Abstract
The characterization of cardanol oil and cassava peel biochar toughened epoxy biocomposite coating has been investigated in this research. The aim of this study was to find the mechanical, wear, dynamic mechanical analysis (DMA), thermogravimetry analysis (TGA), and thermal conductivity behavior of epoxy-based coating material for structural application. The cardanol oil was prepared from the remains of the cashew fruit nut shell, whereas the biochar was prepared from the cassava tuber peels. The composite coating material was prepared using epoxy, cardanol oil, and biochar via a blend mixing method and tested according to ASTM standards. The mechanical testing shows that the 20 vol. % of cardanol oil decreased the strength of the biocomposite, whereas the biochar added RCC6 composite gave improved tensile strength, flexural strength, and hardness for as 93 MPa, 125 MPa, and 93 shore-D. It is observed that the larger addition of cardanol oil decreased the wear resistances too, whereas the addition of cassava peel biochar increased the wear resistances by lowering the coefficient of friction (COF) to 0.51 and sp. wear rate to 0.08 mm3/Nm. The values DMA, TGA, and thermal conductivity were enhanced with incremental in cardanol oil and cassava peel biochar. The best results were found with 20 vol. % of cardanol and 5 vol. % of cassava peel biochar by accounting for all parameters. Such biocomposite coatings with improved properties could be used in electrical appliances, industrial, automotive, aircraft, cold storage units, and defense applications.
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References
Rajadurai A (2016) Thermo-mechanical characterization of siliconized E-glass fiber/hematite particles reinforced epoxy resin hybrid composite. Appl Surf Sci 384:99–106
Wilson et al. (2020) Materials for potential EMI shielding applications. Elsevier, 2020. pp 1–8,https://doi.org/10.1016/B978-0-12-817590-3.00001-4.
Sreehari H, Venu G, Jitha SJ, Sethulekshmi AS, and Saritha A (2022) A comprehensive review on bio epoxy based IPN: Synthesis, properties and applications. Polymer 124950
Alshahrani, Hassan, and Arun Prakash Vr. (2022) Mechanical, wear, and fatigue behavior of alkali-silane-treated areca fiber, RHA biochar, and cardanol oil-toughened epoxy biocomposite. Biomass Conversion and Biorefinery 1–12
Alexander M, Thachil ET (2006) A comparative study of cardanol and aromatic oil as plasticizers for carbonblack‐filled natural rubber. J Appl Polymer Sci 1025:4835–4841
Kumar S, Krishnan S, Mohanty S, Nayak SK (2018) Synthesis and characterization of petroleum and biobased epoxy resins: a review. Polym Int 67:815–839. https://doi.org/10.1002/pi.5575
Balaji A, Udhayasankar R, Karthikeyan B, Swaminathan J, Purushothaman R (2020) Mechanical and thermalcharacterization of bagasse fiber/coconut shell particle hybrid biocomposites reinforced with cardanol resin. Results in Chemistry 2:100056
Ayyappa A, Palevicius A, Vilkauskas A, Janusas G (2020) Review of hybrid fiber based composites with nano particles—material properties and applications. Polymers 12(9):2088
Andrew J, Jefferson, Dhakal HN (2022) Sustainable biobased composites for advanced applications: recent trends and future opportunities–A critical review. Composites Part C: Open Access 7:100220
Ogunsona EO, Codou A, Misra, M, Mohanty AK (2018) Thermally stable pyrolytic biocarbon as an effective and sustainable reinforcing filler for polyamide bio-composites fabrication. J Polymer Environ 26(9):3574–3589
Alshahrani, Hassan, Prakash VR (2022) Effect of silane-grafted orange peel biochar and areca fibre on mechanical, thermal conductivity and dielectric properties of epoxy resin composites. Biomass Conversion and Biorefinery 1–9
Fathima, Anwar Aliya, anitha M, Tripathi L,Muiruri S (2022) Cassava (Manihot esculenta) dual use for food and bioenergy: A review. Food and Energy Security e380.
Rogoski W (2022) Production of cassava peel-based xylooligosaccharides using endo-1, 4-ß-xylanase from Trichoderma longibrachiatum: the effect of alkaline pretreatment.
Thiyagu, Thendral T, Sai Prasanna Kumar JV, Sathiyamoorthy V, Arun Prakash VR (2021) Effect of cashew shell biomass synthesized cardanol oil green compatibilizer on flexibility, barrier, thermal, and wettability of PLA/PBAT biocomposite films. Biomass Conversion and Biorefinery 1–11
Ukanwa, Samuel K, Patchigolla K, Sakrabani R, Anthony E, Mandavgane S (2019) A review of chemicals to produce activated carbon from agricultural waste biomass. Sustainability 11(22):6204
Kalam, Abul M, Khan AA, Alshamsan A, Haque A, Shakeel F (2018) Solubility of a poorly soluble immunosuppressant in different pure solvents: measurement, correlation, thermodynamics and molecular interactions J Mol Liq 249:53–60
Chen, Bo, Qian Wu, Ji Li, Kaidong Lin, Dongchu Chen, Chengliang Zhou, Tao Wu, Xiaohu Luo, Yali Liu (2020) A novel and green method to synthesize a epoxidized biomass eucommia gum as the nanofiller in the epoxy composite coating with excellent anticorrosive performance. Chem Eng J 379:122323
Thiyagu T, Thendral G, Gokilakrishnan VC, Uvaraja T, Maridurai, Prakash VR (2022) Effect of SiO2/TiO2 and ZnO nanoparticle on cardanol oil compatibilized PLA/PBAT biocomposite packaging film. Silicon 14(7):3795–3808
Zhang C, Si W, Wang Y, Dai S, Shu D (2021) Investigations on the influence of annealing on microstructure and mechanical properties of electrodeposited Ni-Mo and Ni-Mo-W alloy coatings. Coatings. 11(11):1428. https://doi.org/10.3390/coatings11111428
Barbosa AQ, Da Silva LFM, Abenojar J, Figueiredo M, Öchsner A(2017) Toughness of a brittle epoxy resin reinforced with micro cork particles: effect of size, amount and surface treatment. Compos Part B Eng 114:299–310
Prakash, Arun VR, Viswanthan R (2019) Fabrication and characterization of echinoidea spike particles and kenaf natural fibre-reinforced Azadirachta-Indica blended epoxy multi-hybrid bio composite. Compos A: Appl Sci Manuf 118:317–326
Jayabalakrishnan D, Prabhu P, Iqbal MS, Mugendiran V, Ravi S, Arun VR Prakash (2021) Mechanical, dielectric, and hydrophobicity behavior of coconut shell biochar toughened Caryota urens natural fiber reinforced epoxy composite. Polym Compos.
V R, A P, V J, T M. et al. (2020) Effect of silicon coupling grafted ferric oxide and E-glass fibre in thermal stability, wear and tensile fatigue behaviour of epoxy hybrid composite. Silicon 12:2533–2544. https://doi.org/10.1007/s12633-019-00347-7
Ravi S, Saravanan K, Jayabalakrishnan D, Prabhu P, Vijayananth Suyamburajan, Jayaseelan V, Mayakkannan AV (2022) Silane grafted nanosilica and aramid fibre-reinforced epoxy composite: dma, fatigue and dynamic loading behaviour. Silicon 14(6):2707–2715
Dinesh T, Kadirvel A, Vincent A (2019) Effect of Silane Modified E-glass Fibre/Iron(III)Oxide Reinforcements on UP Blended Epoxy Resin Hybrid Composite. Silicon 11:2487–2498. https://doi.org/10.1007/s12633-018-9886-0
Ben Samuel J, Julyes Jaisingh S, Sivakumar K, et al. (2021) Visco-Elastic, thermal, antimicrobial and dielectric behaviour of areca fibre-reinforced nano-silica and neem oil-toughened epoxy resin bio composite. Silicon 13:1703–1712 https://doi.org/10.1007/s12633-020-00569-0
George, Justin, Azad LB, Poulose AM, Yiran An, Sarmah AK (2019) Nano-mechanical behaviour of biochar-starch polymer composite: Investigation through advanced dynamic atomic force microscopy. Compos A: Appl Sci Manuf 124:105486
Daud, Zawawi, Nazlizan Nasir, Aziz Abdul Latiff A, Mohd Baharudin Ridzuan, Halizah Awang (2016) Treatment of biodiesel wastewater by coagulation-flocculation process using polyaluminium chloride (PAC) and polyelectrolyte anionic. J Engl Acad Purp 11(20):11855–11859
Karthigairajan M, Nagarajan PK, Raviraja Malarvannan R, Ramesh Bapu BR, Jayabalakrishnan D, Maridurai T, Shanmuganathan VK (2021) Effect of silane-treated rice husk derived biosilica on visco-elastic, thermal conductivity and hydrophobicity behavior of epoxy biocomposite coating for air-duct application. Silicon 13(12):4421–4430
Prabhu P, Jayabalakrishnan D, Balaji V, et al. (2022) Mechanical, tribology, dielectric, thermal conductivity, and water absorption behaviour of Caryota urens woven fibre-reinforced coconut husk biochar toughened wood-plastic composite. Biomass Conv. Bioref. https://doi.org/10.1007/s13399-021-02177-3
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Paul, N.E.E., Sudeshkumar, M.P., Duraimurugan, P. et al. Synthesis and characterization of cardanol oil and cassava tuber peel biochar toughened epoxy composite coating for structural application. Biomass Conv. Bioref. 13, 7301–7310 (2023). https://doi.org/10.1007/s13399-022-03128-2
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DOI: https://doi.org/10.1007/s13399-022-03128-2