Skip to main content
SpringerLink
Log in

To study the effect of boric acid modification on starch–polyvinyl alcohol blend wood adhesive

  • Original Article
  • Published:
Journal of the Indian Academy of Wood Science Aims and scope Submit manuscript

Abstract

Starch–polyvinyl alcohol blends with enhanced properties are achieved with cross-linking it with boric acid. These blends are characterized by FTIR and DSC. A film of starch and PVA blends were prepared by casting on glass plate. The effects of various factors such as increasing starch content, increasing amount of boric acid, on the performance properties like tensile strength, pencil hardness and thermal properties like glass transition temperature were studied. The results showed that the starch–polyvinyl alcohol films prepared by boric acid cross-linking had excellent mechanical, thermal properties and hardness of the film.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Baishya P, Maji TK (2014) Studies on effects of different cross-linkers on the properties of starch-based wood composites. ACS Sustain Chem Eng 2:1760–1768

    Article  CAS  Google Scholar 

  • Gadhave RV, Mahanwar PA, Gadekar PT (2017a) Starch-based adhesives for wood/wood composite bonding: review. Open J Polym Chem 7:19–32

    Article  CAS  Google Scholar 

  • Gadhave RV, Mahanwar PA, Gadekar PT (2017b) Bio-renewable sources for synthesis of eco-friendly polyurethane adhesives—review. Open J Polym Chem 07:57–75. https://doi.org/10.4236/ojpchem.2017.74005

    Article  CAS  Google Scholar 

  • Gadhave RV, Mahanwar PA, Gadekar PT (2018) Starch stabilized polyvinyl acetate emulsion: review. Polym Renew Resour 9:75–84

    Google Scholar 

  • Gu Z, Cheng L, Wang P, Li Z, Hong Y (2014) Preparation method of starch adhesive used for artificial board production. CN 102604560 B, 9 April 2014

  • Huang Z (2006) Environment-friendly type wood-based panel adhesive without MTBE. CN 1884413 A, 27 December 2006

  • Kaewtatip K, Tanrattanakul V (2008) Preparation of cassava starch grafted with polystyrene by suspension polymerization. Carbohyd Polym 73:647–655

    Article  CAS  Google Scholar 

  • Kaur B, Ariffin F, Bhat R, Karim AA (2012) Progress in starch modification in the last decade. Food Hydrocoll 26:398–404

    Article  CAS  Google Scholar 

  • Kennedy HM, Fischer AC (1983) Chap. XX-Starch use in foods. In: Whistler RL, Be Miller JN, Paschall EF (eds) Starch: chemistry and technology, 2nd edn. Academic Press Inc, New York

    Google Scholar 

  • Kim S, Kim H-J (2006) Thermal stability and viscoelastic properties of MF/PVAc hybrid resins on the adhesion for engineered flooring in under heat-ing system; ONDOL. Thermochim Acta 444:134–140

    Article  CAS  Google Scholar 

  • Klenina OV, Klenin VI, Frenkel SY (1970) Formation and breakdown of supermolecular order in aqueous PVA solutions. Polym Sci USSR 12:1448

    Article  Google Scholar 

  • Li P, Guan Y, Liu X (2014) Starch modified polyvinyl alcohol environment-friendly adhesive for buildings and preparation method of adhesive. CN 103897639 A, 2 July 2014

  • Meshram MW, Patil VV, Mhaske ST, Thorat BN (2009) Graft copolymers of starch and its application in textiles. Carbohyd Polym 75:71–78

    Article  CAS  Google Scholar 

  • Nambu M (1984) Freeze-dried poly(vinyl alcohol) gel. US Patent No. 4,472,542

  • Olsson E (2013) Effects of citric acid on starch-based barrier coatings. Karlstad University, Sweden

    Google Scholar 

  • Othman N, Azahari NA, Ismail H (2011) Thermal properties of polyvinyl alcohol (PVOH)/corn starch blend film. Malays Poly J 6:147–154

    Google Scholar 

  • Peppas NA (1975) Turbidimetric studies of aqueous PVA solutions. Makromol Chem 176:3433

    Article  CAS  Google Scholar 

  • Reddy N, Yang Y (2009) Citric acid cross-linking of starch films. Food Chem 118:702–711

    Article  Google Scholar 

  • Sanjiv Kasbe P, Kumar N, Manik G (2017) A molecular simulation analysis of influence of lignosulphonate addition on properties of modified 2-ethyl hexyl acrylate/methyl methacrylate/acrylic acid based pressure sensitive adhesive. Int J Adhes Adhes 78:45–54

    Article  CAS  Google Scholar 

  • Sarwono A, Man ZB, Bustam MA (2014) Effect of urea and borate on water uptake of urea modified tapioca starch film. J Appl Sci Agric 9:95–101

    Google Scholar 

  • Shi D (2014) Corn starch adhesive and preparation method thereof. CN 103333635 A, 2 October 2014

  • Sridach W, Jonjankiat S, Wittaya T (2013) Effect of citric acid, PVOH, and starch ratio on the properties of cross-linked poly(vinyl alcohol)/starch adhesives. J Adhes Sci Technol 27:1727–1738

    Article  CAS  Google Scholar 

  • Stauffer SR, Peppas NA (1992) Poly(vinyl alcohol) hydrogels prepared by freezing-thawing cyclic processing. Polymer 33:3932

    Article  CAS  Google Scholar 

  • Wang ZJ, Li ZF, Gu ZB, Hong Y, Cheng L (2012) Preparation, characte-rization and properties of starch-based wood adhesive. Carbohyd Polym 88:699–706

    Article  CAS  Google Scholar 

  • Xie F, Yu L, Liu H, Chen L (2006) Starch modification using reactive extrusion. Starch 58:131–139

    Article  CAS  Google Scholar 

  • Yin Y, Li J, Liu Y, Li Z (2005) Starch cross-linked with poly(vinyl alcohol) by boric acid. J Appl Polym Sci 96:1394–1397

    Article  CAS  Google Scholar 

  • Zhang X, Wang L (2013) Formaldehyde-free veneering glue applicable to gluing of core veneer and panel of core board and manufacturing method the-reof. CN 103436202 A, 11 December 2013

Download references

Author information

Authors and Affiliations

  1. Department Polymer and Surface Engineering, Institute of Chemical Technology, Mumbai, India

    Ravindra V. Gadhave, Pratik Sanjiv Kasbe, Prakash A. Mahanwar & Pradeep T. Gadekar

Authors
  1. Ravindra V. Gadhave
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pratik Sanjiv Kasbe
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Prakash A. Mahanwar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Pradeep T. Gadekar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ravindra V. Gadhave.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gadhave, R.V., Kasbe, P.S., Mahanwar, P.A. et al. To study the effect of boric acid modification on starch–polyvinyl alcohol blend wood adhesive. J Indian Acad Wood Sci 15, 190–198 (2018). https://doi.org/10.1007/s13196-018-0225-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13196-018-0225-2

Keywords

Search

Navigation