Skip to main content
Log in

Influence of geochemical variation and heavy mineral component on primordial radionuclide presence in Tamiraparani River sediments

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

Gamma spectral analysis for the presence of primordial radionuclides was done on the sediment samples collected from Tamiraparani River, Tamil Nadu, India, which originates in the Western Ghats and flows towards the eastern side of the high background radiation region of Southern Malabar Coast (Kerala). The average activity concentration values for the primordial radionuclides were observed to be higher than the world median ranges reported by UNSCEAR (Report to general assembly with scientific annexes, vol 1, Annex B. United Nations, New York, http://www.unscear.org/docs/publications/2008/UNSCEAR_2008_Annex-B-CORR.pdf, 2008). The radiological parameters calculated for river sediments were found to be comparatively higher than the recommended values. The computed correlation matrix exhibited a positive correlation between various geochemical parameters and the activity concentration values of the primordial radionuclides. The heavy mineral analysis also showed a noticeable correlation with the activity of the actinides. The solid-state electrical conductivity studies on the heavy mineral samples were investigated to study their correlation with the activity of the primordial radionuclides.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Adukpo OK, Faanu A, Lawluvi H, Tettey-Larbi L, Emi-Reynolds G, Darko EO, Kansaana C, Kpeglo DO, Awudu AR, Glover ET, Amoah PA, Efa AO, Agyemang LA, Agyeman BK, Kpordzro R, Doe AI (2015) Distribution and assessment of radionuclides in sediments, soil and water from the lower basin of river Pra in the Central and Western Regions of Ghana. J Radioanal Nucl Chem 303(3):1679–1685

    Google Scholar 

  • Ajayi IR, Kuforiji OO (2001) Natural radioactivity measurements in rock samples of Ondo and Ekiti states in Nigeria. Radiat Meas 33(1):13–16

    Article  Google Scholar 

  • Barnett MO, Jardine PM, Brooks SC (2002) U(VI) adsorption to heterogeneous subsurface media: application of a surface complexation model. Environ Sci Technol 36(5):937–942

    Article  Google Scholar 

  • Bell KG (1963) Uranium in Carbonate Rocks. Geological survey professional paper 474-A (U.S. Atomic Energy Commission). United States Government Printing Office, Washington

    Google Scholar 

  • Boyle RW (1982) Geochemical prospecting for thorium and uranium deposits. Geological Survey of Canada, Ottawa

    Google Scholar 

  • Chowdhury MI, Alam MN, Hazari SKS (1999) Distribution of radionuclides in the river sediments and coastal soils of Chittagong, Bangladesh and evaluation of the radiation hazard. Appl Radiat Isot 51(6):747–755

    Article  Google Scholar 

  • Dalvi AA, Kumar SD, Reddy AVR (2013) A site-specific study on the measurement of sorption coefficients for radionuclides. Int J Environ Sci Technol 11(3):617–622

    Article  Google Scholar 

  • Derin M, Vijayagopal P, Venkatraman B, Chaubey RC, Gopinathan A (2012) Radionuclides and radiation indices of high background radiation area in Chavara-Neendakara placer deposits (Kerala, India). PLoS ONE 7(11):e50468

    Article  Google Scholar 

  • EC (1999) Radiological protection principles concerning the natural radioactivity of building materials. European Commission. Radiation Protection Unit. Radiation Protection, p 112

  • Echevarria G, Sheppard MI, Morel J (2001) Effect of pH on the sorption of uranium in soils. J Environ Radioact 53(2):257–264

    Article  Google Scholar 

  • El-Gamal A, Nasr S, El-Taher A (2007) Study of the spatial distribution of natural radioactivity in the upper Egypt Nile River sediments. Radiat Meas 42(3):457–465

    Article  Google Scholar 

  • Folk RL, Ward WC (1957) Brazos River bar [Texas]; a study in the significance of grain size parameters. J Sediment Res 27(1):3–26

    Article  Google Scholar 

  • Fox PM, Davis JA, Zachara JM (2006) The effect of calcium on aqueous uranium (VI) speciation and adsorption to ferrihydrite and quartz. Geochim et Cosmochim Acta 70(6):1379–1387

    Article  Google Scholar 

  • Guagliardi I, Rovella N, Apollaro C, Bloise A, De Rosa R, Scarciglia F, Buttafuoco G (2016) Effects of source rocks, soil features and climate on natural gamma radioactivity in the Crati valley (Calabria, Southern Italy). Chemosphere 150:97–108

    Article  Google Scholar 

  • Gupta PK (2004) Soil, plant, water and fertilizer analysis. Agrobios (India), Jodhpur

    Google Scholar 

  • Hans Wedepohl K (1995) The composition of the continental crust. Geochim Cosmochim et Acta 59(7):1217–1232

    Article  Google Scholar 

  • Hu B, Li J, Bi N, Wang H, Yang J, Wei H, Zhao J, Li G, Yin X, Liu M, Zou L, Li S (2015) Seasonal variability and flux of particulate trace elements from the Yellow River: impacts of the anthropogenic flood event. Mar Pollut Bull 91(1):35–44

    Article  Google Scholar 

  • Kalpana G, Shanmugasundharam A, Nethaji S, Viswam A, Kalaivanan R, Gopal V, Jayaprakash M (2015) Evaluation of total trace metal (TTMs) enrichment from estuarine sediments of Uppanar, southeast coast of India. Arabian J Geosci 9(1):1–14

    Google Scholar 

  • Kathren RL (1998) NORM sources and their origins. Appl Radiat Isot 49(3):149–168

    Article  Google Scholar 

  • Krishnamoorthy N, Mullainathan S, Mehra R, Chaparro MAE, Chaparro MAE (2013) Evaluation of natural radioactivity and its associated health hazard indices of a south Indian River. Radiat Prot Dosim 162(3):364–374. doi:10.1093/rpd/nct288

    Article  Google Scholar 

  • Krishnamoorthy N, Mullainathan S, Mehra R, Chaparro MAE, Chaparro MAE (2014) Radiation impact assessment of naturally occurring radionuclides and magnetic mineral studies of Bharathapuzha river sediments, South India. Environ Earth Sci 71(8):3593–3604

    Google Scholar 

  • Krmar M, Varga E, Slivka J (2013) Correlations of natural radionuclides in soil with those in sediment from the Danube and nearby irrigation channels. J Environ Radioact 117:31–35

    Article  Google Scholar 

  • Kumarasamy P (2010) Environmental impact assessment for Tamiraparani river basin, Tamil Nadu, South India. Doctor of Philosophy Thesis Department of Marine Science, Bharathidasan University

  • Kumarasamy P, Arthur James R, Dahms H-U, Byeon C-W, Ramesh R (2014) Multivariate water quality assessment from the Tamiraparani river basin, Southern India. Environ Earth Sci 71(5):2441–2451

    Article  Google Scholar 

  • Livshits TS (2009) Stability of artificial ferrite garnets with actinides and lanthanoids in water solutions. Geol Ore Deposits 50(6):470–481

    Article  Google Scholar 

  • Lu X, Zhang X, Wang F (2008) Natural radioactivity in sediment of Wei River, China. Environ Geol 53(7):1475–1481

    Article  Google Scholar 

  • Madruga MJ, Silva L, Gomes AR, Libânio A, Reis M (2014) The influence of particle size on radionuclide activity concentrations in Tejo River sediments. J Environ Radioact 132:65–72

    Article  Google Scholar 

  • Magesh NS, Chandrasekar N, Vetha Roy D (2011) Spatial analysis of trace element contamination in sediments of Tamiraparani estuary, southeast coast of India. Estuar Coast Shelf Sci 92(4):618–628

    Article  Google Scholar 

  • Martin P, Haniffa MA, Arunachalam M (2000) Abundance and diversity of macroinvertebrates and fish in the Tamiraparani river, South India. Hydrobiologia 430(1):59–75

    Article  Google Scholar 

  • Melson Nathan H, Haliena Brian P, Kaplan Daniel I, Barnett Mark O (2012) Adsorption of tetravalent thorium by geomedia. Radiochim Acta 100(11):827

    Article  Google Scholar 

  • Merkel B, Planer-Friedrich B, Wolkersdorfer C (2012) Uranium in the aquatic environment. In: Proceedings of the International Conference Uranium Mining and Hydrogeology III and the International Mine Water Association Symposium Freiberg, Germany. Springer, Heidelberg, pp 15–21

  • Muller G (1981) Die Schwermetallbelastung der sedimenten des Neckars und Seine Nebenflusse. Chemiker Zeitung 6:157–164

    Google Scholar 

  • Narayana Y, Rajashekara KM, Siddappa K (2007) Natural radioactivity in some major rivers of coastal Karnataka on the southwest coast of India. J Environ Radioact 95(2–3):98–106

    Article  Google Scholar 

  • Ndlela SC, Shanks BH (2003) Reducibility of potassium-promoted iron oxide under hydrogen conditions. Ind Eng Chem Res 42(10):2112–2121

    Article  Google Scholar 

  • Örgün Y, Altınsoy N, Şahin SY, Güngör Y, Gültekin AH, Karahan G, Karacık Z (2007) Natural and anthropogenic radionuclides in rocks and beach sands from Ezine region (Çanakkale), Western Anatolia, Turkey. Appl Radiat Isot 65(6):739–747

    Article  Google Scholar 

  • Philander C, Rozendaal A (2012) Rare-earth element and thorium potential of heavy mineral deposits along the West Coast of South Africa with special reference to the Namakwa Sands deposit. In: Broekmans ATMM (ed) Proceedings of the 10th international congress for applied mineralogy (ICAM). Springer, Heidelberg, pp 531–539

    Chapter  Google Scholar 

  • Radhakrishna AP, Somashekarappa HM, Narayana Y, Siddappa K (1993) A new natural background radiation area on the southwest coast of India. Health Phys 65(4):390–395

    Article  Google Scholar 

  • Rajganapathi VC, Jitheshkumar N, Sundararajan M, Bhat KH, Velusamy S (2013) Grain size analysis and characterization of sedimentary environment along Thiruchendur coast, Tamilnadu, India. Arabian J Geosci 6(12):4717–4728

    Article  Google Scholar 

  • Ramasamy V, Suresh G, Meenakshisundaram V, Ponnusamy V (2011a) Horizontal and vertical characterization of radionuclides and minerals in river sediments. Appl Radiat Isot 69(1):184–195

    Article  Google Scholar 

  • Ramasamy V, Suresh G, Rajkumar P, Murugesan S, Mullainathan S, Meenakshisundaram V (2011b) Reassessment and comparison of natural radioactivity levels in relation to granulometric contents of recently excavated major river sediments. J Radioanal Nucl Chem 292(1):381–393

    Article  Google Scholar 

  • Ramasamy V, Sundarrajan M, Paramasivam K, Meenakshisundaram V, Suresh G (2013) Assessment of spatial distribution and radiological hazardous nature of radionuclides in high background radiation area, Kerala, India. Appl Radiat Isot 73:21–31

    Article  Google Scholar 

  • Ramasamy V, Paramasivam K, Suresh G, Jose MT (2014) Function of minerals in the natural radioactivity level of Vaigai River sediments, Tamilnadu, India—Spectroscopical approach. Spectrochim Acta Mol Biomol Spectrosc 117:340–350

    Article  Google Scholar 

  • Rojo I, Seco F, Rovira M, Giménez J, Cervantes G, Martí V, de Pablo J (2009) Thorium sorption onto magnetite and ferrihydrite in acidic conditions. J Nucl Mater 385(2):474–478

    Article  Google Scholar 

  • Santawamaitre T, Malain D, Al-Sulaiti HA, Bradley DA, Matthews MC, Regan PH (2014) Determination of 238U, 232Th and 40 K activity concentrations in riverbank soil along the Chao Phraya river basin in Thailand. J Environ Radioact 138:80–86

    Article  Google Scholar 

  • Selvasekarapandian S, Muguntha Manikandan N, Sivakumar R, Balasubramanian S, Venkatesan T, Meenakshisundram V, Ragunath VM, Gajendran V (1999) Gamma radiation dose from radionuclides in soil samples of Udagamandalam (Ooty) in India. Radiat Prot Dosim 82(3):225–228

    Article  Google Scholar 

  • Solai A, Gandhi MS, Chandrasekaran K, Mohan VR (2013) Depositional environment in and around Tamiraparani estuary, and off Tuticorin, Tamil Nadu, India: clues from grain size studies. Arabian J Geosci 6(7):2419–2446

    Article  Google Scholar 

  • Suresh G, Ramasamy V, Meenakshisundaram V, Venkatachalapathy R, Ponnusamy V (2011) A relationship between the natural radioactivity and mineralogical composition of the Ponnaiyar river sediments, India. J Environ Radioact 102(4):370–377

    Article  Google Scholar 

  • TRS-419 (2003) Extent of environmental contamination by naturally occurring radioactive material (norm) and technological options for mitigation. Technical reports series (No. 419)

  • Tucker ME (2009) Sedimentary petrology: an introduction to the origin of sedimentary rocks, 3rd edn. Wiley, Tucker

    Google Scholar 

  • UNSCEAR (1982) Ionizing radiation: sources and biological effects. United Nations Scientific Committee on the Effects of Atomic Radiation 1982 Report to the General Assembly, with Annexes. United Nations, New York

  • UNSCEAR (2008) United Nations Scientific Committee on the Effect of Atomic Radiation. Sources and Effects of Ionizing Radiation. Report to General Assembly with Scientific Annexes, United Nations, New York. Vol 1, Annex B. http://www.unscear.org/docs/publications/2008/UNSCEAR_2008_Annex-B-CORR.pdf

  • Vargehese NM (2011) Studies on tectonic, climate and other geologic controls of fluvial sediment composition of Tamiraparani river, Tirunelveli and Tuticorin Districts, Tamil Nadu. Master of Science, Dissertation Department of Geology, University of Madras

  • Wang L-L, Zhang H, Cheng X-L (2015) First-principles studies on K-promoted porous iron oxide catalysts. Comput Condens Matter 3:46–52

    Article  Google Scholar 

Download references

Acknowledgements

We acknowledge and thank Dr. M. T. Jose, Mr. S.M.S. Murthy and Mr. R. Ramar, IGCAR, Kalpakkam, for valuable suggestion and technical support. A sincere thanks to Dr. L. Isaiarasu Department of Zoology, ANJA College, Sivakasi for the help and comments. The assistance of Henry Jhonson, Arputha Anand, Manuel. T. Kagoo, Amalraj, Louies and Shanmuga sundaram during field trip is also gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Stephen.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Inigo Valan, I., Vijayalakshmi, I., Mathiyarasu, R. et al. Influence of geochemical variation and heavy mineral component on primordial radionuclide presence in Tamiraparani River sediments. Environ Earth Sci 76, 69 (2017). https://doi.org/10.1007/s12665-017-6400-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12665-017-6400-8

Keywords

Navigation