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Role of tailored surface of activated carbon for adsorption of ionic liquids for environmental remediation

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Abstract

The surface of activated carbon (AC) was oxidized using different oxidizing agents (nitric acid and sodium hypochlorite). This modified AC (mAC) was used for the adsorption of ionic liquids (ILs). These mACs were characterized before and after adsorption of ILs using different techniques. The surface area of AC decreased after oxidation, but total acidity increased as compared to untreated AC. The pH of point zero charge of ACs was also decreased after oxidation. The role of adsorbents and its interaction with ILs have been investigated using batch adsorption experiments. Both the alkyl chain length and cation type of ILs affected their adsorption onto ACs; long alkyl chain showed higher adsorption. The pH study showed higher adsorption at higher pH as compared to lower pH value. The pseudo-second-order model was best fitted to the kinetic adsorption data, and Langmuir isotherm model was best fitted on isotherm data. The overall adsorption process was controlled by intra-particle diffusion and external mass transfer. The adsorption results obtained in this study showed comparably higher value with published literature.

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References

  • Ai L, Zhang C, Liao F, Wang Y, Li M, Meng L, Meng L, Jiang J (2011) Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. J Hazard Mater 198:282–290

    Article  CAS  Google Scholar 

  • Apul OG, Shao T, Zhang S, Karanfil T (2012) Impact of carbon nanotube morphology on phenanthrene adsorption. Environ Toxicol Chem 31:73–78

    Article  CAS  Google Scholar 

  • Armand M, Endres F, MacFarlane DR, Ohno H, Scrosati B (2009) Ionic-liquid materials for the electrochemical challenges of the future. Nature Mater 8:621–629

    Article  CAS  Google Scholar 

  • Biniak S, Szymański G, Siedlewski J, Swiatkowski A (1997) The characterization of activated carbons with oxygen and nitrogen surface groups. Carbon 35:1799–1810

    Article  CAS  Google Scholar 

  • Biniak S, Pakula M, Szymanski GS, Swiatkowski A (1999) Effect of activated carbon surface oxygen-and/or nitrogen-containing groups on adsorption of copper (II) ions from aqueous solution. Langmuir 15:6117–6122

    Article  CAS  Google Scholar 

  • Boehm HP (1994) Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 32:759–769

    Article  CAS  Google Scholar 

  • Chien SH, Clayton WR (1980) Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci Soc Am J 44:265–268

    Article  CAS  Google Scholar 

  • Claudio AFM, Freire MG, Freire CS, Silvestre AJ, Coutinho JA (2010) Extraction of vanillin using ionic-liquid-based aqueous two-phase systems. Sep Purif Technol 75:39–47

    Article  CAS  Google Scholar 

  • Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Plenum Press, New York

    Book  Google Scholar 

  • Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresource Technol 97:1061–1085

    Article  CAS  Google Scholar 

  • Dogan M, Abak H, Alkan M (2009) Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. J Hazard Mater 164:172–181

    Article  CAS  Google Scholar 

  • Donnet JB, Bansal RC (1990) Carbon fibers, 2nd edn. Wiley Online Library, New York Marcel Dekker

  • Donnet J, Ehrburger P (1977) Carbon fibre in polymer reinforcement. Carbon 15:143–152

    Article  CAS  Google Scholar 

  • Ermolenko IN, Lyubliner I, Gulko NV (1990) Chemically modified carbon fibers and their applications. VCH Weinheim, Germany

    Google Scholar 

  • Faria PCC, Orfao JJM, Pereira MFR (2004) Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res 38:2043–2052

    Article  CAS  Google Scholar 

  • Farooq A, Reinert L, Leveque J-M, Papaiconomou N, Irfan N, Duclaux L (2012) Adsorption of ionic liquids onto activated carbons: effect of pH and temperature. Micropor Mesopor Mat 158:55–63

    Article  CAS  Google Scholar 

  • Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM (1999) Modification of the surface chemistry of activated carbons. Carbon 37:1379–1389

    Article  CAS  Google Scholar 

  • Franz M, Arafat HA, Pinto NG (2000) Effect of chemical surface heterogeneity on the adsorption mechanism of dissolved aromatics on activated carbon. Carbon 38:1807–1819

    Article  CAS  Google Scholar 

  • Ghaedi M, Hassanzadeh A, Kokhdan SN (2011) Multiwalled carbon nanotubes as adsorbents for the kinetic and equilibrium study of the removal of Alizarin Red S and Morin. J Chem Eng Data 56:2511–2520

    Article  CAS  Google Scholar 

  • Ghaedi M, Ansari A, Habibi M, Asghari A (2014) Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: kinetics and isotherm study. J Ind Eng Chem 20:17–28

    Article  CAS  Google Scholar 

  • Giles CH, Smith D, Huitson A (1974) A general treatment and classification of the solute adsorption isotherm. I. Theoretical. J Colloid Interf Sci 47:755–765

    Article  CAS  Google Scholar 

  • Gupta VK, Mittal A, Gajbe V, Mittal J (2008) Adsorption of basic fuchsin using waste materials-bottom ash and deoiled soya-as adsorbents. J Colloid Interf Sci 319:30–39

    Article  CAS  Google Scholar 

  • Han X, Armstrong DW (2007) Ionic liquids in separations. Acc Chem Res 40:1079–1086

    Article  CAS  Google Scholar 

  • Hanumantharao Y, Kishore M, Ravindhranath K (2012) Characterization and defluoridation studies of active carbon derived from typha angustata plants. J Adhes Sci Technol 3:167–181

    CAS  Google Scholar 

  • Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–124

    Article  CAS  Google Scholar 

  • Ho Y-S, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465

    Article  CAS  Google Scholar 

  • Ip A, Barford J, McKay G (2008) Production and comparison of high surface area bamboo derived active carbons. Bioresource Technol 99:8909–8916

    Article  CAS  Google Scholar 

  • Jiang Z, Liu Y, Sun X, Tian F, Sun F, Liang C et al (2003) Activated carbons chemically modified by concentrated H2SO4 for the adsorption of the pollutants from wastewater and the dibenzothiophene from fuel oils. Langmuir 19:731–736

    Article  CAS  Google Scholar 

  • Kumar KV, Ramamurthi V, Sivanesan S (2005) Modeling the mechanism involved during the sorption of methylene blue onto fly ash. J Colloid Interf Sci 284:14–21

    Article  CAS  Google Scholar 

  • Kutics K, Suzuki M (1990) Adsorption of organics on surface modified activated carbon fibers. In: The 2nd Korea–Japan symposium on separation technology, Korea-Japan, pp 1–2

  • Lemus J, Palomar J, Heras F, Gilarranz MA, Rodriguez JJ (2012) Developing criteria for the recovery of ionic liquids from aqueous phase by adsorption with activated carbon. Sep Purif Technol 97:11–19

    Article  CAS  Google Scholar 

  • Lisovskii A, Semiat R, Aharoni C (1997) Adsorption of sulfur dioxide by active carbon treated by nitric acid: I. effect of the treatment on adsorption of SO2 and extractability of the acid formed. Carbon 35:1639–1643

    Article  CAS  Google Scholar 

  • Lopez-Ramon M, Stoeckli F, Moreno-Castilla C, Carrasco-Marin F (1999) On the characterization of acidic and basic surface sites on carbons by various techniques. Carbon 37:1215–1221

    Article  CAS  Google Scholar 

  • Mattson JA, Mark HB, Malbin MD, Weber WJ, Crittenden JC (1969) Surface chemistry of active carbon: specific adsorption of phenols. J Colloid Interf Sci 31:116–130

    Article  CAS  Google Scholar 

  • Migowski P, Dupont J (2007) Catalytic applications of metal nanoparticles in imidazolium ionic liquids. Chem Eur J 13:32–39

    Article  CAS  Google Scholar 

  • Mohamed AR, Mohammadi M, Darzi GN (2010) Preparation of carbon molecular sieve from lignocellulosic biomass: a review. Renew Sust Energ Rev 14:1591–1599

    Article  CAS  Google Scholar 

  • Moreno-Castilla C, Carrasco-Marin F, Maldonado-Hodar FJ, Rivera-Utrilla J (1998) Effects of non-oxidant and oxidant acid treatments on the surface properties of an activated carbon with very low ash content. Carbon 36:145–151

    Article  CAS  Google Scholar 

  • Moreno-Castilla C, Lopez-Ramon M, Carrasco-Marın F (2000) Changes in surface chemistry of activated carbons by wet oxidation. Carbon 38:1995–2001

    Article  CAS  Google Scholar 

  • Neves CM, Lemus J, Freire MG, Palomar J, Coutinho JA (2014) Enhancing the adsorption of ionic liquids onto activated carbon by the addition of inorganic salts. Chem Eng J 252:305–310

    Article  CAS  Google Scholar 

  • Olivier-Bourbigou H, Magna L, Morvan D (2010) Ionic liquids and catalysis: recent progress from knowledge to applications. Appl Catal A-Gen 373:1–56

    Article  CAS  Google Scholar 

  • Palomar J, Lemus J, Gilarranz M, Rodriguez J (2009a) Adsorption of ionic liquids from aqueous effluents by activated carbon. Carbon 47:1846–1856

    Article  CAS  Google Scholar 

  • Palomar J, Lemus J, Gilarranz MA, Rodriguez JJ (2009b) Adsorption of ionic liquids from aqueous effluents by activated carbon. Carbon 47:1846–1856

    Article  CAS  Google Scholar 

  • Park S-J, Kim M-H (2000) Effect of acidic anode treatment on carbon fibers for increasing fiber-matrix adhesion and its relationship to interlaminar shear strength of composites. J Mater Sci 35:1901–1905

    Article  CAS  Google Scholar 

  • Peebles LH (1995) Formation, structure, and properties. In: Carbon fibers. CRC Press, Boca Raton, FL

  • Pittman CU, He GR, Wu B, Gardner SD (1997) Chemical modification of carbon fiber surfaces by nitric acid oxidation followed by reaction with tetraethylenepentamine. Carbon 35:317–331

    Article  CAS  Google Scholar 

  • Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150

    Article  CAS  Google Scholar 

  • Radovic LR, Silva IF, Ume JI, Menéndez JA, Leon CALY, Scaroni AW (1997) An experimental and theoretical study of the adsorption of aromatics possessing electron-withdrawing and electron-donating functional groups by chemically modified activated carbons. Carbon 35:1339–1348

  • Rengaraj S, Kim Y, Joo CK, Yi J (2004) Removal of copper from aqueous solution by aminated and protonated mesoporous aluminas: kinetics and equilibrium. J Colloid Interf Sci 273:14–21

    Article  CAS  Google Scholar 

  • Roosta M, Ghaedi M, Daneshfar A, Sahraei R (2014a) Experimental design based response surface methodology optimization of ultrasonic assisted adsorption of safaranin O by tin sulfide nanoparticle loaded on activated carbon. Spectrochim Acta A 122:223–231

    Article  CAS  Google Scholar 

  • Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Asghari A (2014b) Optimization of the ultrasonic assisted removal of methylene blue by gold nanoparticles loaded on activated carbon using experimental design methodology. Ultrason Sonochem 21:242–252

    Article  CAS  Google Scholar 

  • Roosta M, Ghaedi M, Shokri N, Daneshfar A, Sahraei R, Asghari A (2014c) Optimization of the combined ultrasonic assisted/adsorption method for the removal of malachite green by gold nanoparticles loaded on activated carbon: experimental design. Spectrochim Acta A 118:55–65

    Article  CAS  Google Scholar 

  • Sankar M, Sekaran G, Sadulla S, Ramasami T (1999) Removal of diazo and triphenylmethane dyes from aqueous solutions through an adsorption process. J Chem Technol Biotechnol 74:337–344

    Article  CAS  Google Scholar 

  • Shim J-W, Park S-J, Ryu S-K (2001) Effect of modification with HNO3 and NaOH on metal adsorption by pitch-based activated carbon fibers. Carbon 39:1635–1642

    Article  CAS  Google Scholar 

  • Sonawane GH, Shrivastava VS (2011) Orange-II removal from simulated wastewater by adsorption using Annona squamosa shell-A kinetic and equilibrium studies. Desalin Water Treat 36:374–382

    Article  CAS  Google Scholar 

  • van Rantwijk F, Sheldon RA (2007) Biocatalysis in ionic liquids. Chem Rev 107:2757–2785

    Article  Google Scholar 

  • Wasserscheid P, Welton T (2008) Ionic liquids in synthesis. Wiley. doi:10.1002/9783527621194

    Google Scholar 

  • Weast RC (1990) Handbook of chemistry and physics, 70th edn. CRC Press, Boca Raton, Florida

  • Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div Am Soc Civ Eng 89:31–60

    Google Scholar 

  • Xu B, Wu F, Chen R, Cao G, Chen S, Yang Y (2010) Mesoporous activated carbon fiber as electrode material for high-performance electrochemical double layer capacitors with ionic liquid electrolyte. J Power Sources 195:2118–2124

    Article  CAS  Google Scholar 

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Acknowledgments

One of the authors Safia Hassan is highly obliged to Higher Education Commission of Pakistan for granting her research scholarship.

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  1. Pakistan Institute of Engineering and Applied Sciences (PIEAS), P. O. Nilore, Islamabad, 45650, Pakistan

    S. Hassan & T. Yasin

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  1. S. Hassan
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Correspondence to S. Hassan.

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Hassan, S., Yasin, T. Role of tailored surface of activated carbon for adsorption of ionic liquids for environmental remediation. Int. J. Environ. Sci. Technol. 12, 2711–2722 (2015). https://doi.org/10.1007/s13762-014-0678-9

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  • DOI: https://doi.org/10.1007/s13762-014-0678-9

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