Abstract
Graphene oxide (GO) attracts tremendous attention for application in high-performance stimuli-responsive “smart” materials because of its unique and excellent electrical, mechanical, thermal, and optical properties, high biocompatibility, and potential application in a variety of fields, including nanocomposite-based devices. Even at an extremely small loading, the chemical, physical, and mechanical properties of GO-polymer nanocomposites can be significantly changed due to its one-atom thickness and large surface area. Therefore, GO-based filler-containing polymer nanocomposites are sensitive to various external stimuli, such as electric and magnetic fields, pH, thermal or optical excitations, and stress. This article reviews the compositions, preparations, and characteristics of a variety of external stimuli-responsive nanocomposites containing GO and other graphene-based fillers. Particularly, the electrorheological and magnetorheological behaviors of smart fluids are described with well-known models and relationships. Finally, various applications of GO-polymer nanocomposites are briefly presented.
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J. C. Huang, Adv. Polym. Technol., 21, 299 (2002).
M. Moniruzzaman and K. I. Winey, Macromolecules, 39, 5194 (2006).
Y. Q. Rao and J. M. Pochan, Macromolecules, 40, 290 (2007).
A. Dato, V. Radmilovic, Z. Lee, J. Phillips, and M. Frenklach, Nano Lett., 8, 2012 (2008).
A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M. S. Dresselhaus, and J. Kong, Nano Lett., 9, 30 (2009).
E. X. Peng, N. Todorova, and I. Yarovsky, ACS Omega, 3, 11497 (2018).
V. Reddy, K. K. C. S. Babu, S. R. Torati, Y. J. Eom, T. Q. Trung, N. E. Lee, and G. Kim, J. Ind. Eng. Chem., 63, 19 (2018).
S. Y. He, N. D. Petkovich, K. W. Liu, Y. Q. Qian, C. W. Macosko, and A. Stein, Polymer, 110, 149 (2017).
A. Buchsteiner, A. Lerf, and J. Pieper, J. Phys. Chem. B, 110, 22328 (2006).
S. Stankovich, R. D. Piner, X. Q. Chen, N. Q. Wu, S. T. Nguyen, and R. S. Ruoff, J. Mater. Chem., 16, 155 (2006).
D. R. Dreyer, S. J. Park, C. W. Bielawski, and R. S. Ruoff, Chem. Soc. Rev., 39, 228 (2010).
K. I. Winey and R. A. Vaia, MRS Bull., 32, 314 (2011).
J. Wu, W. Wen, and P. Sheng, Soft Matter, 8, 11589 (2012).
I. H. Tseng, Y. F. Liao, J. C. Chiang, and M. H. Tsai, Mater. Chem. Phys., 136, 247 (2012).
S. Seiffert, J. Thiele, A. R. Abate, and D. A. Weitz, J. Am. Chem. Soc., 132, 6606 (2010).
W. C. Bauer, J. Kotar, P. Cicuta, R. T. Woodward, J. V. M. Weaverd, and W. T. S. Huck, Soft Matter, 7, 4214 (2011).
J. A. Marins, B. G. Soares, A. A. Silva, M. G. Hurtado, and S. Livi, J. Colloid Interf. Sci., 405, 64 (2013).
R. Tao and Q. Jiang, Phys. Rev. Lett., 73, 205 (1994).
Y. D. Kim and D. J. Klingenberg, J. Colloid Interf. Sci., 183, 568 (1996).
H. J. Choi and M. S. Jhon, Soft Matter, 5, 1562 (2009).
X. P. Zhao and J. B. Yin, Chem. Mater., 14, 2258 (2002).
Y. D. Kim and J. C. Jung, Macromol. Res., 18, 1203 (2010).
J. K. Hwang, K. Shin, H. S. Lim, J. C. Cho, J. W. Kim, and K. D. Suh, Macromol. Res., 20, 391 (2012).
M. Y. Zhang, X. Q. Gong, and W. J. Wen, Electrophoresis, 30, 3116 (2009).
S. B. Choi, Y. M. Han, H. J. Song, J. W. Sohn, and H. J. Choi, J. Intell. Mater. Syst. Struct., 18, 1169 (2007).
J. Nikitczuk, B. Weinberg, and C. Mavroidis, Smart Mater. Struct., 16, 418 (2007).
A. K. Geim and K. S. Novoselov, Nat. Mater., 6, 183 (2007).
C. Soldano, A. Mahmood, and E. Dujardin, Carbon, 48, 2127 (2010).
H. Q. Chen, M. B. Muller, K. J. Gilmore, and G. G. Wallace, D. Li, Adv. Mater., 20, 3557 (2008).
S. Stankovich, D. A. Dikin, G. H. B. Dommett, K. M. Kohlhaas, E. J. Zimney, E. A. Stach, R. D. Piner, S. T. Nguyen, and R. S. Ruoff, Nature, 442, 282 (2006).
H. B. Zhang, W. G. Zheng, Q. Yan, Y. Yong, J. W. Wang, Z. H. Lu, G. Y. Ji, and Z. Z. Yu, Polymer, 51, 1191 (2010).
A. J. Marsden, D. G. Papageorgiou, C. Vallés, A. Liscio, V. Palermo, M. A. Bissett, R. J. Young, and I. A. Kinloch, 2D Mater., 5, 032003 (2018).
K. Kalaitzidou, H. Fukushima, and L. T. Drzal, Compos. Sci. Technol., 67, 2045 (2007).
H. Kim, Y. Miura, and C. W. Macosko, Chem. Mater., 22, 3441 (2010).
A. M. Alekseev, A. E. Efimov, and G. de With, Mater. Sci. Eng., 443, 012002 (2018).
X. Wu, S. Qi, J. He, and G. Duan, J. Mater. Sci., 45, 483 (2009).
M. Yoonessi and J. R. Gaier, ACS Nano, 4, 7211 (2010).
G. H. Chen, W. G. Weng, D. J. Wu, and C. L. Wu, Eur. Polym. J., 39, 2329 (2003).
H. J. Salavagione, G. Martínez, and M. A. Gómez, J. Mater. Chem., 19, 5027 (2009).
S. Vadukumpully, J. Paul, N. Mahanta, and S. Valiyaveettil, Carbon, 49, 198 (2011).
N. Du, C. Y. Zhao, Q. Chen, G. Wu, and R. Lu, Mater. Chem. Phys., 120, 167 (2010).
D. Yan, H. B. Zhang, Y. Jia, J. Hu, X. Y. Qi, Z. Zhang, and Z. Z. Yu, ACS Appl. Mater. Interf., 4, 4740 (2012).
W. L. Zhang, Y. D. Liu, and H. J. Choi, Carbon., 50, 290 (2012).
M. S. Cho, H. J. Choi, and W. S. Ahn, Langmuir, 20, 202 (2004).
Y. L. Cao, H. J. Choi, W. L. Zhang, B. X. Wang, C. C. Hao, and J. Q. Liu., Compos. Sci. Technol., 122, 36 (2016).
B. Sim, W. L. Zhang, and H. J. Choi, Mater. Chem. Phys., 153, 443 (2015).
M. Y. Tang, X. R. Wang, F. Wu, Y. Liu, S. Zhang, X. B. Pang, X. X. Li, and H. X. Qiu, Carbon, 71, 238 (2014).
J. M. Kim, L. J. Cote, F. Kim, W. Yuan, K. R. Shull, and J. X. Huang, J. Am. Chem. Soc., 132, 8180 (2010).
S. D. Kim, W. L. Zhang, and H. J. Choi, J. Mater. Chem. C, 2, 7541 (2014).
T. H. Min and H. J. Choi, Macromol. Res., 25, 565 (2017).
C. J. Lee and H. J. Choi, Colloids Surf. A: Physicochem. Eng. Asp., 550, 56 (2018).
W. L. Zhang, H. J. Choi, and Y. S. Seo, Macromol. Chem. Phys., 214, 1415 (2013).
K. Zhang, W. L. Zhang, and H. J. Choi, Colloid Polym. Sci., 291, 955 (2012).
P. P. Chen, Q. Q. Cheng, L. M. Wang, Y. D. Liu, and H. J. Choi, J. Ind. Eng. Chem., 69, 106 (2019).
M. Yalcintas and H. Dai, Smart Mater. Struct., 8, 560 (1999).
K. Zhang, H. T. Li, Y. Z. Dong, H. L. Zhang, W. Zhao, S. Q. Zhao, and H. J. Choi, Polymer, 168, 29 (2019).
M. S. Cho, H. J. Choi, and M. S. Jhon, Polymer, 46, 11484 (2005).
T. H. Min, C. J. Lee, and H. J. Choi, Polym. Test., 66, 195 (2018).
W. L. Zhang, H. J. Choi, and Y. Seo, Macromol. Chem. Phys., 214, 1415 (2013).
K. S. Cole and R. H. Cole, J. Chem. Phys., 9, 341 (1941).
T. Tang, F. Liu, Y. Liu, X. Li, Q. Xu, Q. Feng, N. Tang, and Y. Du, Appl. Phys. Lett., 104, 123104 (2014).
G. Ning, C. Xu, L. Hao, O. Kazakova, Z. Fun, H. Wang, K. Wang, J. Gao, W. Qian, and F. Wei, Carbon, 51, 390 (2013).
S. Qin, X. Guo, Y. Cao, Z. Ni, and Q. Xu, Carbon, 78, 559 (2014).
H. P. Cong, J. J. He, Y. Lu, and S. H. Yu, Small, 6, 169 (2010).
X. Y. Yang, X. Y. Zhang, Y. F Ma, Y. Huang, Y. S. Wang, and Y. S. Chen, J. Mater. Chem, 19, 2710 (2009).
W. L. Zhang, Y. Tian, Y. D. Liu, Z. Q. Song, J. Q. Liu, and H. J. Choi, RSC Adv., 6, 77925 (2016).
C. H. Hong, M. W. Kim, W. L. Zhang, I. J. Moon, and H. J. Choi, J. Colloid Interf. Sci., 481, 194 (2016).
S. H. Lee, J. H. Jung, and I. K. Oh, Small, 10, 3880 (2014).
J. Zhu, C. M. Andres, J. D. Xu, A. Ramamoorthy, T. Tsotsis, and N. A. Kotov, ACS Nano, 6, 8357 (2012).
H. Yang, K. Paek, and B. J. Kim, Nanoscale, 5, 5720 (2013).
J. H. Lee, H. S. Yang, C. H. Park, H. H Cho, H. S. Yun, and B. J. Kim, Chem. Mater., 28, 3446 (2016).
L. Qiu, D. Y. Liu, Y. F. Wang, C. Cheng, K. Zhou, J. Ding, V. T. Truong, and D. Li, Adv. Mater., 26, 3333 (2014).
D. M. Wang, H. C. Duan, J. H. Lu, and C. L. Lu, J. Mater. Chem. A, 5, 5088 (2017).
S. Ganguli, A. K. Roy, and D. P. Anderson, Carbon, 46, 806 (2008).
A. Yu, P. Ramesh, M. E. Itkis, E. Bekyarova, and R. C. Haddon, J. Phys. Chem. C, 111, 7565 (2007).
A. Yu, P. Ramesh, X. B. Sun, E. Bekyarova, M. E. Itkis, and R. C. Haddon, Adv. Mater., 20, 4740 (2008).
W. Lin, R. Zhang, and C. P. Wong, J. Electron. Mater., 39, 268 (2010).
L. M. Veca, M. J. Meziani, W. Wang, X. Wang, F. S. Lu, P. Y. Zhang, Y. Lin, R. Fee, J. W. Connell, and Y. P. Sun, Adv. Mater., 21, 2088 (2009).
M. Fang, K. G. Wang, H. B. Lu, Y. L. Yanga, and S. Nutt, J. Mater. Chem., 19, 7098 (2009).
M. Acik, G. Lee, C. Mattevi, M. Chhowalla, K. Cho, and Y. J. Chabal, Nat. Mater., 9, 840 (2010).
J. J. Liang, Y. F. Xu, Y. Huang, L. Zhang, Y. Wang, Y. F. Ma, F. F. Li, T. Y. Guo, and Y. S. Chen, J. Phys. Chem. C, 113, 9921 (2009).
J. Loomis, B. King, and B. Panchapakesan, Appl. Phys. Lett., 100, 073108 (2012).
J. Loomis, X. M. Fan, F. Khosravi, P. Xu, M. Fletcher, R. W. Cohn, and B. Panchapakesan, Sci. Rep., 3, 1900 (2013).
M. N. Muralidharan and S. Ansari, Adv. Mater. Lett., 4, 927 (2013).
Z. X. Cheng, T. J. Wang, X. Li, Y. H. Zhang, and H. F. Yu, ACS Appl. Mater. Interf., 7, 27494 (2015).
L. Yu and H. Yu, ACS Appl. Mater. Interf., 7, 3834 (2015).
R. Weissleder, Nat. Biotechnol., 19, 316 (2001).
H. Kim, D. Lee, J. Kim, T. I. Kim, and W. J. Kim, ACS Nano, 7, 6735 (2013).
A. Sakhaee-Pour, M. T. Ahmadian, and A. Vafai, Solid State Commun., 147, 336 (2008).
S. M. Choi, S. H. Jhi, and Y. W. Son, Nano Lett., 10, 3486 (2010).
G. Cocco, E. Cadelano, and L. Colombo, Phys. Rev. B, 81, 241412 (2010).
Y. Lu and J. Guo, Nano Res., 3, 189 (2009).
K. S. Kim, Y. Zhao, H. Jang, S. Y. Lee, J. M. Kim, K. S. Kim, J. H. Ahn, P. Kim, J. Y. Choi, and B. H. Hong, Nature, 457, 706 (2009).
Y. B. Lee, S. K. Bae, H. Jang, S. J. Jang, S. E. Zhu, S. H. Sim, Y. I. Song, B. H. Hong, and J. H. Ahn, Nano Lett., 10, 490 (2010).
C. Gómez-Navarro, M. Burghard, and K. Kern, Nano Lett., 8, 2045 (2008).
T. D. Fornes and D. R. Paul, Polymer, 44, 4993 (2003).
H. Zhong and J. R. Lukes, Phys. Rev. B, 74, 125403 (2006).
G. L. Pollack, Rev. Mod. Phys., 41, 48 (1969).
N. Shenogina, R. Godawat, P. Keblinski, and S. Garde, Phys. Rev. Lett., 102, 156101 (2009).
S. Shenogin, A. Bodapati, L. Xue, R. Ozisik, and P. Keblinski, Appl. Phys. Lett., 85, 2229 (2004).
G. H. Chen, D. J. Wu, W. G. Weng, and W. L. Yan, J. Appl. Polym. Sci., 82, 2506 (2001).
G. H. Chen, D. J. Wu, W. G. Weng, and W. L. Yan, Polym. Eng. Sci., 41, 2148 (2001).
X. S. Du, M. Xiao, Y. Z. Meng, and A. S. Hay, Polymer, 45, 6713 (2004).
Y. She, G. Chen, and D. Wu, Polym. Int., 56, 679 (2007).
W.-P. Wang and C. Y. Pan, Polymer, 45, 3987 (2004).
G. Kocak, C. Tuncer, and V. Bütün, Polym. Chem., 8, 144 (2017).
C. J. Shih, S. C. Lin, R. Sharma, M. S. Strano, and D. Blankschtein, Langmuir, 28, 235 (2012).
J. M. Bak and H. I. Lee, Polymer, 53, 4955 (2012).
M. F., J. Long, W. F. Zhao, L. W. Wang, and G. H. Chen, Langmuir, 26, 16771 (2010).
T. Kavitha, S. I. Haider Abdi, and S. Y. Park, Phys. Chem. Phys., 15, 5176 (2013).
C. L. Wang, B. Li, W. F. Niu, S. S. Hong, B. Saif, S. B. Wang, C. Dong, and S. M. Shuang, RSC Adv., 5, 89299 (2015).
S. K. Bae, H. K. Kim, Y. B. Lee, X. F. Xu, J. S. Park, Y. Zheng, J. Balakrishnan, T. Lei, H. R. Kim, Y. I. Song, Y.-J. Kim, K. S. Kim, B. Özyilmaz, J.-H. Ahn, B. H. Hong, and S. Iijima, Nat. Nanotechnol., 5, 574 (2010).
H. Kim and C. W. Macosko, Polymer, 50, 3797 (2009).
L. Gong, I. A. Kinloch, R. J. Young, I. Riaz, R. Jalil, and K. S. Novoselov, Adv. Mater., 22, 2694 (2010).
G. L. Li, G. Liu, M. Li, D. Wan, K. G. Neoh, and E. T. Kang, J. Phys. Chem. C, 114, 12742 (2010).
C. P. Tien and H. Teng, J. Power Sources, 195, 2414 (2010).
Q. Wu, Y. X. Xu, Z. Y. Yao, A. R. Liu, and G. Q. Shi, ACS Nano, 4, 1963 (2010).
D. W. Wang, F. Li, J. P. Zhao, W. C. Ren, Z. G. Chen, J. Tan, Z. S. Wu, I. G. G. Q. Lu, and H. M. Cheng, ACS Nano, 3, 1745 (2009).
G. Eda and M. Chhowalla, Nano Lett., 9, 814 (2009).
T. Hasan, Z. P. Sun, F. Q. Wang, F. Bonaccorso, P. H. Tan, A. G. Rozhin, and A. C. Ferrar, Adv. Mater., 21, 3874 (2009).
W. Zhang, B. S. Xu, A. Tanaka, and Y. Koga, Carbon, 47, 922 (2009).
W. L. Zhang, Y. D. Liu, H. J. Choi, and Y. S. Seo, RSC Adv., 3, 11723 (2013).
X. Xiao, T. Xie, and Y. T. Cheng, J. Mater. Chem., 20, 3508 (2010).
J. T. Kim, H. J. Jeong, H. C. Park, H. M. Jeong, S. Y. Bae, and B. K. Kim, React. Fucnt. Polym., 88, 1 (2015).
S. Ansari and E. P. Giannelis, J. Polym. Sci. B: Polym. Phys., 47, 888 (2009).
B. Pukanszky and E. Fekete, Mineral Fillers in Theroplastics, 139, 109 (1999).
D. D. Kulkarni, I. J. Choi, S. S. Singamaneni, and V. V. Tsukruk, ACS Nano, 4, 4667 (2010).
K. A. Williams, A. J. Boydston, and C. W. Bielawski, J. R. Soc. Interf., 4, 359 (2007).
B. Z. Jang and A. J. Zhamu, J. Mater. Sci., 43, 5092 (2008).
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Acknowledgment: This work was supported by Inha University (2019).
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Lu, Q., Jang, H.S., Han, W.J. et al. Stimuli-Responsive Graphene Oxide-Polymer Nanocomposites. Macromol. Res. 27, 1061–1070 (2019). https://doi.org/10.1007/s13233-019-7176-3
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DOI: https://doi.org/10.1007/s13233-019-7176-3