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Trityl bromide versus nano-magnetic catalyst in the synthesis of henna-based xanthenes and bis-coumarins

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Abstract

In this work, trityl bromide (TrBr) as a new, efficient, mild and neutral catalyst was used for the synthesis of henna-based xanthenes (aryl-5H-dibenzo[b,i]xanthene-5,7,12,14(13H)-tetraones) and bis-coumarins by in situ generation of trityl carbocation under solvent-free conditions in comparison with [Fe3O4@SiO2@(CH2)3-Im-SO3H]Cl as an acidic and reusable catalyst for the first time.

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Acknowledgements

We thank Bu-Ali Sina University and Iran National Science Foundation (INSF) for financial support (The Grant Number: 940124) to our research group.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Mahmoud Zarei, Mohammad Ali Zolfigol & Ehsan Noroozizadeh

  2. Sayyed Jamaleddin Asadabadi University, Asadabad, 6541835583, Iran

    Ahmad Reza Moosavi-Zare

Authors
  1. Mahmoud Zarei
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  2. Mohammad Ali Zolfigol
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  3. Ahmad Reza Moosavi-Zare
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  4. Ehsan Noroozizadeh
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Correspondence to Mahmoud Zarei, Mohammad Ali Zolfigol or Ahmad Reza Moosavi-Zare.

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Zarei, M., Zolfigol, M.A., Moosavi-Zare, A.R. et al. Trityl bromide versus nano-magnetic catalyst in the synthesis of henna-based xanthenes and bis-coumarins. J IRAN CHEM SOC 14, 2187–2198 (2017). https://doi.org/10.1007/s13738-017-1155-4

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