for such great interest stems from a unique combination of chemical stability, redox properties, excited-state reactivity, luminescence emission, and excited-state lifetime. Ruthenium polypyridine complexes are indeed good visible light absorbers, feature relatively intense and long-lived luminescence, and can undergo reversible redox processes in both the ground and excited states. This chapter presents some general concepts on the photochemical properties of Ru(II) polypyridine complexes and gives an overview of various research topics involving ruthenium photochemistry which have emerged in the last 15 years. In particular, aspects connected to supramolecular photochemistry and photophysics are discussed, such as multicomponent systems for light harvesting and photoinduced charge separation, systems for photoinduced multielectron/hole storage, and photocatalytic processes based on supramolecular Ru(II) polypyridine species. Interaction with biological systems and dye-sensitized photoelectrochemical cells are also briefly discussed.

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Authors and Affiliations

  1. Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Via Sperone 31, 98166, Messina, Italy

    Sebastiano Campagna, Fausto Puntoriero & Francesco Nastasi

  2. Dipartimento di Chimica “G. Ciamician”, Università di Bologna, Via Selmi 2, 40126, Bologna, Italy

    Giacomo Bergamini & Vincenzo Balzani

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  1. Sebastiano Campagna
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  2. Fausto Puntoriero
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  3. Francesco Nastasi
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  4. Giacomo Bergamini
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  5. Vincenzo Balzani
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Correspondence to Sebastiano Campagna .

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Vincenzo Balzani Sebastiano Campagna

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Campagna, S., Puntoriero, F., Nastasi, F., Bergamini, G., Balzani, V. (2007). Photochemistry and Photophysics of Coordination Compounds: Ruthenium. In: Balzani, V., Campagna, S. (eds) Photochemistry and Photophysics of Coordination Compounds I. Topics in Current Chemistry, vol 280. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2007_133

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