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Development of Ti0.85Zr0.17(Cr-Mn-V)1.3Fe0.7-based Laves phase alloys for thermal hydrogen compression at mild operating temperatures

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金属氢化物是静态氢压缩装置的核心材料, 需要具备与静态氢压缩工艺参数相匹配的储氢性能。本文针对水浴温区工作条件的静态氢压缩目标, 对Ti0.85Zr0.17(Cr-Mn-V)1.3Fe0.7系合金展开了系统研究。结果表明, 所有Ti0.85Zr0.17(Cr-Mn-V)1.3Fe0.7系储氢合金均具有成分分布均一的C14 型Laves单相结构。随Ti0.85Zr0.17Cr1.2-xMnxFe0.7V0.1 (x = 0, 0.1, 0.2, 0.3)合金中Mn取代Cr含量的增加, 合金的坪台氢压、储氢容量都呈现上升趋势, 坪台斜率也有所下降, 但吸放氢滞后效应增大; 随Ti0.85Zr0.17Cr1.0+yMn0.2Fe0.7V0.1-y (y = 0, 0.05, 0.10)合金中V取代Cr含量的减少, 合金的坪台氢压上升, 但储氢容量略有下降。在所研究的样品中, Ti0.85Zr0.17Cr1.1Mn0.2Fe0.7合金具有较佳综合性能, 拥有1.67 wt%储氢容量与21.09 kJ/mol H2放氢焓变, 其在293 K下吸氢平衡压为5.08 MPa, 在363 K下放氢平衡压为24.90 MPa, 能够满足静态氢压缩装置的性能要求。

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Acknowledgements

This study was financially supported by the National Key Research and Development Program of China (No. 2019YFB1505100), the National Natural Science Foundation of China (No. U20A20237) and Zhejiang Provincial Natural Science Foundation of China (No. LZ21E010002).

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Authors and Affiliations

  1. State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Zi-Ming Cao, Pan-Pan Zhou, Xue-Zhang Xiao, Liu-Jun Zhan & Li-Xin Chen

  2. Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Hangzhou, 310013, China

    Li-Xin Chen

  3. Department of Materials Science and Engineering, The University of Manchester, Manchester, M13 9PL, UK

    Zhi-Fei Jiang

  4. Institute of Energy Materials and Technology, General Research Institute for Non-ferrous Metals, Beijing, 100088, China

    Shu-Mao Wang & Li-Jun Jiang

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  1. Zi-Ming Cao
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Cao, ZM., Zhou, PP., Xiao, XZ. et al. Development of Ti0.85Zr0.17(Cr-Mn-V)1.3Fe0.7-based Laves phase alloys for thermal hydrogen compression at mild operating temperatures. Rare Met. 41, 2588–2594 (2022). https://doi.org/10.1007/s12598-022-01962-x

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