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Transport and mobilization of multiwall carbon nanotubes in quartz sand under varying saturation

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Abstract

In this study, a series of sand packed columns were used to investigate the mobility of multiwall carbon nanotubes (MWCNTs) in unsaturated porous media under unfavorable conditions for deposition. The flow through column experiments were designed to assess water content, flow rate, and grain size effect on the mobility of MWCNTs. It was found that variation in water content had no significant effect on retention of MWCNTs until it was lowered to 16 % effective saturation. Thick water films, high flow rate, and repulsive forces between MWCNTs and porous media made MWCNTs highly mobile. Different porous media grain sizes (D 50 = 150–300 μm) were used in this study. The mobility of MWCNTs slightly decreased in finer grain sands, which was deemed to be an effect of increase in surface area and the number of depositional sites, in combination with low-pore water velocity. However, physical straining was not observed in selected fine-grain sands and aspect ratio of MWCNTs had low impact on mobility. Variations in pore-water velocity were produced by both changes in water saturation and in flow rate. At high pore-water velocities, the MWCNTs were generally mobile. However, for the combination of low-pore water velocity with either low water saturation or small grain size, some retention of MWCNTs was observed. Hence, low velocity in combination with flow through smaller pores increased MWCNT deposition.

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References

  • Aramrak S, Flury M, Harsh JB, Zollars RL, Davis HP (2013) Does colloid shape affect detachment of colloids by a moving air-water interfaces? Langmuir 29:5770–5780

    Article  Google Scholar 

  • Auffan M, Rose J, Bottero JY, Lowry GV, Jolivet JP, Wiesner MR (2009) Towards a definition of inorganic nanoparticles from an environmental, health and safety perspective. Nature nanotechnol 4:634–641

    Article  Google Scholar 

  • Auset M and Keller AA (2006) Pore-scale visualization of colloid straining and filtration in saturated porous media using micromodels. Water Resour Res 42: W12S02

  • Bradford SA, Torkzaban S, Walker SL (2007) Coupling of physical and chemical mechanisms of colloid straining in saturated porous media. Water Res 41:3012–3024

    Article  Google Scholar 

  • Canales RM, Guan H, Bestland E, Hutson J, Simmons CT (2013) Particle-size effects on dissolved arsenic adsorption to an Australian laterite. Environ Earth Sci 68:2301–2312

    Article  Google Scholar 

  • Chen L, Sabatini DA, Kibbey TC (2008) Role of the air-water interface in the retention of TiO2 nanoparticles in porous media during primary drainage. Environ Sci Technol 42:1916–1921

    Article  Google Scholar 

  • Corapcioglu MY, Choi H (1996) Modeling colloid transport in unsaturated porous media and validation with laboratory column data. Water Resour Res 32:3437–3449

    Article  Google Scholar 

  • Crist JT, Zevi Y, McCarthy JF, Throop JA, Steenhuis TS (2005) Transport and retention mechanisms of colloids in partially saturated porous media. Vadose Zone J 4:184–195

    Article  Google Scholar 

  • Cullen E, O’Carroll DM, Yanful EK, Sleep B (2010) Simulation of the subsurface mobility of carbon nanoparticles at the field scale. Adv Water Resour 33:361–371

    Article  Google Scholar 

  • Dane JH, Hopmans JW (2002) Hanging water column. In: Dane JH, Topp GC (eds) Methods of Soil Analysis, Part 4 Physical Methods. Soil Science Society of America, Madison, pp 680–683

    Google Scholar 

  • Elmi A, Abou Nohra JS, Madramootoo CA, Hendershot W (2012) Estimating phosphorus leachibility in reconstructed soil columns using HYDRUS-1D model. Environ Earth Sci 65:1751–1758

    Article  Google Scholar 

  • Flahaut E (2011) Toxicity and environmental impact of carbon nanotubes carbon nanotubes for biomedical applications. Carbon Nanostruct 3:211–219

    Google Scholar 

  • Gao B, Saiers JE, Ryan J (2006) Pore-scale mechanisms of colloid deposition and mobilization during steady and transient flow through unsaturated granular media. Water Resour Res 42:W01410

    Article  Google Scholar 

  • Gao B, Steenhuis TS, Zevi Y, Morales VL, Nieber JL, Richards BK, Parlange JY (2008) Capillary retention of colloids in unsaturated porous media. Water Resour Res 44:W04504

    Article  Google Scholar 

  • Jaisi DP, Elimelech M (2009) Single-walled carbon nanotubes exhibit limited transport in soil columns. Environ Sci Technol 43:9161–9166

    Article  Google Scholar 

  • Jaisi DP, Saleh NB, Blake RE, Elimelech M (2008) Transport of single-walled carbon nanotubes in porous media: filtration mechanisms and reversibility. Environ Sci Technol 42:8317–8323

    Article  Google Scholar 

  • Kennedy AJ, Hull MS, Steevens JA, Dontsova KM, Chappell MA, Gunter JC, Weiss CA Jr (2008) Factors influencing the partitioning and toxicity of nanotubes in the aquatic environment. Environ Toxicol Chem 27:1932–1941

    Article  Google Scholar 

  • Klaine SJ, Alvarez PJJ, Batley GE, Fernandes TF, Handy RD, Lyon DY, Lead JR (2008) Nanomaterials in the environment: behavior, fate, bioavailability, and effects. Environ Toxicol Chem 27:1825–1851

    Article  Google Scholar 

  • Liu X, O’Carroll DM, Petersen EJ, Huang Q, Anderson CL (2009) Mobility of multi-walled carbon nanotubes in porous media. Environ Sci Technol 43:8153–8158

    Article  Google Scholar 

  • Mattison NT, O’Carroll DM, Kerry Rowe R, Petersen EJ (2011) Impact of porous media grain size on the transport of multi-walled carbon nanotubes. Environ Sci Technol 45:9765–9775

    Article  Google Scholar 

  • Mauter MS, Elimelech M (2008) Environmental applications of carbon-based nanomaterials. Environ Sci Technol 42:5843–5859

    Article  Google Scholar 

  • Monteiro-Riviere NA, Nemanich RJ, Inman AO, Wang YY, Riviere JE (2005) Multi-walled carbon nanotube interactions with human epidermal keratinocytes. Toxicol. Letters 155:377–384

    Article  Google Scholar 

  • Monthioux M, Serp P, Flahaut E, Razafinimanana M, Laurent C, Peigney A, Broto JM (2007) Introduction to carbon nanotubes. Springer Handbook of Nanotechnology, ISBN: 978-3-540-29855-7. Springer, Berlin

  • Pan B, Xing B (2008) Adsorption mechanisms of organic chemicals on carbon nanotubes. Environ Sci Technol 42:9005–9013

    Article  Google Scholar 

  • Pérez S, Farré M, Barceló D (2009) Analysis, behavior and ecotoxicity of carbon-based nanomaterials in the aquatic environment. Trends Anal Chem 28:820–832

    Article  Google Scholar 

  • Petersen EJ, Zhang L, Mattison NT, O’Carroll DM, Whelton A, Uddin N, Holbrook RD (2011a) Potential release pathways, environmental fate, and ecological risks of carbon nanotubes. Environ Sci Technol 45:9837–9856

    Article  Google Scholar 

  • Petersen EJ, Pinto RA, Zhang L, Huang Q, Landrum PF, Weber WJ Jr (2011b) Effects of Polyethyleneimine-mediated functionalization of multi-walled carbon nanotubes on earthworm bioaccumulation and sorption by soils. Environ Sci Technol 45:3718–3724

    Article  Google Scholar 

  • Pfletschinger H, Engelhardt, Piepenbring M, Königer F, Schuhmann R, Kallioras A, Schuth C (2012) Soil column experiments to quantify vadose zone water fluxes in arid settings. Environ. Earth Sci 65:1523–1533

    Article  Google Scholar 

  • Phenrat T, Lowry GV, Hotze EM (2010) Nanoparticle aggregation: challenges to understanding transport and reactivity in the environment. J Environ Qual 39:1909–1924

    Article  Google Scholar 

  • Rao GP, Lu C, Su F (2007) Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review. Sep Purif Technol 58:224–231

    Article  Google Scholar 

  • Schijven JF, Hassanizadeh SM (2000) Removal of viruses by soil passage: overview of modeling, processes, and parameters. Crit Rev Environ Sci Technol 30:49–127

    Article  Google Scholar 

  • Scott-Fordsmand JJ, Krogh PH, Schaefer M, Johansen A (2008) The toxicity testing of double-walled nanotubes-contaminated food to Eisenia veneta earthworms. Ecotoxicol Environ Safety 71:616–619

    Article  Google Scholar 

  • Shang J, Flury M, Chen G, Zhuang J (2008) Impact of flow rate, water content, and capillary forces on in situ colloid mobilization during infiltration in unsaturated sediments. Water Resour Res 44:W06411

    Article  Google Scholar 

  • Sharma P, Abdou HM, Flury M (2008a) Effect of the lower boundary condition and flotation on colloid mobilization in unsaturated sandy sediments. Vadose Zone J 7:930–940

    Article  Google Scholar 

  • Sharma P, Flury M, Zhou J (2008b) Detachment of colloids from a solid surface by a moving air-water interface. J Colloid Interface Sci 326:143–150

    Article  Google Scholar 

  • Sharma P, Flury M, Mattson E (2008c) Studying colloid transport in porous media using a geocentrifuge. Water Resour Res 44:W07407. doi:10.1029/2007WR006456

    Article  Google Scholar 

  • Shen M, Wang SH, Shi X, Chen X, Huang Q, Petersen EJ, Weber WJ Jr (2009) Polyethyleneimine-mediated functionalization of multi-walled carbon nanotubes: synthesis, characterization, and in vitro toxicity assay. J Phys Chem C 113:3150–3156

    Article  Google Scholar 

  • Šimůnek J, van Genuchten MT, Šejna M (2008) Development and applications of the HYDRUS and STANMOD software packages and related codes. Vadose Zone J 7:587–600

    Article  Google Scholar 

  • Tan C, Tan K, Ong Y, Mohamed A, Zein S, Tan S (2012) Energy and environmental applications of carbon nanotubes. Environ Chem Lett 10:265–273

    Article  Google Scholar 

  • Tian Y, Gao B, Ziegler KJ (2011) High mobility of SDBS-dispersed single-walled carbon nanotubes in saturated and unsaturated porous media. J Hazard Mater 186:1766–1772

    Article  Google Scholar 

  • Tian Y, Gao B, Wang Y, Morales VL, Carpena RM, Huang Q, Yang L (2012a) Deposition and transport of functionalized carbon nanotubes in water-saturated sand columns. J Hazard Mater 213–214:265–272

    Article  Google Scholar 

  • Tian Y, Gao B, Morales VL, Wang Y, Yang L (2012b) Effect of surface modification on single-walled carbon nanotube retention and transport in saturated and unsaturated porous media. J Hazard Mater 239–240:333–339

    Article  Google Scholar 

  • Tiraferri A, Tosco T, Sethi R (2011) Transport and retention of microparticles in packed sand columns at low and intermediate ionic strengths: experiements and mathematical modeling. Environ Earth Sci 63:847–859

    Article  Google Scholar 

  • Torkzaban S, Bradford SA, Van Genuchten MT, Walker SL (2008) Colloid transport in unsaturated porous media: the role of water content and ionic strength on particle straining. J Contaminant Hydrol 96:113–127

    Article  Google Scholar 

  • Van Genuchten MT, Leij F, Yates S (1991) The RETC code for quantifying the hydraulic functions of unsaturated soils. U.S. Salinity Laboratory, USDA, Riverside

    Google Scholar 

  • Wan J, Tokunaga TK (1997) Film straining of colloids in unsaturated porous media: conceptual model and experimental testing. Environ Sci Technol 31:2413–2420

    Article  Google Scholar 

  • Wan J, Wilson JL (1994a) Visualization of the role of the gas-water interface on the fate and transport of colloids in porous media. Water Resour Res 30:11–24

    Article  Google Scholar 

  • Wan J, Wilson JL (1994b) Colloid transport in unsaturated porous media. Water Resour Res 30:857–864

    Article  Google Scholar 

  • Wang P, Shi Q, Liang H, Steuerman DW, Stucky GD, Keller AA (2008) Enhanced environmental mobility of carbon nanotubes in the presence of humic acid and their removal from aqueous solution. Small 4:2166–2170

    Article  Google Scholar 

  • Wang C, Wang L, Wang Y, Liang Y, Zhang J (2012) Toxicity effects of four typical nanomaterials on the growth of Escherichia coli, Bacillus subtilis and Agrobacterium tumefaciens. Environ Earth Sci 65:1643–1649

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Earth Sciences, Uppsala University, Villavagan 16, 75236, Uppsala, Sweden

    Abenezer Mekonen, Prabhakar Sharma & Fritjof Fagerlund

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  1. Abenezer Mekonen
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  2. Prabhakar Sharma
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  3. Fritjof Fagerlund
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Correspondence to Prabhakar Sharma.

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Mekonen, A., Sharma, P. & Fagerlund, F. Transport and mobilization of multiwall carbon nanotubes in quartz sand under varying saturation. Environ Earth Sci 71, 3751–3760 (2014). https://doi.org/10.1007/s12665-013-2769-1

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  • DOI: https://doi.org/10.1007/s12665-013-2769-1

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