Abstract
With the growing demand for high-energy-density rechargeable batteries, lithium metal anodes have reemerged as a promising alternative to conventional graphite anodes in lithium-ion batteries. Lithium metal boasts exceptional energy storage characteristics, yet its practical application has been impeded by dendritic growth issues. Extensive research has explored various solutions, including electrode engineering through surface modification and 3D structural hosts, which often involve intricate designs and processes. This study introduces an effective approach to govern lithium metal nucleation and growth, leveraging the synergistic effects of a lithiophilic layer and surface energy diversification. Inspired by the structure of standard copper mesh grids used in transmission electron microscopy (TEM), we illustrate how subtle topographic modifications can provide a viable path to anode-free lithium metal batteries. This research represents a significant stride towards accelerated advancements in lithium metal batteries, promising higher energy density and enhanced safety for energy storage solutions.
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Duan, J., Tang, X., Dai, H.F., Yang, Y., Wu, W.Y., Wei, X.Z., Huang, Y.H.: Electrochem. Energy R. 3(1), 1–42 (2020). https://doi.org/10.1007/s41918-019-00060-4
Wen, J.P., Zhao, D., Zhang, C.W.: Renew. Energ. 162, 1629–1648 (2020). https://doi.org/10.1016/j.renene.2020.09.055
Zeng, X.Q., Li, M., Abd El-Hady, D., Alshitari, W., Al-Bogami, A.S., Lu, J., Amine, K.: Adv. Energy Mater. 9, 27, 201900161 (2019). https://doi.org/10.1002/aenm.201900161
Um, J.H., Kim, K., Park, J., Sung, Y.E., Yu, S.H.: J. Mater. Chem. A. 8, 28, 13874–13895 (2020). https://doi.org/10.1039/d0ta03774e
Lin, D.C., Liu, Y.Y., Cui, Y.: Nat. Nanotechnol. 12, 3, 194–206 (2017). https://doi.org/10.1038/NNANO.2017.16
Xu, W., Wang, J.L., Ding, F., Chen, X.L., Nasybutin, E., Zhang, Y.H., Zhang, J.G.: Energ. Environ. Sci. 7, 2, 513–537 (2014). https://doi.org/10.1039/C3EE40795K
Whittingham, M.S.: Science, 192, 4244, 1126–1127 (1976). https://doi.org/10.1126/science.192.4244.1126
Brandt, K.: Solid State Ionics, 69, 3–4, 173–183 (1994). https://doi.org/10.1016/0167-2738(94)90408-1
Guo, Y.P., Li, H.Q., Zhai, T.Y.: Adv. Mater. 29, 1700007 (2017). https://doi.org/10.1002/adma.201700007
Liu, B., Zhang, J.-G., Xu, W.: Joule, 2, 5, 833–845 (2018). https://doi.org/10.1016/j.joule.2018.03.008
Vaughey, J.T., Liu, G., Zhang, J.G.: Mrs Bull. 39, 5, 429–435 (2014). https://doi.org/10.1557/mrs.2014.88
Dudney, N.J., Mrs Bull: 43, 10, 752–758 (2018). https://doi.org/10.1557/mrs.2018.233
Wang, L., Zhou, Z., Yan, X., Hou, F., Wen, L., Luo, W., Liang, J., Dou, S.X.: Energy Storage Materials. 14, 22–48 (2018). https://doi.org/10.1016/j.ensm.2018.02.014
Ue, M., Uosaki, K.: Curr. Opin. Electroche. 17, 106–113 (2019). https://doi.org/10.1016/j.coelec.2019.05.001
Yu, X.W., Manthiram, A.: Energ. Environ. Sci. 11(3), 527–543 (2018). https://doi.org/10.1039/c7ee02555f
Zhang, R., Li, N.W., Cheng, X.B., Yin, Y.X., Zhang, Q., Guo, Y.G.: Adv. Sci. 4, 3, 1600445 (2017). https://doi.org/10.1002/advs.201600445
Shao, A.H., Tang, X.Y., Zhang, M., Bai, M., Ma, Y.: Adv. Energ. Sust Res. 3(4), 202100197 (2022). https://doi.org/10.1002/aesr.202100197
Cha, E., Yun, J.H., Ponraj, R., Kim, D.K.: Mater. Chem. Front. 5. 17, 6294–6314 (2021). https://doi.org/10.1039/d1qm00579k
Cui, S.Q., Zhai, P.B., Yang, W.W., Wei, Y., Xiao, J., Deng, L.B., Gong, Y.J.: Small. 16, 5, 1905620 (2020). https://doi.org/10.1002/smll.201905620
Guo, F.H., Wu, C., Chen, H., Zhong, F.P., Ai, X.P., Yang, H.X., Qian, J.F.: Energy Storage Materials. 24, 635–643 (2020). https://doi.org/10.1016/j.ensm.2019.06.010
Cheng, Y.F., Chen, J.B.A., Chen, Y.M., Ke, X., Li, J., Yang, Y., Shi, Z.C.: Energy Storage Materials. 38, 276–298 (2021). https://doi.org/10.1016/j.ensm.2021.03.008
Park, S., Jin, H.J., Yun, Y.S.: Adv. Mater. 32, 51, 2002193 (2020). https://doi.org/10.1002/adma.202002193
Liu, H., Di, J., Wang, P., Gao, R., Tian, H., Ren, P.F., Yuan, Q.X., Huang, W.X., Liu, R.P., Liu, Q., Feng, M.: Carbon Energy. 4(4), 654–664 (2022). https://doi.org/10.1002/cey2.193
Cosslett, V., Horne, R., Vacuum: 5, 109–130 (1955). https://doi.org/10.1016/0042-207X(55)90010-5
Galushko, A.S., Gordeev, E.G., Kashin, A.S., Zubavichus, Y.V., Ananikov, V.P.: Faraday Discuss. 229, 0, 458–474 (2021). https://doi.org/10.1039/c9fd00125e
Noh, M., Kwon, Y., Lee, H., Cho, J., Kim, Y., Kim, M.G.: Chem. Mater. 17, 8, 1926–1929 (2005). https://doi.org/10.1021/cm0481372
Fan, P., Mu, T., Lou, S., Cheng, X., Gao, Y., Du, C., Zuo, P., Ma, Y., Yin, G.: Electrochim. Acta. 306, 590–598 (2019). https://doi.org/10.1016/j.electacta.2019.03.154
Gourdin, G., Smith, P.H., Jiang, T., Tran, T.N., Qu, D.: J. Electroanal. Chem. 688, 103–112 (2013). https://doi.org/10.1016/j.jelechem.2012.08.029
Cui, S., Zhai, P., Yang, W., Wei, Y., Xiao, J., Deng, L., Gong, Y.: Small. 16, 5, 1905620 (2020). https://doi.org/10.1002/smll.201905620
Shen, X., Shi, S., Li, B., Li, S., Zhang, H., Chen, S., Deng, H., Zhang, Q., Zhu, J., Duan, X.: Adv. Funct. Mater. 32, 39, 2206388 (2022). https://doi.org/10.1002/adfm.202206388
De Yoreo, J.J., Vekilov, P.G.: Reviews in mineralogy and geochemistry, 54, 1, 57–93 (2003). https://doi.org/10.2113/0540057
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This work was supported by National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. RS-2023-00222411 and NRF-2022R1C1C1010157).
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Kim, J., Kim, M., Kim, M. et al. A Stepped Mesh Host for Lithium Metal Batteries Inspired by Transmission Electron Microscopy Sampling Grids. Electron. Mater. Lett. (2023). https://doi.org/10.1007/s13391-023-00474-9
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DOI: https://doi.org/10.1007/s13391-023-00474-9