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Urea-functionalized silica-coated Fe3−x Ti x O4 magnetic nanoparticles: as highly efficient and recyclable heterogeneous nanocatalyst for synthesis of 4H-chromene and 1H-pyrazolo[1,2-b]phthalazine-5,10-dione derivatives

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Abstract

Novel urea-functionalized silica-coated magnetic core–shell Fe3−x Ti x O4 nanoparticles were prepared and fully characterized by different methods such as Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, vibrating sample magnetometer, X-ray diffraction, and thermogravimetric analyses. These magnetic nanoparticles have been explored as highly efficient and recoverable heterogeneous nanocatalyst for one-pot three-component reactions under mild conditions for the synthesis of diverse range of 5-oxo-dihydropyrano[3,2-c]chromenes known as coumarins and 1H-pyrazolo[1,2-b] phthalazine-5,10-diones in high yields. Simple isolation of the products, use of green solvent, and magnetically easy isolation and reusability of the catalyst with no significant loss of activity are the main advantages of the present method.

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Acknowledgments

The authors wish to thank the Research Council of Bu-Ali Sina University for financial support to carry out this research.

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Authors and Affiliations

  1. Department of Chemistry, Bu-Ali Sina University, Hamedan, 65178, Iran

    Davood Azarifar, Omolbanin Badalkhani, Younes Abbasi & Morteza Hasanabadi

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  1. Davood Azarifar
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  2. Omolbanin Badalkhani
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Correspondence to Davood Azarifar.

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Azarifar, D., Badalkhani, O., Abbasi, Y. et al. Urea-functionalized silica-coated Fe3−x Ti x O4 magnetic nanoparticles: as highly efficient and recyclable heterogeneous nanocatalyst for synthesis of 4H-chromene and 1H-pyrazolo[1,2-b]phthalazine-5,10-dione derivatives. J IRAN CHEM SOC 14, 403–418 (2017). https://doi.org/10.1007/s13738-016-0989-5

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