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Magnetic Aluminosilicate Nanoclay: a Natural and Efficient Nanocatalyst for the Green Synthesis of 4H-Pyran Derivatives

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Abstract

In this study, the magnetic nanoparticles have been loaded on the halloysite nanotubes (HNTs) as an aluminosilicate clay mineral. Fe3O4/HNTs nanocomposite was fully characterized by Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray (EDX) analysis, thermogravimetric analysis (TGA), field-emission scanning electron microscopy (FE-SEM) image, transmission electron microscope (TEM) image, inductively coupled plasma (ICP) analysis, X-ray diffraction (XRD) pattern and vibrating sample magnetometer (VSM) curve. The performance of the Fe3O4/HNTs as a heterogeneous catalyst was investigated in the synthesis of 4H-pyran derivatives. The high efficiently, mild reaction condition, green solvents and using the eco-friendly and recoverable catalyst are the most advantages of the present work. Moreover, the simple separation and reuse of the Fe3O4/HNTs nanocatalyst were confirmed stability and efficiency of the catalyst after 7 runs.

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Acknowledgements

The authors gratefully acknowledge the partial support from the Research Council of the Iran University of Science and Technology.

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Authors and Affiliations

  1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, Iran

    Ali Maleki & Zoleikha Hajizadeh

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  1. Ali Maleki
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  2. Zoleikha Hajizadeh
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Maleki, A., Hajizadeh, Z. Magnetic Aluminosilicate Nanoclay: a Natural and Efficient Nanocatalyst for the Green Synthesis of 4H-Pyran Derivatives. Silicon 11, 2789–2798 (2019). https://doi.org/10.1007/s12633-019-0069-4

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  • DOI: https://doi.org/10.1007/s12633-019-0069-4

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