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Identifying interactions between river water and groundwater in the North China Plain using multiple tracers

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Abstract

Interactions between river water and groundwater have been used to help understand the movement of water and to evaluate water quality in the semi-arid area of the North China Plain (NCP). Stable isotopes, chlorofluorocarbons (CFCs) and hydrochemistry were used to study the influence of surface water from the Xiao River on regional groundwater. Using a mass balance approach based on chloride concentrations, hydrogen and oxygen isotope ratios, the average fraction of surface water recharging to groundwater was 50–60 %. CFC results indicated that the groundwater recharge age varied from 22.5 to 39.5 years. The vertical flow velocity of groundwater was estimated at about 1.8–3.5 m year−1. Nitrate concentrations in groundwater varied from 9.42 to 156.62 mg L−1, and exceeded 50 mg L−1 in most aquifers shallower than 80 m bordering the Xiao River. The δ 15N-NO3 data indicate that the major sources of nitrogen in groundwater are human sewage and animal excreta. Because groundwater is the main source of drinking water, there should be concern about public health related to the elevated nitrate concentrations in the NCP.

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References

  • Agrawal G, Lunkad S, Malkhed T (1999) Diffuse agricultural nitrate pollution of groundwaters in India. Water Sci Technol 39(3):67–75

    Article  Google Scholar 

  • Bennetts D, Webb J, Stone D, Hill D (2006) Understanding the salinisation process for groundwater in an area of south-eastern Australia, using hydrochemical and isotopic evidence. J Hydrol 323(1):178–192

    Article  Google Scholar 

  • Busenberg E, Plummer LN (2008) Dating groundwater with trifluoromethyl sulfurpentafluoride (SF5CF3), sulfur hexafluoride (SF6), CF3Cl (CFC-13), and CF2Cl2 (CFC-12). Water Resour Res 44, W02431. doi:10.1029/2007WR006150

  • Cao Y, Tang C, Song X, Liu C, Zhang Y (2012) Characteristics of nitrate in major rivers and aquifers of the Sanjiang Plain, China. J Environ Monit 14(10):2624–2633

    Article  Google Scholar 

  • Chen J (2010) Holistic assessment of groundwater resources and regional environmental problems in the North China Plain. Environ Earth Sci 61(5):1037–1047

    Article  Google Scholar 

  • Chen Z, Qi J, Xu J, Xu J, Ye H, Na Y (2003) Paleoclimatic interpretation of the past 30 ka from isotopic studies of the deep confined aquifer of the North China plain. Appl Geochem 18(7):997–1009

    Article  Google Scholar 

  • Chen J, Tang C, Yu J (2006) Use of 18O, 2H and 15N to identify nitrate contamination of groundwater in a wastewater irrigated field near the city of Shijiazhuang, China. J Hydrol 326(1):367–378

    Article  Google Scholar 

  • Chen X, Ling M, Zhou Q, Zhang Z, Cheng Q (2012) Numerical modeling the role of rubber dams on groundwater recharge and phreatic evaporation loss in riparian zones. Environ Earth Sci 65(1):345–352

    Article  Google Scholar 

  • Christophersen N, Hooper P (1992) Multivariate analysis of stream water chemical data: the use of principal components analysis for the end-member mixing problem. Water Resour Res 28:99–107

    Article  Google Scholar 

  • Clark D, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishers, New York

    Google Scholar 

  • Cook PG, Favreau G, Dighton JC, Tickell S (2003) Determining natural groundwater influx to a tropical river using radon, chlorofluorocarbons and ionic environmental tracers. J Hydrol 277:74–88

    Article  Google Scholar 

  • Darling W, Bath A, Talbot J (2003) The O and H stable isotope composition of freshwaters in the British Isles. 2, surface waters and groundwater. Hydrol Earth Syst Sci 7:183–195

    Article  Google Scholar 

  • Dor N, Syafalni S, Abustan I, Rahman MTA, Nazri MAA, Mostafa R, Mejus L (2011) Verification of surface–groundwater connectivity in an irrigation canal using geophysical, water balance and stable isotope approaches. Water Resour Manag 25(11):2837–2853

    Article  Google Scholar 

  • Gooddy DC, Darling WG, Abesser C, Lapworth DJ (2006) Using chlorofluorocarbons (CFCs) and sulphur hexafluoride (SF6) to characterise groundwater movement and residence time in a lowland Chalk catchment. J Hydrol 330(1):44–52

    Article  Google Scholar 

  • Han DM, Song XF, Currell MJ, Tsujimura M (2012) Using chlorofluorocarbons (CFCs) and tritium to improve conceptual model of groundwater flow in the South Coast Aquifers of Laizhou Bay, China. Hydrol Process 26(23):3614–3629

    Article  Google Scholar 

  • IAEA/WMO (2004) Global network of isotopes in precipitation. The GNIP database. Accessible at http://isohis.iaea.org

  • Katz BG, Chelette AR, Pratt TR (2004) Use of chemical and isotopic tracers to assess nitrate contamination and ground-water age, Woodville Karst Plain, USA. J Hydrol 289(1):36–61

    Article  Google Scholar 

  • Kendall C, McDonnell J (1998) Isotope tracers in catchment hydrology. Elsevier, Amsterdam

    Google Scholar 

  • Kohl DH, Shearer GB, Commoner B (1971) Fertilizer nitrogen: contribution to nitrate in surface water in a corn belt watershed. Science 174(4016):1331–1334

    Article  Google Scholar 

  • Kreuzer AM, von Rohden C, Friedrich R, Chen Z, Shi J, Hajdas I, Kipfer R, Aeschbach-Hertig W (2009) A record of temperature and monsoon intensity over the past 40 kyr from groundwater in the North China Plain. Chem Geol 259(3):168–180

    Article  Google Scholar 

  • Kumazawa K (2002) Nitrogen fertilization and nitrate pollution in groundwater in Japan: present status and measures for sustainable agriculture. Nutr Cycl Agroecosyst 63(2–3):129–137

    Article  Google Scholar 

  • Li F, Pan G, Tang C, Zhang Q, Yu J (2008a) Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system, southwest of North China Plain. Environ Geol 55(5):1109–1122

    Article  Google Scholar 

  • Li F, Tang C, Yang Y, Zhang Q, Liu C, Zhang W (2008b) Trefry M Nitrate contamination of groundwater in the alluvial fans of the Taihang Mts and Yanshan Mts. In: Proceedings of the groundwater quality 2007 conference, Fremantle, Australia, 2–7 December 2007. IAHS Press, Oxfordshire, pp 79–85

  • Li F, Tang C, Zhang Q, Pan G (2008c) Surface water–groundwater interactions in a Yellow River alluvial fan. IAHS-AISH publication, Oxfordshire, pp 189–196

  • Lis G, Wassenaar L, Hendry M (2008) High-precision laser spectroscopy D/H and 18O/16O measurements of microliter natural water samples. Anal Chem 80(1):287–293

    Google Scholar 

  • Liu C, Xia J (2004) Water problems and hydrological research in the Yellow River and the Huai and Hai River basins of China. Hydrol Process 18(12):2197–2210

    Article  Google Scholar 

  • Liu C, Yu J, Eloise K (2001) Groundwater exploitation and its impact on the environment in the North China Plain. Water Int 26(2):265–272

    Article  Google Scholar 

  • Liu C, Zhang X, Zhang Y (2002) Determination of daily evaporation and evapotranspiration of winter wheat and maize by large-scale weighing lysimeter and micro-lysimeter. Agric For Meteorol 111(2):109–120

    Article  Google Scholar 

  • Lu Y, Tang C, Chen J, Song X, Li F, Sakura Y (2008) Spatial characteristics of water quality, stable isotopes and tritium associated with groundwater flow in the Hutuo River alluvial fan plain of the North China Plain. Hydrogeol J 16(5):1003–1015

    Article  Google Scholar 

  • McIsaac GF, David MB, Gertner GZ, Goolsby DA (2001) Eutrophication: nitrate flux in the Mississippi river. Nature 414(6860):166–167

    Article  Google Scholar 

  • Mo X, Liu S, Lin Z, Guo R (2009) Regional crop yield, water consumption and water use efficiency and their responses to climate change in the North China Plain. Agric Ecosyst Environ 134(1):67–78

    Article  Google Scholar 

  • Nolan BT, Hitt KJ (2006) Vulnerability of shallow groundwater and drinking-water wells to nitrate in the United States. Environ Sci Technol 40(24):7834–7840

    Article  Google Scholar 

  • Orban P, Brouyère S, Batlle-Aguilar J, Couturier J, Goderniaux P, Leroy M, Maloszewski P, Dassargues A (2010) Regional transport modelling for nitrate trend assessment and forecasting in a chalk aquifer. J Contam Hydrol 118(1):79–93

    Article  Google Scholar 

  • Oster H, Sonntag C, Münnich K (1996) Groundwater age dating with chlorofluorocarbons. Water Resour Res 32(10):2989–3001

    Article  Google Scholar 

  • Panno S, Hackley K, Hwang H, Kelly W (2001) Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators. Chem Geol 179(1):113–128

    Article  Google Scholar 

  • Panno S, Hackley K, Hwang H, Greenberg S, Krapac I, Landsberger S, O’Kelly D (2006) Characterization and identification of Na-Cl sources in ground water. Ground Water 44(2):176–187

    Article  Google Scholar 

  • Robinson D (2001) δ 15N as an integrator of the nitrogen cycle. Trends Ecol Evol 16(3):153–162

    Article  Google Scholar 

  • Rohden C, Kreuzer A, Chen Z, Kipfer R, Aeschbach-Hertig W (2010) Characterizing the recharge regime of the strongly exploited aquifers of the North China Plain by environmental tracers. Water Resour Res 46:W05511. doi:10.1029/2008WR007660

    Google Scholar 

  • Sato Y, Ma X, Xu J, Matsuoka M, Zheng H, Liu C, Fukushima Y (2008) Analysis of long-term water balance in the source area of the Yellow River basin. Hydrol Process 22(11):1618–1629

    Article  Google Scholar 

  • Silva S, Kendall C, Wilkison D, Ziegler A, Chang C, Avanzino R (2000) A new method for collection of nitrate from fresh water and the analysis of nitrogen and oxygen isotope ratios. J Hydrol 228(1):22–36

    Article  Google Scholar 

  • Song X, Liu X, Xia J, Yu J, Tang C (2006) A study of interaction between surface water and groundwater using environmental isotope in Huaisha River basin. Sci China Ser D Earth Sci 49(12):1299–1310

    Article  Google Scholar 

  • Song X, Wang P, Yu J, Liu X, Liu J, Yuan R (2011) Relationships between precipitation, soil water and groundwater at Chongling catchment with the typical vegetation cover in the Taihang mountainous region, China. Environ Earth Sci 62(4):787–796

    Article  Google Scholar 

  • Stellato L, Petrella E, Terrasi F, Belloni P, Belli M, Sansone U, Celico F (2008) Some limitations in using 222Rn to assess river–groundwater interactions: the case of Castel di Sangro alluvial plain (central Italy). Hydrogeol J 16(4):701–712

    Article  Google Scholar 

  • Tang C, Shindo S, Sakura Y, Li X (2003) Utilization of water resources and its effects on the hydrological environment of the Tarim River basin in Xinjiang, China. Int Assoc Hydrol Sci Publ 280:23–29

    Google Scholar 

  • Tang C, Chen J, Shindo S, Sakura Y, Zhang W, Shen Y (2004) Assessment of groundwater contamination by nitrates associated with wastewater irrigation: a case study in Shijiazhuang region. China. Hydrol Process 18(12):2303–2312

    Article  Google Scholar 

  • Wang S, Song X, Wang Q, Xiao G, Wang Z, Liu X, Wang P (2012) Shallow groundwater dynamics and origin of salinity at two sites in salinated and water-deficient region of North China Plain. China. Environ Earth Sci 66(3):729–739

    Article  Google Scholar 

  • Weiskel PK, Howes BL (1992) Differential transport of sewage-derived nitrogen and phosphorus through a coastal watershed. Environ Sci Technol 26(2):352–360

    Article  Google Scholar 

  • Xue D, Botte J, De Baets B, Accoe F, Nestler A, Taylor P, Van Cleemput O, Berglund M, Boeckx P (2009) Present limitations and future prospects of stable isotope methods for nitrate source identification in surface- and groundwater. Water Res 43(5):1159–1170

    Article  Google Scholar 

  • Yang R, Liu W (2010) Nitrate contamination of groundwater in an agroecosystem in Zhangye Oasis, Northwest China. Environ Sci Technol 61(1):123–129

    Google Scholar 

  • Yang Y, Watanabe M, Sakura Y, Changyuan T, Hayashi S (2004) Groundwater-table and recharge changes in the Piedmont region of Taihang Mountain in Gaocheng City and its relation to agricultural water use. Water SA 28(2):171–178

    Google Scholar 

  • Yang Y, Watanabe M, Zhang X, Zhang J, Wang Q, Hayashi S (2006) Optimizing irrigation management for wheat to reduce groundwater depletion in the piedmont region of the Taihang Mountains in the North China Plain. Agric Water Manage 82(1):25–44

    Article  Google Scholar 

  • Yang L, Song X, Zhang Y, Han D, Zhang B, Long D (2012) Characterizing interactions between surface water and groundwater in the Jialu River basin using major ion chemistry and stable isotopes. Hydrol Earth Syst Sci 16(11):4265

    Article  Google Scholar 

  • Yuan R, Song X, Zhang Y, Han D, Wang S, Tang C (2011) Using major ions and stable isotopes to characterize recharge regime of a fault-influenced aquifer in Beiyishui River Watershed, North China Plain. J Hydrol 405(3):512–521

    Article  Google Scholar 

  • Zhang W, Tian Z, Zhang N, Li X (1996) Nitrate pollution of groundwater in northern China. Agric Ecosyst Environ 59(3):223–231

    Article  Google Scholar 

  • Zhang G, Chen Z, Fei Y (2000) Relationship between the formation of groundwater and the evolution of regional hydrologic cycle in North China Plain (in Chinese). Adv Water Sci 11(4):415–420

    Google Scholar 

  • Zhang Z, Fei Y, Chen Z, Zhao Z, Xie Z, Wang Y, Miao J, Yang L, Shao J, Jin M, Xu G, Yang Q (2009) Investigation and assessment of sustainable utilization of groundwater resources in the North China Plain. Geological Publishing House, Beijing (in Chinese)

    Google Scholar 

  • Zhuang C, Ouyang Z, Xu W, Bai Y, Zhou W, Zheng H, Wang X (2011) Impacts of human activities on the hydrology of Baiyangdian Lake, China. Environ Earth Sci 62(7):1343–1350

    Article  Google Scholar 

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Acknowledgments

The authors thank Assistant Prof. Dr. Miwa Matsushima of Chiba University for δ 15N analyses and also thank Dr. Zhang Yucui of Agricultural Resources Research Center for sample collections. Especially thank reviewers and Dr. Cao yingjie for improving our manuscript.

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Correspondence to Changyuan Tang.

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Dun, Y., Tang, C. & Shen, Y. Identifying interactions between river water and groundwater in the North China Plain using multiple tracers. Environ Earth Sci 72, 99–110 (2014). https://doi.org/10.1007/s12665-013-2989-4

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