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Quasi-two-dimensional bismuth oxychalcogenide nanoflakes as novel anode for potassium-ion batteries

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摘要

钾离子电池因其资源丰富、成本效益高, 工作原理相似而被认为是锂离子电池的理想替代品。 随着钾离子电池的发展, 由于钾离子具有更大的离子半径, 因此寻找具有结构稳定、载流子 扩散快等特点的负极材料成为当下最迫切的需求。本文通过简单的化学沉淀法, 在室温下合 理设计并精细制备了一种石墨烯包覆的新型超薄Bi2O2S@C 纳米。由于Bi2O2S 的层状结构 和独特的晶体框架结构, Bi2O2S@C 作为钾离子电池负极, 具有良好的储钾性能, 在100 mA·g-1 的条件下循环100 次后的容量为223. mAh·-11。此外, 结合原位X 射线衍射、拉曼 光谱和X 射线光电子能谱表征, Bi2O2S 的钾离子存储过程被揭示为多步转化和合金化反应。

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (Nos. 52070194, 52073309 and 51902347) and the Natural Science Foundation of Hunan Province (No. 2020JJ5741).

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Authors and Affiliations

  1. School of Metallurgy and Environment, Central South University, Changsha, 410083, China

    Shao-Jun Fang, Peng Du, Jia-Feng Zhang, Chun-Hui Wang, Zhi-Ming Xiao, Bao Zhang, Liang Cao, Xin-Ming Fan & Xing Ou

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  1. Shao-Jun Fang
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  2. Peng Du
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Correspondence to Liang Cao, Xin-Ming Fan or Xing Ou.

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Fang, SJ., Du, P., Zhang, JF. et al. Quasi-two-dimensional bismuth oxychalcogenide nanoflakes as novel anode for potassium-ion batteries. Rare Met. 41, 2567–2574 (2022). https://doi.org/10.1007/s12598-022-01970-x

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