Skip to main content
Log in

Mössbauer and electron microscopy study of martensitic transformations in an Fe-Mn-Mo alloy

  • Published:
International Journal of Minerals, Metallurgy, and Materials Aims and scope Submit manuscript

Abstract

The kinetic, morphological, crystallographic, and magnetic characteristics of thermally induced martensites in Fe-13.4wt% Mn-5.2wt% Mo alloy were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Mössbauer spectroscopy. The experimental results reveal that two types of thermal-induced martensites, ɛ (hcp) and α′ (bcc) martensites, are formed in the as-quenched condition, and these transformations have athermal characters. Mo addition to the Fe-Mn alloy does not change the coexistence of ɛ and α′ martensites with the Mn content between 10wt% and 15wt%. Besides, Mössbauer spectra reveal a paramagnetic character with a singlet for the γ (fcc) austenite and ɛ martensite phases and a ferromagnetic character with a broad sextet for the α′ martensite phase. The volume fraction of α′ martensite forming in the quenched alloy is much more than that of the ɛ martensite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T. Kirindi and M. Dikici, Microstructural analysis of thermally induced and deformation induced martensitic transformations in Fe-12.5wt% Mn-5.5wt% Si-9wt% Cr-3.5wt% Ni alloy, J. Alloys Compd., 407(2006), p.157.

    Article  CAS  Google Scholar 

  2. U. Sarı and İ. Aksoy, Electron microscopy study of 2H and 18R martensites in Cu-11.92wt% Al-3.78wt% Ni shape memory alloy, J. Alloys Compd., 417(2006), p.138.

    Article  Google Scholar 

  3. Z. Nishiyama, Martensitic Transformation, Academic Press, London, 1978.

    Google Scholar 

  4. J.H. Jun and C.S. Choi, The influence of Mn content on microstructure and damping capacity in Fe-(17–23)% Mn alloys, Mater. Sci. Eng. A, 252(1998), p.133.

    Article  Google Scholar 

  5. T.N. Durlu, Effect of austenite grain size on ɛ martensite formation in an Fe-Mn-Mo alloy, J. Mater. Sci. Lett., 16(1997), p.320.

    Article  CAS  Google Scholar 

  6. T. Kirindi, E. Güler, and M. Dikici, Effects of homogenization time on the both martensitic transformations and mechanical properties of Fe-Mn-Si-Cr-Ni shape memory alloy, J. Alloys Compd., 433(2007), p.202.

    Article  CAS  Google Scholar 

  7. J. Martínez, S.M. Cotes, A.F. Cabrera, J. Desimoni, and A. Fernández Guillermet, On the relative fraction of ɛ martensite in γ-Fe-Mn alloys, Mater. Sci. Eng. A, 408(2005), p.26.

    Article  Google Scholar 

  8. M. Acet, T. Schneider, B. Gehrmann, and E.F. Wassermann, The magnetic aspect of the γ-α and γ-ɛ martensitic transformation in Fe-Mn alloys, J. Phys. IV, 5(1995), p.379.

    Article  CAS  ADS  Google Scholar 

  9. P. Marinelli, A. Fernández Guillermet, and M. Sade, The enthalpy change of the hcp→fcc martensitic transformation in Fe-Mn-Co alloys: composition dependence and thermal cycling effects, Mater. Sci. Eng. A, 373(2004), p.1.

    Article  Google Scholar 

  10. S. Cotes, M. Sade, and A. Fernández Guillermet, Fcc/Hcp martensitic transformation in the Fe-Mn system: Experimental study and thermodynamic analysis of phase stability, Metall. Mater. Trans. A, 26(1995), p.1957.

    Article  Google Scholar 

  11. S. Cotes, A. Fernández Guillermet, and M. Sade, Phase stability and fcc/hcp martensitic transformation in Fe-Mn-Si alloys Part I. Experimental study and systematics of the M s and A s temperatures, J. Alloys Compd., 278(1998), p.231.

    Article  CAS  Google Scholar 

  12. P. Marinelli, A. Baruj, S. Cotes, A. Fernández Guillermet, and M. Sade, The γ↔α′ martensitic transformation in Fe-Mn and Fe-Mn-Co alloys: experiments, thermodynamic analysis and systematics of driving forces, Mater. Sci. Eng. A, 273–275(1999), p.498.

    Google Scholar 

  13. H. Li, D. Dunne, and N. Kennon, Factors influencing shape memory effect and phase transformation behaviour of Fe-Mn-Si based shape memory alloys, Mater. Sci. Eng. A, 273–275(1999), p.571.

    Google Scholar 

  14. T.N. Durlu, The effect of deformation on γ-ɛ martensitic transformation in an Fe-Mn-Mo alloy, J. Mater. Sci., 34(1999), p.2887.

    Article  CAS  Google Scholar 

  15. T.N. Durlu, Effect of γ↔ɛ cycles on the martensitic transformation characteristics of an Fe-Mn-Mo alloy, J. Mater. Sci. Lett., 15(1996), p.2134.

    CAS  Google Scholar 

  16. S.M. Cotes, A. Fernández Guillermet, and M. Sade, Fcc/Hcp martensitic transformation in the Fe-Mn system: Part II. Driving force and thermodynamics of the nucleation process, Metall. Mater. Trans. A, 35(2004), p.83.

    Article  Google Scholar 

  17. E. Güler, T. Kirindi, and H. Aktaş, Comparison of thermally induced and deformation induced martensite in Fe-29% Ni-2% Mn alloy, J. Alloys. Compd., 440(2007), p.168.

    Article  Google Scholar 

  18. X. Lu, Z.X. Qin, Y.S. Zhang, et al., Study of the paramagnetic-antiferromagnetic transition and the γ→ɛ martensitic transformation in Fe-Mn alloys, J. Mater. Sci., 35(2000), p.5597.

    Article  CAS  Google Scholar 

  19. J.H. Yang, H. Chen, and C.M. Wayman, Development of Fe-based shape memory alloys associated with face-centered cubic-hexagonal close-packed martensitic transformations: Part II. Transformation behaviour, Metall. Trans. A, 23(1992), p.1439.

    Article  Google Scholar 

  20. M. Mizrahi, A.F. Cabrera, S.M. Cotes, et al., Distribution of Mn atoms in a substitutional bcc-FeMn solid solution, Hyperfine Interact., 156/157(2004), p.541.

    Article  CAS  ADS  Google Scholar 

  21. S.M. Cotes, A.F. Cabrera, L.C. Damonte, et al., Phase transformations in Fe-Mn alloys induced by ball milling, Hyperfine Interact., 141/142 (2002), p.409.

    Article  CAS  ADS  Google Scholar 

  22. P. Marinelli, A. Baruj, J. Pons, et al., The enthalpy change of the hcp→fcc martensitic transformation in Fe-Mn alloys: composition dependence and effects of thermal cycling, Mater. Sci. Eng. A, 335(2002), p.137.

    Article  Google Scholar 

  23. Y.I. Petrow, E.A. Shafranovsky, Y.V. Baldokhin, and G.A. Kochetov, On ferro- and antiferromagnetic ordering in ultrafine particle of Fe-Rich Fe-Ni and Fe-Mn alloys, J. Appl. Phys., 86(1999), p.7001.

    Article  ADS  Google Scholar 

  24. J. Martínez, G. Aurelio, G. Cuello, et al., Mössbauer spectroscopy, dilatometry and neutron diffraction detection of the ɛ-phase fraction in Fe-Mn shape memory alloys, Hyperfine Interact., 161(2005), p.221.

    Article  ADS  Google Scholar 

  25. S.M. Cotes, A.F. Cabrera, L.C. Damonte, et al., Magnetic properties of ball-milled Fe-Mn alloys, Phys. B, 320(2002), p.274.

    Article  CAS  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. Kırındı.

Additional information

This study was financially supported by the Kırıkkale University Scientific Research Fund (Nos.2008/34 and 2008/35).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kırındı, T., Sarı, U. & Kurt, M. Mössbauer and electron microscopy study of martensitic transformations in an Fe-Mn-Mo alloy. Int J Miner Metall Mater 17, 448–452 (2010). https://doi.org/10.1007/s12613-010-0339-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-010-0339-z

Keywords

Navigation