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Influence of the Sn-Oxide-Carbon Carrier Composition on the Functional Characteristics of Deposited Platinum Electrocatalysts

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Abstract

The effect of the SnO2 nanoparticles content on the structure and electrochemical behavior of Pt/(SnO2/C) catalysts containing about 20 wt% Pt was studied. In this case, SnO2/C nanostructured materials were obtained by tin electrodeposition on the carbon particles in suspension. It was found that the optimal combination of stability and activity in the oxygen electroreduction reaction is demonstrated by materials containing 25–30% wt. SnO2. A comparative assessment of the durability and activity of Pt/(SnO2/C) catalysts and a commercial Pt/C catalyst with 20% Pt-loading has been carried out.

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Acknowledgements

The authors are grateful to Dr. V.A. Volochaev for the help in registering XRD spectra.

Funding

This research was financially supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment in the field of scientific activity no 0852-2020-0019).

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Authors and Affiliations

  1. Southern Federal University, Chemistry Faculty, 7 Zorge st., Rostov-on-Don, 344090, Russia

    I. N. Novomlinskiy, M. V. Danilenko, O. I. Safronenko & V. E. Guterman

  2. The Prokhorov Institute of General Physics, the Russian Academy of Sciences, 38 Vavilov st., Moscow, 119991, Russia

    N. Yu. Tabachkova

Authors
  1. I. N. Novomlinskiy
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  2. M. V. Danilenko
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  3. O. I. Safronenko
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  4. N. Yu. Tabachkova
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  5. V. E. Guterman
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Correspondence to I. N. Novomlinskiy.

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Novomlinskiy, I.N., Danilenko, M.V., Safronenko, O.I. et al. Influence of the Sn-Oxide-Carbon Carrier Composition on the Functional Characteristics of Deposited Platinum Electrocatalysts. Electrocatalysis 12, 489–498 (2021). https://doi.org/10.1007/s12678-021-00649-8

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  • DOI: https://doi.org/10.1007/s12678-021-00649-8

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