Abstract
The cubic and spherical shaped iron pyrite (FeS2) nanocrystals were synthesized in a pure phase form by an efficient hot injection method. These FeS2 nanocrystals were used as a counter electrode (CE) alternative to the conventional Pt CE in dye-sensitized solar cells (DSSCs) owing to its tremendous optical properties and low-cost. The obtained FeS2 nanocrystalline materials with excellent shape and phase purity were confirmed through XRD and Raman spectroscopy data. From Tafel, and impedance spectroscopy studies, the catalytic activity FeS2 CEs are found to be comparable with that of Pt CE. Along with the I3−/I− electrolyte, photo-conversion efficiency is found to be 6.9% (spherical), 6.2% (cubic) for the FeS2 CE, and 7% for Pt CE. The excellent performance of the FeS2 CE in DSSCs makes it a distinctive choice among the various CE materials studied including low-cost photovoltaics.
Graphical Abstract
Similar content being viewed by others
References
Gratzel, M.: Recent advances in sensitized mesoscopic solar cells. Acc. Chem. Res. 42, 1788 (2009)
Gonga, J., Sumathya, K., Qiaob, Q., Zhoub, Z.: Review on dye-sensitized solar cells (DSSCs): advanced techniques and research trends. Renew. Sustain. Energy Rev. 68, 234 (2017)
Yun, S., Liu, Y., Zhang, T., Ahmad, S.: Recent advances in alternative counter electrode materials for Co-mediated dye-sensitized solar cells. Nanoscale 7, 11877 (2015)
O’Regan, B., Gratzel, M.: A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353, 737 (1991)
Yun, S., Lund, P.D., Hinsch, A.: Stability assessment of alternative platinum free counter electrodes for dye-sensitized solar cells. Energy Environ. Sci. 8, 3495 (2015)
Hwang, S., Batmunkh, M., Nine, M.J., Chung, H., Jeong, H.: Dye-sensitized solar cell counter electrodes based on carbon nanotubes. Chem. Phys. Chem. 16, 53 (2015)
Thomas, S., Deepak, T., Anjusree, G., Arun, T., Naira, S., Nair, A.: A review on counter electrode materials in dye-sensitized solar cells. J. Mater. Chem. A. 2, 4474 (2014)
Yun, S., Hagfeldt, A., Ma, T.: Pt-free counter electrode for dye-sensitized solar cells with high efficiency. Adv. Mater. 26, 6210 (2014)
Wang, L., Al-Mamun, M., Liu, P., Wang, Y., Yang, H., Wang, H., Zhao, H.: The search for efficient electrocatalysts as counter electrode materials for dye-sensitized solar cells: mechanistic study, material screening and experimental validation. NPG Asia Mater. 7, e226 (2015)
Papageorgiou, N., Maier, W., Gratzel, M.: An iodine/triiodide reduction electrocatalyst for aqueous and organic media. J. Electrochem. Soc. 144, 876 (1997)
Wu, J., Li, Y., Tang, Q., Yue, G., Lin, J., Huang, M., Meng, L.: Bifacial dye-sensitized solar cells: a strategy to enhance overall efficiency based on transparent polyaniline electrode. Sci. Rep. 4, 4028 (2014)
Trancik, J., Barton, S., Hone, J.: Transparent and catalytic carbon nanotube films. Nano Lett. 8, 982 (2008)
Liu, G., Li, X., Wang, H., Rong, Y., Ku, Z., Xu, M., Liu, L., Hu, M., Yang, Y., Han, H.: A class of carbon supported transition metal_nitrogen complex catalysts for dye-sensitized solar cells. J. Mater. Chem. A 1, 1475 (2013)
Susac, D., Zhu, L., Teo, M., Sode, A., Wong, K.C., Wong, P.C., Parsons, R.R., Bizzotto, D., Mitchell, K.A.R., Campbell, S.A.: Characterization of FeS2-based thin films as model catalysts for the oxygen reduction reaction. J. Phys. Chem. C 111, 18715 (2007)
Seefeld, S., Limpinsel, M., Liu, Y., Farhi, N., Weber, A., Zhang, Y., Berry, N., Kwon, Y.J., Perkins, C.L., Hemminger, J.C., Wu, R., Law, M.: Iron pyrite thin films synthesized from an Fe(acac)3 ink. J. Am. Chem. Soc. 135, 4412 (2013)
Ennaoui, A., Fiechter, S., Pettenkofer, C., Alonso-Vante, N., Büker, K., Bronold, M., Höpfner, C., Tributsch, H.: Iron disulfide for solar energy conversion. Sol. Energy Mater. Sol. Cells 29, 289 (1993)
Puthessery, J., Seefeld, S., Berry, N., Bibb, M., Law, M.: Colloidal iron pyrite (FeS2) nanocrystal inks for thin-film photovoltaics. J. Am. Chem. Soc. 133, 716 (2011)
Ge, H., Hai, L., Prabhakar, R.R., Ming, L.Y., Sritharan, T.: Evolution of nanoplate morphology, structure and chemistry during synthesis of pyrite by a hot injection method. RCS Adv. 4, 16489 (2014)
Zhu, L., Richardson, B.J., Yu, Q.: Controlled colloidal synthesis of iron pyrite FeS2 nanorods and quasi-cubic nanocrystal agglomerates. Nanoscale 6, 1029 (2014)
Jiang, F., Peckler, L.T., Muscat, A.J.: Phase pure pyrite FeS2 nanocube synthesized using oleylamine as ligand, solvent, and reductant. Cryst. Growth Des. 15, 3565 (2015)
Trinh, T.K., Pham, V.T.H., Truong, N.T.N., Kim, C.D., Park, C.: Iron pyrite: phase and shape control by facile hot injection method. J. Cryst. Growth 461, 53 (2017)
Shukla, S., Loc, N.H., Boix, P.P., Koh, T.M., Prabhakar, R.R., Mulmudi, H.K., Zhang, J., Chen, S., Nf, C.F., Huan, C.H.A., Mathews, N., Sritharan, T., Xiong, Q.: Iron pyrite thin film counter electrodes for dye-sensitized solar cells: high efficiency for iodine and cobalt redox electrolyte cells. ACS Nano 8, 10597 (2014)
Utyuzh, A.N.: Influence of temperature on raman spectra of the FeS2 single crystal with pyrite structure. Phys. Solid State 56, 2050 (2014)
Kleppe, A.K., Jephcoat, A.P.: High-pressure Raman spectroscopic studies of FeS2 pyrite. Mineral. Mag. 68, 433 (2004)
Gopel, W.: Chemisorption and charge transfer at ionic semiconductor surfaces: implications in designing gas sensors. Prog. Surf. Sci. 20, 9 (1985)
Geistlinger, H., Eisele, I., Flietner, B., Winter, R.: Dipole-and charge transfer contributions to the work function change of semiconducting thin films: experiment and theory. Sens. Actuators B 34, 499 (1996)
Otero, R., Parga, A.L.V.D., Gallego, J.M.: Electronic, structural and chemical effects of charge-transfer at organic/inorganic interfaces. Surf. Sci. Rep. 72, 105 (2017)
Kavan, L., Yum, J.-H., Gratzel, M.: Graphene nanoplatelets outperforming platinum as the electrocatalyst in co-bipyridine-mediated dye-sensitized solar cells. Nano Lett. 11, 5501 (2011)
Ion, L., Enculescu, I., Antohe, S.: Physical properties of CdTe nanowires electrodeposited by a template method, for photovoltaic applications. J. Optoelectron. Adv. Mater. 10, 3241 (2008)
Song, C., Wang, S., Dong, W., Fang, X., Shao, J., Zhu, J., Pan, X.: Hydrothermal synthesis of iron pyrite (FeS2) as efficient counter electrodes for dye-sensitized solar cells. Sol. Energy 133, 429 (2016)
Lee, Y.H., Park, J.Y., Thogiti, S., Cheruku, R., Kim, J.H.: Application of CBZ dimer, C343 and SQ dye as photosensitizers for pn-tandem DSCs. Electron. Mater. Lett. 12, 524 (2016)
Ho, P., Bao, L.Q., Cheruku, R., Kim, J.H.: Improved performance of P-type DSCs with a compact blocking layer coated by different thicknesses. Electron. Mater. Lett. 12, 638 (2016)
He, B., Meng, X., Tang, Q.: Low-cost counter electrodes from CoPt alloys for efficient dye-sensitized solar cells. ACS Appl. Mater. Interfaces 6, 4812 (2014)
Wang, W., Anghel, A.M., Marsan, B., Ha, N.L.C., Pootrakulchote, N., Zakeeruddin, S.M., Gratzel, M.: CoS supersedes Pt as efficient electrocatalyst for triiodide reduction in dye-sensitized solar cells. J. Am. Chem. Soc. 131, 15976 (2009)
Acknowledgements
This study was supported by a grant from the Fundamental R&D program for Core Technology of Materials (10050966) funded by the Ministry of Knowledge Economy, Republic of Korea. This work was supported by the “Human Resources Program in Energy Technology” of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20174030201760).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Ho, P., Van, T.N., Lee, J.H. et al. Shape Control Iron Pyrite Synthesized by Hot Injection Method: Counter Electrode for Efficient Dye-Sensitized Solar Cells. Electron. Mater. Lett. 15, 350–356 (2019). https://doi.org/10.1007/s13391-019-00140-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13391-019-00140-z