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Green Biosynthesis of Copper Oxide Nanoparticles Using Waste Colocasia esculenta Leaves Extract and Their Application as Recyclable Catalyst Towards the Synthesis of 1,2,3-triazoles

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Abstract

Generation of value-added materials from waste product is in high demand for sustainable chemistry. In order to reduce the use of toxic chemicals in the synthesis of metal nanoparticles, alternative green methods are in demand. Herein, we report the synthesis of copper oxide nanoparticles from plant extract of Colocasia esculenta leaves which is thrown as waste after cultivation. The synthesized nanoparticle was characterized using UV, FT-IR, EDX, TEM, AAS, DLS, and XPS. The synthesized nanoparticles were used as heterogenous catalyst for carrying out the click reaction of azide and alkyne. The catalyst showed good catalytic activity for the synthesis of various 1,2,3-triazoles with very low catalyst loading (0.535 mol% of copper) giving excellent yield of various triazoles. The catalyst could be easily separated from the reaction medium and recycled several times without losing much catalytic activity. The catalyst showed good TON (177.6) and TOF (29.6 h−1) for the optimized reaction. Thus, the method has several advantages such as synthesis of the nanoparticle from cheap sources (plant extract of waste Colocasia esculenta leaves), use of the water as environmentally benign solvent for carrying out the click reaction, one-pot reaction, low catalyst loading, recyclability of catalyst, and high yield of 1,2,3-triazole products.

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Acknowledgments

The authors acknowledge the Dept. of Chemistry, Gauhati University, India, and Sophisticated Analytical Instrument Facility (SAIF), NEHU, Shillong, India, for TEM and EDX analysis of the samples.

Funding

This study is financially supported by DST, Govt. of India (Grant No. SB/FT/CS-100/2012).

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Authors and Affiliations

  1. Department of Applied Sciences, GUIST, Gauhati University, Guwahati, Assam, 781014, India

    Kailash Barman, Prantu Dutta & Pranjal K. Baruah

  2. Material Nanochemistry Laboratory, Physical Sciences Division, Institute of Advanced Study in Science and Technology, Paschim Boragaon, Garchuk, Guwahati, Assam, 781035, India

    Devasish Chowdhury

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  1. Kailash Barman
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ESM 1

The characterization data including 1H & 13C NMR and IR spectra of the synthesized 1,2,3-triazoles are provided. XPS spectra of the catalyst is provided. The IR and EDX data of the fresh catalyst and after each reaction cycle is also provided. (PDF 2307 kb)

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Barman, K., Dutta, P., Chowdhury, D. et al. Green Biosynthesis of Copper Oxide Nanoparticles Using Waste Colocasia esculenta Leaves Extract and Their Application as Recyclable Catalyst Towards the Synthesis of 1,2,3-triazoles. BioNanoSci. 11, 189–199 (2021). https://doi.org/10.1007/s12668-021-00826-5

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