Skip to main content
Log in

Effect of graphite fillers on woven bamboo fiber-reinforced epoxy hybrid composites for semistructural applications: fabrication and characterization

  • Original Article
  • Published:
Biomass Conversion and Biorefinery Aims and scope Submit manuscript

Abstract

In this work, the effect of graphite nanoparticles on the thermal, mechanical, physical, and fatigue properties of woven bamboo fiber hybrid composites was investigated. Different weight fractions of graphite nanoparticles are incorporated into the epoxy matrix to produce hybrid composites containing three layers of bamboo fiber/graphite using the hand layup method. The prepared samples are characterized using mechanical, thermal, and physical properties to understand the synergistic effects of hybridization. Results from the study show that the properties of the hybrid composites are improved with the addition of secondary reinforcement. For instance, the addition of graphite nanoparticles has improved the tensile strength, flexural strength, and impact properties up to 32.78%, 27.37%, and 172.4%, respectively. Further, TGA, DMA, and TMA experiments show that the thermal properties of the produced composites are improved with filler loading. The water contact angle studies show that the hydrophilic values increase from 54.4 to 74.5 with the increase in graphite particulates. Finally, fatigue properties represent the long-term stability of the composites under cyclic loading.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. Saba N, Jawaid M, Asim M (2016) Recent advances in nanoclay/natural fibers hybrid composites. Nanoclay reinforced polymer composites:1–28

  2. Saba N, Paridah MT, Abdan K, Ibrahim NA (2016) Dynamic mechanical properties of oil palm nano filler/kenaf/epoxy hybrid nanocomposites. Construct Build Mater 124:133–138

    Article  Google Scholar 

  3. Eng CC, Ibrahim NA, Zainuddin N, Ariffin H, Yunus WM, Wan Z, Then YY (2014) Enhancement of mechanical and dynamic mechanical properties of hydrophilic nanoclay reinforced polylactic acid/polycaprolactone/oil palm mesocarp fiber hybrid composites. Int J Polym Sci 715801

  4. Prasob PA, Sasikumar M (2019) Viscoelastic and mechanical behaviour of reduced graphene oxide and zirconium dioxide filled jute/epoxy composites at different temperature conditions. Mater Today Commun 19:252–261

    Article  Google Scholar 

  5. Anandjiwala RD, Blouw S (2007) Composites from bast fibres-prospects and potential in the changing market environment. J Nat Fibers 4(2):91–109

    Article  Google Scholar 

  6. Mittal V, Saini R, Sinha S (2016) Natural fiber-mediated epoxy composites–a review. Compos Part B Eng 99:425–435

    Article  Google Scholar 

  7. Radouane N, Depriester M, Maaroufi A, Singh DP, Ouaki B, Duponchel B, Elass A, Tidahy L, Hadj-Sahraoui A (2021) Synthesis, mechanical, thermal, and electrical characterization of graphite–epoxy composites. J Chin Chem Soc 68(8):1456–1465

    Article  Google Scholar 

  8. Skoda M, Dudek I, Jarosz A, Szukiewicz D (2014) Graphene: one material, many possibilities-application difficulties in biological systems. J Nanomater 890246

  9. Yao SS, Jiang D, Zhang QZ, Wang XX (2020) Preparation and properties of graphite/epoxy resin conductive composites. IOP Conf Ser: Mater Sci Eng 740:012064

    Article  Google Scholar 

  10. Mouritz AP (2012) Manufacturing of fibre–polymer composite materials. Introduction to aerospace materials 10:303–337

    Google Scholar 

  11. Gantayat S, Prusty G, Rout DR, Swain SK (2015) Expanded graphite as a filler for epoxy matrix composites to improve their thermal, mechanical and electrical properties. New Carbon Materials 30(5):432–437

    Article  Google Scholar 

  12. Lv R, Ren Y, Guo H, Bai S (2021) Recent progress on thermal conductivity of graphene filled epoxy composites. Nano. Mater Sci Forum

  13. Khan Z, Yousif BF, Islam M (2017) Fracture behaviour of bamboo fiber reinforced epoxy composites. Compos Part B Eng 116:186–199

    Article  Google Scholar 

  14. Zhang K, Wang F, Liang W, Wang Z, Duan Z, Yang B (2018) Thermal and mechanical properties of bamboo fiber reinforced epoxy composites. Polymers 10(6):608

    Article  Google Scholar 

  15. Long H, Wu Z, Dong Q, Shen Y, Zhou W, Luo Y, Zhang C, Dong X (2019) Effect of polyethylene glycol on mechanical properties of bamboo fiber-reinforced polylactic acid composites. J Appl Polym Sci 136(26):47709

    Article  Google Scholar 

  16. Wang Q, Zhang Y, Liang W, Wang J, Chen Y (2020) Improved mechanical properties of the graphene oxide modified bamboo fiber reinforced polypropylene composites. Polym Compos 41(9):3615–3626

    Article  Google Scholar 

  17. Ansari R, Torabi J, Shojaei MF (2017) Buckling and vibration analysis of embedded functionally graded carbon nanotube-reinforced composite annular sector plates under thermal loading. Compos Part B Eng 109:197–213

    Article  Google Scholar 

  18. Arefi M, Soltan Arani AH (2018) Higher order shear deformation bending results of a magnetoelectrothermoelastic functionally graded nanobeam in thermal, mechanical, electrical, and magnetic environments. Mech Based Des Struct Mach 46(6):669–692

    Article  Google Scholar 

  19. Farzam A, Hassani B (2018) Thermal and mechanical buckling analysis of FG carbon nanotube reinforced composite plates using modified couple stress theory and isogeometric approach. Composite Structures 206:774–790

    Article  Google Scholar 

  20. Torabi J, Ansari R, Hassani R (2019) Numerical study on the thermal buckling analysis of CNT-reinforced composite plates with different shapes based on the higher-order shear deformation theory. Eur J Mech A Solids 73:144–160

    Article  MATH  Google Scholar 

  21. Kim BC, Park SW (2008) Fracture toughness of the nano-particle reinforced epoxy composite. Composite structures 86(1-3):69–77

    Article  Google Scholar 

  22. Nayak RK, Dash A, Ray BC (2014) Effect of epoxy modifiers (Al2O3/SiO2/TiO2) on mechanical performance of epoxy/glass fiber hybrid composites. Procedia Mater Sci 6:1359–1364

    Article  Google Scholar 

  23. McGrath LM, Parnas RS, King SH, Schroeder JL, Fischer DA, Lenhart JL (2008) Investigation of the thermal, mechanical, and fracture properties of alumina–epoxy composites. Polymer 49(4):999–1014

    Article  Google Scholar 

  24. Kamarian S, Bodaghi M, Isfahani RB, Shakeri M, Yas MH (2021) Influence of carbon nanotubes on thermal expansion coefficient and thermal buckling of polymer composite plates: experimental and numerical investigations. Mech Based Des Struct Mach 49(2):217–232

    Article  Google Scholar 

  25. El Oudiani A, Chaabouni Y, Msahli S, Sakli F (2011) Crystal transition from cellulose I to cellulose II in NaOH treated Agave americana L. fibre. Carbohydr Polym 86(3):1221–1229

    Article  Google Scholar 

  26. Hu M, Wang C, Lu C, Anuar NIS, Yousfani SHS, Jing M, Chen Z, Zakaria S, Zuo H (2019) Investigation on the classified extraction of the bamboo fiber and its properties. J Nat Fibers 17:1798–1808

    Article  Google Scholar 

  27. Madhu P, Mavinkere Rangappa S, Khan A, Al Otaibi A, Al-Zahrani SA, Pradeep S, Gupta MK, Boonyasopon P, Siengchin S (2020) Experimental investigation on the mechanical and morphological behavior of Prosopis juliflora bark fibers/E-glass/carbon fabrics reinforced hybrid polymeric composites for structural applications. Polym Compos 41(12):4983–4993

    Article  Google Scholar 

  28. Ashok KG, Kalaichelvan K, Damodaran A (2022) Effect of nano fillers on mechanical properties of luffa fiber epoxy composites. J Nat Fibers 19(4):1472–1489

    Article  Google Scholar 

  29. Reddy KM, Vardhan DH, Reddy Y, Raghavendra G, Rudrapati R (2021) Experimental study of thermal and mechanical behaviour of graphite-filled UJF composite. Adv Mater Sci Eng 2021

  30. Suresha B, Chandramohan G, Renukappa NM (2007) Mechanical and tribological properties of glass–epoxy composites with and without graphite particulate filler. J Appl Polym Sci 103(4):2472–2480

    Article  Google Scholar 

  31. Shanti Y, Satyadevi A (2021) Effect of wood and graphite fillers on the glass fiber reinforced composite. Mater Lett 284:128971

    Article  Google Scholar 

  32. Bledzki AK, Gassan J (1999) Composites reinforced with cellulose based fibres. Prog Polym Sci 24(2):221–274

    Article  Google Scholar 

  33. Shalwan A, Yousif BF (2014) Influence of date palm fibre and graphite filler on mechanical and wear characteristics of epoxy composites. Materials & Design 59:264–273

    Article  Google Scholar 

  34. Matykiewicz D, Barczewski M, Mousa MS, Sanjay MR, Siengchin S (2021) Impact strength of hybrid epoxy–basalt composites modified with mineral and natural fillers. ChemEngineering 5(3):56

    Article  Google Scholar 

  35. HM K, Bavan S, MR S, Siengchin S, Gorbatyuk S (2021) Effect of coir fiber and inorganic filler on physical and mechanical properties of epoxy based hybrid composites. Polym Compos 42(8):3911–3921

    Article  Google Scholar 

  36. Baptista R, Mendão A, Guedes M, Marat-Mendes R (2016) An experimental study on mechanical properties of epoxy-matrix composites containing graphite filler. Procedia Structural Integrity 1:74–81

    Article  Google Scholar 

  37. Gouda K, Paul R, Bhowmik S, Das B (2021) Tailoring the thermomechanical behaviour of epoxy with the incorporation of bamboo and graphite filler. Materials Today: Proceedings 46:9084–9088

    Google Scholar 

  38. Alo OA, Otunniyi IO (2021) Graphite-filled polyethylene/epoxy blend for high-conductivity applications: the immiscibility edge. Polymer-Plastics Technology and Materials 60(1):105–116

    Article  Google Scholar 

  39. Choi YJ, Lee KM, Kang DH, Han JI, Lee YS (2019) Oxyfluorination of expanded graphite: improving the thermal properties of epoxy composites through interfacial interaction. Carbon Letters 29(4):401–409

    Article  Google Scholar 

  40. Khalili P, Tshai KY, Kong I (2017) Natural fiber reinforced expandable graphite filled composites: evaluation of the flame retardancy, thermal and mechanical performances. Compos A: Appl Sci Manuf 100:194–205

    Article  Google Scholar 

  41. Rajesh M, Jayakrishna K, Sultan MTH, Manikandan M, Mugeshkannan V, Shah AUM, Safri SNA (2020) The hydroscopic effect on dynamic and thermal properties of woven jute, banana, and intra-ply hybrid natural fiber composites. J Mater Res Technol 9(5):10305–10315

    Article  Google Scholar 

  42. Kumar R, Nayak SK, Sahoo S, Panda BP, Mohanty S, Nayak SK (2018) Study on thermal conductive epoxy adhesive based on adopting hexagonal boron nitride/graphite hybrids. J Mater Sci Mater Electron 29(19):16932–16938

    Article  Google Scholar 

  43. Ghosh SK, Prusty RK, Rathore DK, Ray BC (2017) Creep behaviour of graphite oxide nanoplates embedded glass fiber/epoxy composites: emphasizing the role of temperature and stress. Compos A: Appl Sci Manuf 102:166–177

    Article  Google Scholar 

  44. SudarshanRao K (2021) Dynamic mechanical behavior of unfilled and graphite filled carbon epoxy composites. IOP Conf Ser: Mater Sci Eng 1126(1):012033). IOP Publishing

    Article  Google Scholar 

  45. Devi LU, Bhagawan SS, Thomas S (2010) Dynamic mechanical analysis of pineapple leaf/glass hybrid fiber reinforced polyester composites. Polym Compos 31(6):956–965

    Article  Google Scholar 

  46. Şansveren MF, Yaman M (2019) The effect of carbon nanofiber on the dynamic and mechanical properties of epoxy/glass microballoon syntactic foam. Advanced Composite Materials 28:561–575

    Article  Google Scholar 

  47. Chee SS, Jawaid M, Sultan MTH, Alothman OY, Abdullah LC (2019) Thermomechanical and dynamic mechanical properties of bamboo/woven kenaf mat reinforced epoxy hybrid composites. Compos Part B Eng 163:165–174

    Article  Google Scholar 

  48. Amir S, BabaAkbar-Zarei H, Khorasani M (2020) Flexoelectric vibration analysis of nanocomposite sandwich plates. Mech Based Des Struct Mach 48(2):146–163

    Article  Google Scholar 

  49. Ayatollahi MR, Barbaz Isfahani R, Moghimi Monfared R (2017) Effects of multi-walled carbon nanotube and nanosilica on tensile properties of woven carbon fabric-reinforced epoxy composites fabricated using VARIM. Journal of Composite Materials 51(30):4177–4188

    Article  Google Scholar 

  50. Constable I, Williams JG, Burns DJ Fatigue and cyclic thermal softening of thermoplastics. Journal of Mechanical Engineering Science 12(1):20–29

  51. Crawford RJ, Benham PP (1974) Cyclic stress fatigue and thermal softening failure of a thermoplastic. J Mater Sci 9(1):18–28

    Article  Google Scholar 

  52. Cauich-Cupul JI, Herrera-Franco PJ, García-Hernández E, Moreno-Chulim V, Valadez-González A (2019) Factorial design approach to assess the effect of fiber–matrix adhesion on the IFSS and work of adhesion of carbon fiber/polysulfone-modified epoxy composites. Carbon Letters 29(4):345–358

    Article  Google Scholar 

  53. Kang WS, Rhee KY, Park SJ (2017) Influence of surface energetics of graphene oxide on fracture toughness of epoxy nanocomposites. Compos Part B Eng 114:175–183

    Article  Google Scholar 

Download references

Data availability

Not applicable.

Funding

This research was funded by the National Science, Research and Innovation Fund (NSRF) and King Mongkut’s University of Technology North Bangkok with Contract no. KMUTNB-FF-66-14.

Author information

Authors and Affiliations

Authors

Contributions

All authors equally contributed to conceptualization, methodology, writing—original draft, and writing—review and editing.

Corresponding authors

Correspondence to Harikrishnan Pulikkalparambil or Sanjay Mavinkere Rangappa.

Ethics declarations

Ethics approval

The authors hereby state that the present work is in compliance with the ethical standards.

Consent to participate

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pulikkalparambil, H., Saravana Kumar, M., Babu, A. et al. Effect of graphite fillers on woven bamboo fiber-reinforced epoxy hybrid composites for semistructural applications: fabrication and characterization. Biomass Conv. Bioref. (2023). https://doi.org/10.1007/s13399-023-03811-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s13399-023-03811-y

Keywords

Navigation