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Structure, microstructure, and piezoelectric properties of ytterbium-doped potassium sodium niobate lead-free ceramics

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Abstract

The structure, microstructure, and piezoelectric properties of conventionally sintered Yb-doped K0.5Na0.5NbO3 (KNN) lead-free ceramics were investigated. Doping the KNN ceramics with Yb2O3 was effective in inhibiting the grain growth in the KNN ceramics and in densifying the ceramics. The 1.0 wt. % Yb-doped KNN ceramics showed the maximum density, about 96.8% of the theoretical density. X-ray diffraction analysis showed that a small number of Yb3+ ions could be incorporated into the matrix of the ceramicsto occupythe α- or β-sites in the crystal lattice, thereby significantly affecting the piezoelectric properties of the ceramics. Enhanced piezoelectric properties (i.e., d 33= 135 pC/N, k p = 34.5%, and Q m = 80.2) were obtained for the 0.50 wt. % Yb-doped KNN ceramics.

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References

  1. G. H. Haertling, J. Am. Ceram. Soc. 82, 797 (1999).

    Article  CAS  Google Scholar 

  2. T. R. Shrout and S. J. Zhang, J. Electroceram. 19, 111 (2007).

    CAS  Google Scholar 

  3. L. Egerton and D. M. Dillon, J. Am. Ceram. Soc. 42, 438 (1959).

    Article  CAS  Google Scholar 

  4. Y. Saito, H. Takao, T. Tani, T. Nanoyama, K. Takatori, T. Homma, T. Nagaya, and M. Nakamura, Nature 123, 84 (2004).

    Article  Google Scholar 

  5. S. Lee, H. Kim, and Y. Lee, Electron. Mater. Lett. 8, 289 (2012).

    Article  CAS  Google Scholar 

  6. D. Lee, S. Lee, E. Choi, S. Lee, and Y. Lee, Electron. Mater. Lett. 7, 201 (2011).

    Article  CAS  Google Scholar 

  7. R. E. Jaeger and L. Egerton, J. Am. Ceram. Soc. 45, 209 (1962).

    Article  CAS  Google Scholar 

  8. B. Zhang, J. Li, K. Wang, and H. Zhang, J. Am. Ceram. Soc. 89, 1605 (2006).

    Article  CAS  Google Scholar 

  9. S. Park, C. Ahn, S. Nahm, and J. Song, Jpn. J. Appl. Phys. 43, L1072 (2004).

    Article  CAS  Google Scholar 

  10. E. Li, H. Kakemoto, S. Wada, and T. Tsurumi, J. Am. Ceram. Soc. 90, 1787 (2007).

    Article  CAS  Google Scholar 

  11. H. E. Mgbemere, R. Herber, and G. A. Schneider, J. Eur. Ceram. Soc. 29, 1729 (2009).

    Article  CAS  Google Scholar 

  12. W. Yang, Z. Zhou, B. Yang, R. Zhang, Z. Wang, H. Chen, and Y. Jiang, J. Am. Ceram. Soc. 94, 2489 (2011).

    Article  CAS  Google Scholar 

  13. R. Zuo, Z. Xu, and L. Li, J. Phys. Chem. Solids 69, 1728 (2008).

    Article  CAS  Google Scholar 

  14. T. Lee, K. W. Kwok, and H. L. W. Chan, J. Phys. D: Appl. Phys. 41, 155402 (2008).

    Article  Google Scholar 

  15. H. Du, D. Liu, F. Tang, D. Zhu, and W. Zhou, J. Am. Ceram. Soc. 90, 2824 (2007).

    Article  CAS  Google Scholar 

  16. B. Malic, J. Bernard, J. Holc, D. Jenko, and M. Kosec, J. Eur. Ceram. Soc. 25, 2707 (2005).

    Article  CAS  Google Scholar 

  17. Y. Wang, L. Li, J. Qi, and Z. Gui, Ceram. Int. 28, 657 (2002).

    Article  CAS  Google Scholar 

  18. Z. Wang, Y. Zhuo, D. Xiao, W. Wu, C. Zhang, X. Huang, and J. Zhu, Curr. Appl. Phys. 11, S143 (2011).

    Article  Google Scholar 

  19. M. Pereira, A. G. Peixoto, and M. J. M. Gomes, J. Eur. Ceram. Soc. 21, 1353 (2001).

    Article  CAS  Google Scholar 

  20. B. D. Stojanovi, V. R. Mastelaro, C. O. Paiva Santos, and J. A. Varela, Sci. Sinter. 36, 179 (2004).

    Article  Google Scholar 

  21. M. Hammer and M. J. Hoffmann, J. Electroceram. 2, 75 (1998).

    Article  CAS  Google Scholar 

  22. K. Wang and J. Li, Adv. Funct. Mater. 20, 1924 (2010).

    Article  CAS  Google Scholar 

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Correspondence to Zhongxiang Zhou.

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Li, H., Yang, W., Zhou, Z. et al. Structure, microstructure, and piezoelectric properties of ytterbium-doped potassium sodium niobate lead-free ceramics. Electron. Mater. Lett. 9, 649–654 (2013). https://doi.org/10.1007/s13391-013-3015-4

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  • DOI: https://doi.org/10.1007/s13391-013-3015-4

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