Abstract
A deconvolution method based iterative system was employed for the analysis of Infrared (IR) absorption spectra of some prepared lead silicate unfilled glasses together with samples filled with a low doping level of one of the first 3d-transition metal oxides (TMO’s) (TiO2→CuO) in the region of 4,000-400 cm-1. The IR spectra were analyzed to determine, evaluate, differentiate the various vibrational modes and to retrace precisely the role of low level doping of the different TMO’s in the structural changes. The first examination reveals a close similarity between the different transition metals doped samples, but careful inspection indicates there are some minor differences depending on the type of TM ions. These observed data are correlated with the similarity of the 3d orbitals in the neutral atoms and when the atoms are ionized. It was also observed that the 3d orbitals become more stable than the 4s orbitals.
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References
Wong J, Angell CA (1976) Glass structure by spectroscopy. Dekker, New York
Efimov AM (1999) J Non-Cryst Solids 235:95
Kamitsos EI, Varsamis CPE, Vegeri A (2001) Proc. Int. Glass, congres vol. I, Invited paper, Edimbargh, Scotland. pp 234–246
Kamitsos EI (2003) Phys Chem Glasses 44:79
Exarhos GJ (1986) In: Walrafen GE, Revesz AG (Eds.) Structure and bonding in Non-Crystalline Solids, Plenum, New York. p 203
Bates T (1962) Modern aspects of the vitreous state, Vol.2, Chapter 5, Ed. Mackenzie JD, Butterworths, London, p 195
Bamford CR (1977) Colour generation and control in glass, glass science & technology. Elsevier Scientific Publishing Company, Amsterdam
Khalil MM (2007) Appl. Phys A86:505
Shelby JE (1997) Introduction to glass science & technology. The Royal Socity of Chemistry, Cambridge
Levelut C, Le Parc R, Faivre A, Champagnon B (2006) J Non-Cryst Solids 352:4495
Tomozawa M, Hong JW, Ryu SR (2005) J Non-Cryst Solids 351:1054
Rabinovich E (1976) J Mater Sci 11:925
Weinstein IA, Zatsepin AF, Kortov VS (2001) J Non-Cryst Solids 279:77
Schlenz H, Kirfel A, Schulmeister K, Wartner N, Mader W, Raberg W, Wandelt K, Oligschleger C, Bender S, Franke R, Hormes J, Hoffbauer W, Lansmann V, Jansen M, Zotov N, Mariam C, Putz H, Neuefeind J (2002) J Non-Cryst Solids 297:37
Micoulaut M, Malki M, Simon P, Canizares A (2005) Philos Mag 85:3357
Rybicki J, Rybicka A, Witkowska A, Bergmanski G, Di Cicco A, Minicucci M, Mancini G (2001) J Phys: Condens Matter 13:9781
Hoppe U, Kranold U, Ghosh A, Landron C, Neuefeind J, Jovari P (2003) J Non-Cryst Solids 328:146
Imaoka M, Hasegawa H, Yasui I (1986) J Non-Cryst Solids 85:393
Wang PW, Zhang L (1996) J Non-Cryst Solids 194:129
Fayon F, Bessada C, Massiot D, Farnan I, Coutures JP (1998) J Non-Cryst Solids 232–234:403
Takaishi T, Takahashi M, Jin J, Uchino T, Yoko T (2005) J Am Ceram Soc 88:1591
Tanaka K, Yamada N, Oto M (2003) Appl Phys Lett 83:3012
Khalil MI, ElBatal FH, Nada N, Desouky SA (2003) Indian J Pure & Appl Phys 41:851
ElBatal FH, Nada N, Desouky SA, Khalil MI (2004) Indian J Pure & Appl Phys 42:711
Merzbacher CI, White WB (1991) J Non-Cryst Solids 130:18
Husung RD, Doremus RH (1990) J Mater Res 5(10):2209
El-Batal FH, Khalil EMA, Hamdy YM, Zidan HM, Aziz MS, Abdelghany AM (2010) Physica B 504:1294
Dunken H, Doremus RH (1987) J Non-Cryst Solids 92:61
Efimov AM (2003) J Non Cryst Solids 93:334
Khalil EMA, El-Batal FH, Hamdy YM, Zidan HM, Aziz MS, Abdelghany AM (2010) Silicon 2:49
Navara G (2007) J Non-Cryst Solids 353:555
Efimov AM (1995) Optical constants of inorganic glasses. CRC, Boca Raton
Efimov AM (1996) J Non-Cryst Solids 203:1
MdR A, Mortuzal MG (2005) J Non-Cryst Solids 351:2333
El-Batal FH, Khalil EMA, Hamdy YM, Zidan HM, Aziz MS, Abdelghany AM (2010) Silicon 2:41
Sari SO, Hollingsworth-Smith P, Ona H (1978) J Phys Chem Solids 39:857
Mirogrodskii AP, Pavinich VF, Lazarev AN (1980) In: Lazarev AN (ed) Vibrations of Oxide Lattices. Nauka, Moscow
Bell RJ, Bird NF, Dean P (1968) J Phys C1:299
Villegas MA, Fernandez Navarro JM (1988) J Mat Sci 23:2464
Agarwal A, Tomozawa M (1997) J Non-Cryst Solids 209:166
Cotton FA, Wilkinson G, Murillo CA, Bochmann M (1999) Advanced inorganic chemistry, 6th edn. Wiley, New York
Bates T (1962) Ligend field theory and absorption spectra of transition metal ions in glasses. In: Mackenzie JD (ed) Modern aspects of the vitreous state, vol 2. Butterworths, London, p 175
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Abdelghany, A.M. The Elusory Role of Low Level Doping Transition Metals in Lead Silicate Glasses. Silicon 2, 179–184 (2010). https://doi.org/10.1007/s12633-010-9053-8
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DOI: https://doi.org/10.1007/s12633-010-9053-8