Abstract
Copper matrix composites consisting of chromium (Cr) or ferrochrome (Cr-Fe) as strengthening elements and molybdenum disulfide as a lubricant had been sintered in nitrogen and hydrogen atmosphere, respectively. Their morphology and energy-dispersive X-ray spectrometry (EDS) analysis showed that serious interaction occurred between MoS2 and Cr (or Cr-Fe) particles when the samples were sintered in hydrogen atmosphere. Chromium sulfide compound (Cr x S y ) was formed as a reaction product, which decreased the density and strength of the composites remarkably. This interaction was inhibited when the samples were sintered in nitrogen atmosphere; thus, the mechanical properties of the composites were improved.
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A.M. Kovalchenko, O.I. Fushchich, and S. Danyluk, The tribological properties and mechanism of wear of Cu-based sintered powder materials containing molybdenum disulfide and molybdenum diselenite under unlubricated sliding against copper, Wear, 290–291(2012), p. 106.
W. Österle, C. Prietzel, H. Kloß, and A.I. Dmitriev, On the role of copper in brake friction materials, Tribol. Int., 43(2010), No. 12, p. 2317.
X. Xiong, H.C. Sheng, J. Chen, P.P. Yao, Effects of sintering pressure and temperature on microstructure and tribological characteristic of Cu-based aircraft brake material, Trans. Nonferrous Met. Soc. China, 17(2007), No. 4, p. 669.
D. Gultekin, M. Uysal, S. Aslan, M. Alaf, M.O. Guler, and H. Akbulut, The effects of applied load on the coefficient of friction in Cu-MMC brake pad/Al-SiCp MMC brake disc system, Wear, 270(2010), No. 1–2, p. 73.
J.H. Nie, C.C. Jia, X. Jia, Y. Li, Y.F. Zhang, and X.B. Liang, Fabrication and thermal conductivity of copper matrix composites reinforced by tungsten-coated carbon nanotubes, Int. J. Miner. Metall. Mater., 19(2012), No. 5, p. 446.
A. Hassani, A. Habibollahzadeh, and S. Sadeghinejad, Influence of vanadium and chromium additions on the wear resistance of a gray cast iron, Int. J. Miner. Metall. Mater., 19(2012), No. 7, p. 602.
D. Uzunsoy, E. Kelesoglu, and Y. Erarslan, Contribution of MoS2 additives to the microstructure and properties of PM copper based Brake material, Mater. Test., 51(2009), No. 5, p. 318.
W.O. Winer, Molybdenum disulfide as a lubricant: a review of the fundamental knowledge, Wear, 10(1967), No. 6, p. 422.
H. Kato, M. Takama, Y. Iwai, K. Washida, and Y. Sasaki, Wear and mechanical properties of sintered copper-tin composites containing graphite or molybdenum disulfide, Wear, 255(2003), No. 1–6, p. 573.
S. Dhanasekaran and R. Gnanamoorthy, Dry sliding friction and wear characteristics of Fe-C-Cu alloy containing molybdenum di sulphide, Mater. Des., 28(2007), No. 4, p. 1135.
S. Dhanasekaran and R. Gnanamoorthy, Heat generation in Fe-C-Cu-MoS2-sintered spur gears under unlubricated conditions, J. Eng. Tribol., 221(2007), No. 6, p. 645.
Y. Wang, Q.Z. Yan, F.F. Zhang, C.C. Ge, X.L. Zhang, and H.Q. Zhao, Interaction between Cr & MoS2 and effect on mechanical properties & microstructure of Cu based friction material, [in]_Proceedings of 10th China-Japan Joint Conference on Composite Materials, Chengdu, 2012, p. 321.
J. Chen, P.P. Yao, X. Xiong, and W.D. Qiao, The behaviors of MoS2 in the sintering process of Fe-based friction materials, Non Met Mines, 26(2003), No. 4, p. 50.
J.J. Tang, Y. Feng, X.T. Yang, C.J. Zhang, and Y.C. Xu, Effect of component change on electrical wear properties of Cu-MoS2-G composites, Met. Funct. Mater., 17(2010), No. 1, p. 41.
X. Xiong, J. Chen, P.P. Yao, J.H. Li, and B.Y. Huang, Effect of MoS2 on the sintering behaviors and mechanical properties of iron-based friction materials, Powder. Metall. Technol., 24(2006), No. 3, p. 182.
T.Q. Bai, L.S. Tong, and D.S. Li, Effects of MoS2 on properties of copper-based cermet friction materials, J. Mater. Eng., 5(2006), p. 25.
C.Y. Kan, J.Z. Liu, G.W. Zhang, and J.L. Ouyang, Preparation and tribological performance of a Ni-Cr-S alloy, Tribology, 14(1994), No. 3, p. 193.
J.L. Li, D.S. Xiong, and M.F. Huo, Friction and wear properties of Ni-Cr-W-Al-Ti-MoS2 at elevated temperatures and self-consumption phenomena, Wear, 265(2008), No. 3–4, p. 566.
D.B. Rao and H.G. Nelson, Influence of temperature and the role of chromium on the kinetics of sulfidation of 310 stainless steel, Oxid. Met., 12(1978), No. 2, p. 111.
R. Zhang, L. Gao, and J.K. Guo, Effect of Cu2O on the fabrication of SiCp/Cu nanocomposites using coated particles and conventional sintering, Compos. Part A, 35(2004), p. 1301.
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Wang, Y., Yan, Qz., Zhang, Ff. et al. Sintering behavior of Cr in different atmospheres and its effect on the microstructure and properties of copper-based composite materials. Int J Miner Metall Mater 20, 1208–1213 (2013). https://doi.org/10.1007/s12613-013-0856-7
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DOI: https://doi.org/10.1007/s12613-013-0856-7