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Solvent-free chemoselective oxidation of alcohols by hydrogen peroxide using a new synthesized copper complex as reusable heterogeneous nanocatalyst

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Abstract

Single crystal of a new copper(II) Schiff base complex [Cu(HL)(H2O)NO3] (1) (H2L = {2-[(2-hydroxy-1,1-dimethyl-ethylimino)methyl]phenol}) and its nanostructure have been synthesized by slow evaporation of a methanol solution and sonochemical process, respectively. The structure of complex 1 was determined by FTIR, UV–Visible spectra and single-crystal X-ray diffraction. Nanostructure of the complex was characterized by X-ray powder diffraction (XRD), FTIR spectroscopy and scanning electron microscopy (SEM). The synthesized complex was successfully applied as a new chemoselective and recyclable heterogeneous catalyst for the selective oxidation of alcohols to the corresponding carbonyl compounds in the presence of H2O2 as a green oxidant under solvent-free conditions. A suitable mechanism for the reaction is proposed.

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Acknowledgments

The support of this work by Vali-e-Asr University of Rafsanjan is acknowledged. The authors also thank Dr. Atena Naeimi from Jiroft University for her valuable helps.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Vali-e-Asr University of Rafsanjan, 77188-97111, Rafsanjan, Iran

    S. Saeednia, M. Hatefi Ardakani & S. Sinaei

  2. Department of Nuclear Medicine and Molecular Imaging, Razavi Hospital, 9198613676, Mashhad, Iran

    Z. Pakdin-Parizi

  3. Department of Physics, Faculty of Science, Vali-e-Asr University of Rafsanjan, 77188-97111, Rafsanjan, Iran

    P. Iranmanesh

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  1. S. Saeednia
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  2. M. Hatefi Ardakani
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Correspondence to S. Saeednia.

Electronic supplementary material

Below is the link to the electronic supplementary material.

13738_2016_913_MOESM1_ESM.doc

CCDC 1043827 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk. (DOC 274 kb)

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Saeednia, S., Hatefi Ardakani, M., Pakdin-Parizi, Z. et al. Solvent-free chemoselective oxidation of alcohols by hydrogen peroxide using a new synthesized copper complex as reusable heterogeneous nanocatalyst. J IRAN CHEM SOC 13, 1963–1975 (2016). https://doi.org/10.1007/s13738-016-0913-z

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  • DOI: https://doi.org/10.1007/s13738-016-0913-z

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