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Mononuclear and dinuclear indium(III) complexes containing methoxy and hydroxy-bridge groups, nitrate anion and 4,4′-dimethyl-2,2′-bipyridine ligand: synthesis, characterization, crystal structure determination, luminescent properties, and thermal analyses

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Abstract

[In(4,4′-dmbipy)(η2-NO3)2(η-NO3)(H2O)] complex (1) and [{In(4,4′-dmbipy)(η2-NO3)2}2(µ-OCH3)2] complex (2) (4,4′-dmbipy is 4,4′-dimethyl-2,2′-bipyridine) were prepared from the reaction of In(NO3)3·4H2O with 4,4′-dmbipy in CH3CN and CH3OH, respectively. [{In(4,4′-dmbipy)(η2-NO3)(η-NO3)}2(µ-OH)2] complex (3) was also prepared from the reaction of InCl3·4H2O with 4,4′-dmbipy in mixture of CH3CN/H2O in 3:1 ratio. These complexes were characterized by elemental analysis, IR, 1H NMR, 13C{1H}NMR, UV–Vis, and luminescence spectroscopy and their structures were studied by single-crystal X-ray diffraction method. Compound 1 is an eight-coordinated mononuclear complex, compound 2 is an eight-coordinated centrosymmetric dinuclear complex with two methoxy-bridges, and compound 3 is a seven-coordinated C2-symmetric dinuclear complex with two hydroxy-bridges. Also, the thermal stabilities of 1–3 were studied by thermogravimetric (TG) and differential thermal analyses (DTA).

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Acknowledgments

The authors gratefully acknowledge the financial and other support of the research entitled “Synthesis, characterization, crystal structure and photoluminescence properties of Indium(III) nitrate complexes with bipyridine derivates” provided by the Islamic Azad University, Islamshahr Branch, Tehran, Iran.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Islamshahr Branch, Islamic Azad University, Tehran, Iran

    Akram Sadat Delbari & Vida Jodaian

  2. Department of Chemistry, Shahre-Rey Branch, Islamic Azad University, Tehran, Iran

    Ashraf Sadat Shahvelayati & Vahid Amani

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  1. Akram Sadat Delbari
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  2. Ashraf Sadat Shahvelayati
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  4. Vahid Amani
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Correspondence to Akram Sadat Delbari or Vahid Amani.

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Delbari, A.S., Shahvelayati, A.S., Jodaian, V. et al. Mononuclear and dinuclear indium(III) complexes containing methoxy and hydroxy-bridge groups, nitrate anion and 4,4′-dimethyl-2,2′-bipyridine ligand: synthesis, characterization, crystal structure determination, luminescent properties, and thermal analyses. J IRAN CHEM SOC 12, 223–232 (2015). https://doi.org/10.1007/s13738-014-0477-8

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